| Page Range | 11209-11212 | |
| FR Document | 2016-04756 |
[Federal Register Volume 81, Number 42 (Thursday, March 3, 2016)] [Notices] [Pages 11209-11212] From the Federal Register Online [www.thefederalregister.org] [FR Doc No: 2016-04756] ----------------------------------------------------------------------- ENVIRONMENTAL PROTECTION AGENCY [FRL-9943-23-Region 5] Notice of Final Decision To Reissue the Ineos Nitriles USA LLC Land-Ban Exemption AGENCY: Environmental Protection Agency (EPA). ACTION: Notice of final decision on a Request by Ineos Nitriles USA LLC of Lima, Ohio to Reissue its Exemption from the Land Disposal Restrictions under the Resource Conservation and Recovery Act. ----------------------------------------------------------------------- SUMMARY: Notice is hereby given by the U.S. Environmental Protection Agency (U.S. EPA or Agency) that an exemption to the land disposal restrictions under the 1984 Hazardous and Solid Waste Amendments to the Resource Conservation and Recovery Act (RCRA) has been granted to Ineos Nitriles USA LLC (formerly known as Ineos USA LLC) (Ineos) of Lima, Ohio for four Class I injection wells located in Lima, Ohio. [[Page 11210]] As required by 40 CFR part 148, Ineos has demonstrated, to a reasonable degree of certainty, that there will be no migration of hazardous constituents out of the injection zone or into an underground source of drinking water for at least 10,000 years. This final decision allows the continued underground injection by Ineos of those hazardous wastes designated by the codes in Table 1 through its four Class I hazardous waste injection wells identified as #1, #2, #3, and #4. This decision constitutes a final U.S. EPA action for which there is no administrative appeal. DATES: This action is effective as of March 3, 2016. FOR FURTHER INFORMATION CONTACT: Stephen Roy, Lead Petition Reviewer, U.S. EPA, Region 5, Underground Injection Control Branch, WU-16J, 77 W. Jackson Blvd., Chicago, Illinois 60604-3590; telephone number: (312) 886-6556; fax number (312) 692-2951; email address: epa.gov">roy.stephen@epa.gov. Copies of the petition and all pertinent information are on file and are part of the Administrative Record. Please contact the lead reviewer to review the Administrative Record. SUPPLEMENTARY INFORMATION: Ineos submitted a request for reissuance of its existing exemption from the land disposal restrictions for hazardous waste in August, 2005. U.S. EPA reviewed all data pertaining to the petition including, but not limited to, well construction, well operations, regional and local geology, seismic activity, penetrations of the confining zone, and computational models of the injection zone. U.S. EPA has determined that the hydrogeological and geochemical conditions at the site and the nature of the waste streams are such that injected fluids will not migrate out of the injection zone within 10,000 years, as set forth at 40 CFR part 148. The injection zone includes the injection interval into which fluid is directly emplaced and the overlying arrestment interval into which fluid may diffuse. The injection interval for the Ineos facility is composed of the Lower Eau Claire Formation, the Mt. Simon Sandstone and the Middle Run Formation between 2,631 and 3,241 feet below ground level. The arrestment interval is composed of the Lower Black River Group, the Wells Creek Formation, the Knox Dolomite and the Upper Eau Claire Formation between 1,631 and 2,631 feet below ground level. The confining zone is composed of the Upper Black River Group between 1,427 and 1,631 feet below ground level. The confining zone is separated from the lowermost underground source of drinking water (at a depth of approximately 400 feet below ground level) by a sequence of permeable and less permeable sedimentary rocks. This sequence provides additional protection from fluid migration into drinking water sources. U.S. EPA issued a draft decision, which described the reasons for granting this exemption in more detail, a fact sheet, which summarized these reasons, and a public notice on September 10, 2015, pursuant to 40 CFR 124.10. The public comment period ended on October 13, 2015. U.S. EPA received comments from one citizen during the comment period. U.S. EPA has prepared a response to these comments, which can be viewed at the following URL: http:\\epa.gov\region5\water\uic\ineos-response- to-comments. The response is part of the Administrative Record for this decision. U.S. EPA is issuing the final exemption with no changes from the draft decision. Conditions This exemption is subject to the following conditions. Non- compliance with any of these conditions is grounds for termination of the exemption. (1) The exemption applies to the four existing hazardous waste injection wells, #1, #2, #3, and #4, located at the Ineos facility at 1900 Fort Amanda Road, Lima, Ohio; (2) Injection of hazardous waste is limited to the parts of the Lower Eau Claire Formation, the Mt. Simon Sandstone and the Middle Run Formation at depths between 2,631 and 3,241 feet below ground level; (3) The only RCRA-restricted wastes that may be injected are those designated by the RCRA waste codes found in Table 1; (4) Maximum concentrations of chemicals that are allowed to be injected are listed in Table 2; (5) The average specific gravity of the injected waste stream must be between 1.00 and 1.05 over a three month period; (6) Ineos may inject up to 175 gallons per minute through each of its four wells, based on a monthly average; (7) This exemption is approved for the 20-year modeled injection period, which ends on January 31, 2025. Ineos may petition U.S. EPA for reissuance of the exemption beyond that date, provided that a new and complete petition and no-migration demonstration is received at U.S. EPA, Region 5, by June 30, 2024; (8) Ineos must submit a quarterly report containing the fluid analyses of the injected waste and indicate the chemical and physical properties, including the concentrations, of all the injected chemical constituents listed in Table 2 to U.S. EPA; (9) Ineos must submit an annual report containing the results of a bottom hole pressure survey (fall-off test) performed on one well each year to U.S. EPA. The survey must be performed after shutting down the well for sufficient time to conduct a valid observation of the pressure fall-off curve under 40 CFR 146.68(e)(1). The annual report must include a comparison of reservoir parameters determined from the fall- off test with parameters used in the approved no-migration petition; (10) Ineos must submit the results of radioactive tracer surveys and annulus pressure tests for its four wells to U.S. EPA annually; (11) Ineos must notify U.S. EPA in writing if any well loses mechanical integrity and prior to any workover or plugging; (12) Ineos must fully comply with all requirements set forth in Underground Injection Control Permits #UIC 03-02-003-PTO-1, UIC 03-02- 004-PTO-1, UIC 03-02-005-PTO-01 and 03-02-006-PTO-1 issued by the Ohio Environmental Protection Agency; (13) Upon the expiration, cancellation, reissuance, or modification of the permits referenced above, this exemption is subject to review by U.S. EPA; and (14) Whenever U.S. EPA determines that the basis for approval of a petition under 40 CFR 148.23 and 148.24 may no longer be valid, U.S. EPA may terminate this exemption and will require a new demonstration in accordance with 40 CFR 148.20. Table 1--List of RCRA Waste Codes Approved for Injection -------------------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------------------- D001 D002 D003 D004 D005 D006 D007 D008 D009 D010 D011 D018 D019 D035 D038 F039 K011 K013 K014 P003 P005 P030 P063 P069 P098 P101 P106 P120 U001 U002 U003 U007 U008 U009 U019 U031 U044 U053 U056 U057 U080 U112 U122 U123 U124 U125 U129 U140 U147 U149 U151 U152 U154 U159 U161 U169 U188 U191 U196 U211 [[Page 11211]] U213 U219 U220 U239 -------------------------------------------------------------------------------------------------------------------------------------------------------- These waste codes are identified in 40 CFR part 261, subpart C and subpart D. Table 2--Concentration Limits of Chemical Contaminants That Are Hazardous at Less Than 0.001 Mg/L ---------------------------------------------------------------------------------------------------------------- Concentration Health based limit limit at the Concentration Chemical constituent Waste code (mg/L) wellhead (mg/ reduction factor L) (Note 2) (C/C0) ---------------------------------------------------------------------------------------------------------------- Acetaldehyde................... U001.............. 0.11 2,000 5.5 x 10-5 Acetamide...................... Note 2............ 1.0 x 10-5 10,000 1.0 x 10-9 Acetic acid.................... Note 2............ 6.0 x 10-6 6,000 1.0 x 10-9 Acetone........................ U002.............. 3.5 2,000 1.75 x 10-3 Acetone cyanohydrin............ P069.............. 0.005 6,000 8.33 x 10-7 Acetonitrile................... K011, K013, K014, 0.21 100,000 2.1 x 10-6 U003. Acrolein....................... P003.............. 0.005 2,000 2.5 x 10-6 Acrylamide..................... K011, K013, K014, 8 x 10-6 6,000 1.33 x 10-9 U007. Note 1 Acrylic acid................... U008.............. 17.5 60,000 2.92 x 10-4 Acrylonitrile.................. K011, K013, K014, 6.0 x 10-5 24,000 2.5 x 10-9 U009. Allyl alcohol.................. P005.............. 0.175 2,000 8.75 x 10-5 Antimony....................... F039.............. 0.006 100 6.0 x 10-5 Arsenic........................ D004.............. 0.05 100 5.0 x 10-4 Barium......................... D005.............. 2 100 2.0 x 10-2 Benzene........................ D018, K011, K013, 0.005 400 1.25 x 10-5 K014, U019. 1,3-Butanediol................. Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 1,4-Butanediol................. Note 2............ 1.4 x 10-5 14,000 1.0 x 10-9 Butanetriol.................... Note 2............ 4.0 x 10-6 4,000 1.0 x 10-9 Butanol........................ U140.............. 3.5 4,000 8.75 x 10-4 Butyrolactone.................. Note 2............ 5.0 x 10-6 5,000 1.0 x 10-9 Cadmium........................ D006.............. 0.005 100 5.0 x 10-5 Carbon tetrachloride........... D019, U211........ 0.005 100 5.0 x 10-5 Chloroform..................... U044.............. 0.006 100 6.0 x 10-5 Chromium....................... D007.............. 0.1 100 1.0 x 10-3 Cobalt......................... Note.............. 1.0 x 10-7 100 1.0 x 10-9 Crotonaldehyde................. U053.............. 0.002 200 1.0 x 10-5 Crotonitrile................... Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 Cyclohexane.................... U056.............. 9.0 x 10-5 100 9.0 x 10-7 Cyclohexanone.................. U057.............. 180 100 1.8 Diethylenetriamine pentaacetic Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 acid. Dimethylhydantoin.............. Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 Ethanol........................ Note 2............ 2.0 x 10-6 2,000 1.0 x 10-9 Ethyl acetate.................. U112.............. 31.5 100 3.15 x 10-1 Ethylenediamine Note 2............ 4.0 x 10-6 4,000 1.0 x 10-9 tetracetonitrile. Formic acid.................... U123.............. 0.01 20,000 5.0 x 10-7 Formaldehyde................... U122.............. 7 4,000 1.75 x 10-3 Formamide...................... Note 2............ 4.0 x 10-6 4,000 1.0 x 10-9 Fumaronitrile.................. Note 2............ 4.0 x 10-6 4,000 1.0 x 10-9 Furan.......................... U124.............. 3.5 x 10-3 100 3.5 x 10-4 Furfural....................... U125.............. 0.11 100 1.1 x 10-3 Glyconitrile................... Note 2............ 7.0 x 10-6 7,000 1.0 x 10-9 HCN (Free)..................... K011, K013, K014, 0.2 3,200 6.25 x 10-5 P030, P063, P098, P106. HCN (Total).................... K011, K013, K014, 0.7 21,200 3.3 x 10-5 P030, P063, P098, P106. Hexamethylenetetramine (or Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 acid). Iminodiacetonitrile............ Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 Isobutanol..................... U140.............. 11 200 5.5 x 10-2 Isopropyl alcohol.............. Note 2............ 1.2 x 10-6 1,200 1.0 x 10-9 Lead........................... D008.............. 0.001 100 1.0 x 10-5 Lindane........................ U129.............. 2.0 x 10-4 1,000 2.0 x 10-7 Maleic anhydride............... U147.............. 3.5 100 3.5 x 10-2 Maleonitrile................... Note 2............ 2.0 x 10-5 20,000 1.0 x 10-9 Malonitrile.................... U149.............. 0.005 2,000 2.5 x 10-6 Mercury........................ D009, U151........ 0.002 100 2.0 x 10-5 Methanol....................... U154.............. 17.5 40,000 4.38 x 10-4 Methyacrylonitrile............. U152.............. 0.0035 400 8.75 x 10-6 Methylethylhydantoin........... Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 Methylene chloride............. U080.............. 5.3 x 10-3 100 5.0 x 10-5 Methyl ethyl ketone............ D035, U159........ 21 1,000 2.1 x 10-2 Methyl isobutyl ketone......... U161.............. 2.0 x 10-3 100 2.0 x 10-5 [[Page 11212]] 2-Methylpyridine............... U191.............. 2.0 x 10-3 1,000 2.0 x 10-6 3-Methylpyridine............... Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 Nickel......................... F006.............. 0.001 100 1.0 x 10-5 Nicotinonitrile................ Note 2............ 6.0 x 10-6 6,000 1.0 x 10-9 Nitrilotiracetonitrile......... Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 Nitrobenzene................... U169.............. 1.8 x 10-2 100 1.8 x 10-4 Oleic acid..................... Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 Oleoylsarconsinate............. Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 Phenol......................... U188.............. 21 100 2.1 x 10-1 1,2-Propanediol................ Note 2............ 6.0 x 10-8 60 1.0 x 10-9 1,3-Propanediol................ Note 2............ 2.0 x 10-6 2,000 1.0 x 10-9 Propanol....................... Note 2............ 2,0 x 10-6 2,000 1.0 x 10-9 Propionitrile.................. P101.............. 0.005 2,000 2.5 x 10-6 Propylenediamine Note 2............ 1.0 x 10-6 1,000 1.0 x 10-9 tetracetonitrile. Pyroazole...................... Note 2............ 4.0 x 10-6 4,000 1.0 x 10-9 Pyridine....................... D038, U196........ 0.035 2,000 1.75 x 10-5 Selenium....................... D010.............. 0.05 100 5.0 x 10-4 Silver......................... D011.............. 0.175 100 1.75 x 10-3 Sodium cyanide................. D003, K011, K013, 1.4 1,200 1.17 x 10-3 P030, P063, P106. Strontium...................... Note 2............ 1.0 x 10-7 100 1.0 x 10-9 Succinic acid.................. Note 2............ 8.0 x 10-7 800 1.0 x 10-9 Succinotrile................... Note 2............ 6.0 x 10-6 6,000 1.0 x 10-9 Tetrahydrofuran................ U213.............. 0.002 5,000 4.0 x 10-7 Thiourea....................... U219.............. 1.0 x 10-2 100 1.0 x 10-4 Toluene........................ U220.............. 1 100 1.0 x 10-2 Vanadium....................... P120.............. 0.004 100 4.0 x 10-5 Vanadium pentoxide............. P120.............. 0.315 400 7.88 x 10-4 Xylene......................... U239.............. 10 100 1.0 x 10-1 Zinc........................... Note 2............ 10.5 400 2.63 x 10-2 ---------------------------------------------------------------------------------------------------------------- Note 1--Worst-case constituent. Health Based Limit (HBL) contour for no-migration boundary set at 1.0 x 10-9 for this constituent. The HBL values are from the compilation by EPA Region 6, revised 2005. Note 2--Constituents not associated with an EPA RCRA waste code or listed in HBL guidelines are assigned the minimum C/C0 of 1.0 x 10-9. A provisional ``HBL'' for these constituents is then derived from the product of C/C0 and the concentration limit at the wellhead. If a RCRA waste code is promulgated for any of these constituents, the HBL selected by EPA will be compared to the provisional ``HBL'' on this table. If the EPA HBL is more stringent, the Concentration Limit at the Wellhead will be reduced or migration of the constituent will be reconsidered in detail. Electronic Access. You may access this Federal Register document electronically from the Government Printing Office under the ``Federal Register'' listings at FDSys (http://www.thefederalregister.org/fdsys/browse/collection.action?collectionCode=FR). Dated: February 1, 2016. Tinka G. Hyde, Director, Water Division. [FR Doc. 2016-04756 Filed 3-2-16; 8:45 am] BILLING CODE 6560-50-P
| Category | Regulatory Information | |
| Collection | Federal Register | |
| sudoc Class | AE 2.7: GS 4.107: AE 2.106: | |
| Publisher | Office of the Federal Register, National Archives and Records Administration | |
| Section | Notices | |
| Action | Notice of final decision on a Request by Ineos Nitriles USA LLC of Lima, Ohio to Reissue its Exemption from the Land Disposal Restrictions under the Resource Conservation and Recovery Act. | |
| Dates | This action is effective as of March 3, 2016. | |
| Contact | Stephen Roy, Lead Petition Reviewer, U.S. EPA, Region 5, Underground Injection Control Branch, WU-16J, 77 W. Jackson Blvd., Chicago, Illinois 60604-3590; telephone number: (312) | |
| FR Citation | 81 FR 11209 |