83_FR_47119 83 FR 46939 - Notice of Final Approval for an Alternative Means of Emission Limitation at ExxonMobil Corporation; Marathon Petroleum Company, LP (for Itself and on Behalf of Its Subsidiary, Blanchard Refining, LLC); Chalmette Refining, LLC; and LACC, LLC

83 FR 46939 - Notice of Final Approval for an Alternative Means of Emission Limitation at ExxonMobil Corporation; Marathon Petroleum Company, LP (for Itself and on Behalf of Its Subsidiary, Blanchard Refining, LLC); Chalmette Refining, LLC; and LACC, LLC

ENVIRONMENTAL PROTECTION AGENCY

Federal Register Volume 83, Issue 180 (September 17, 2018)

Page Range46939-46945
FR Document2018-20148

This notice announces our approval of the Alternative Means of Emission Limitation (AMEL) requests under the Clean Air Act (CAA) submitted from ExxonMobil Corporation; Marathon Petroleum Company, LP (for itself and on behalf of its subsidiary, Blanchard Refining, LLC); and Chalmette Refining, LLC to operate flares and multi-point ground flares (MPGFs) at several refineries in Texas and Louisiana, and from LACC, LLC to operate flares at a chemical plant in Louisiana. This approval notice specifies the operating conditions and monitoring, recordkeeping, and reporting requirements that these facilities must follow to demonstrate compliance with the approved AMEL.

Federal Register, Volume 83 Issue 180 (Monday, September 17, 2018)
[Federal Register Volume 83, Number 180 (Monday, September 17, 2018)]
[Notices]
[Pages 46939-46945]
From the Federal Register Online  [www.thefederalregister.org]
[FR Doc No: 2018-20148]


=======================================================================
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ENVIRONMENTAL PROTECTION AGENCY

[EPA-HQ-OAR-2014-0738 and EPA-HQ-OAR-2010-0682; FRL-9983-26-OAR]


Notice of Final Approval for an Alternative Means of Emission 
Limitation at ExxonMobil Corporation; Marathon Petroleum Company, LP 
(for Itself and on Behalf of Its Subsidiary, Blanchard Refining, LLC); 
Chalmette Refining, LLC; and LACC, LLC

AGENCY: Environmental Protection Agency (EPA).

ACTION: Notice; final approval.

-----------------------------------------------------------------------

SUMMARY: This notice announces our approval of the Alternative Means of 
Emission Limitation (AMEL) requests under the Clean Air Act (CAA) 
submitted from ExxonMobil Corporation; Marathon Petroleum Company, LP 
(for itself and on behalf of its subsidiary, Blanchard Refining, LLC); 
and Chalmette Refining, LLC to operate flares and multi-point ground 
flares (MPGFs) at several refineries in Texas and Louisiana, and from 
LACC, LLC to operate flares at a chemical plant in Louisiana. This 
approval notice specifies the operating conditions and monitoring, 
recordkeeping, and reporting requirements that these facilities must 
follow to demonstrate compliance with the approved AMEL.

DATES: The approval of the AMEL requests from ExxonMobil Corporation; 
Marathon Petroleum Company, LP (for itself and on behalf of its 
subsidiary, Blanchard Refining, LLC); Chalmette Refining, LLC; and 
LACC, LLC to operate certain flares at the refineries and a chemical 
plant, as specified in this notice, is effective on September 17, 2018.

ADDRESSES: The Environmental Protection Agency (EPA) has established a 
docket for this action under Docket ID No. EPA-HQ-OAR-2014-0738. All 
documents in the docket are listed on the https://www.regulations.gov 
website. Although listed, some information is not publicly available, 
e.g., confidential business information (CBI) or other information 
whose disclosure is restricted by statute. Certain other material, such 
as copyrighted material, is not placed on the internet and will be 
publicly available only in hard copy form. Publicly available docket 
materials are available either electronically through http://www.regulations.gov or in hard copy at EPA Docket Center, EPA WJC West 
Building, Room Number 3334, 1301 Constitution Ave. NW, Washington, DC. 
The Public Reading Room hours of operation are 8:30 a.m. to 4:30 p.m. 
Eastern Standard Time (EST), Monday through Friday. The telephone 
number for the Public Reading Room is (202) 566-1744, and the telephone 
number for the Docket Center is (202) 566-1742.

FOR FURTHER INFORMATION CONTACT: For questions about this final action, 
contact Ms. Angie Carey, Sector Policies and Programs Division (E143-
01), Office of Air Quality Planning and Standards, U.S. Environmental 
Protection Agency, Research Triangle Park, North Carolina 27711; 
telephone number: (919) 541-2187; fax number: (919) 541-0516; and email 
address: [email protected].

SUPPLEMENTARY INFORMATION: Preamble acronyms and abbreviations. We use 
multiple acronyms and terms in this preamble. While this list may not 
be exhaustive, to ease the reading of this preamble and for reference 
purposes, the EPA defines the following terms and acronyms here:

AMEL alternative means of emission limitation
BTU/scf British thermal units per standard cubic foot
CAA Clean Air Act
CBI confidential business information
CFR Code of Federal Regulations
EPA Environmental Protection Agency
Eqn equation
g/mol grams per gram mole
HAP hazardous air pollutants
HP high pressure
LFL lower flammability limit
LFLcz lower flammability limit of combustion zone gas
LFLvg lower flammability limit of flare vent gas
LRGO linear relief gas oxidizer
MPGF multi-point ground flare
NESHAP national emission standards for hazardous air pollutants
NHV net heating value
NHVcz net heating value of combustion zone gas
NHVvg net heating value of flare vent gas
NSPS new source performance standards
OAQPS Office of Air Quality Planning and Standards
scf standard cubic feet
SKEC steam-assisted kinetic energy combustor
TCEQ Texas Commission on Environmental Quality
VOC volatile organic compounds

    Organization of This Document. The information in this notice is 
organized as follows:

I. Background
    A. Summary
    B. Regulatory Flare Requirements
II. Summary of Public Comments on the AMEL Requests
III. AMEL for the Flares

I. Background

A. Summary

    In a Federal Register notice dated April 25, 2018, the EPA provided 
public notice and solicited comment on the requests under the CAA from 
ExxonMobil Corporation; Marathon Petroleum Company, LP (for itself and 
on behalf of its subsidiary, Blanchard Refining, LLC's); and Chalmette 
Refining, LLC for the operation of flares and MPGFs at several 
refineries in Texas and Louisiana, and from LACC, LLC to operate flares 
at a chemical plant in Louisiana (see 83 FR 18034). This action 
solicited comment on all aspects of the AMEL requests, including the 
operating conditions specified in that action that are necessary to 
achieve a reduction in emissions of volatile organic compounds and 
organic hazardous air pollutants at least equivalent to the reduction 
in emissions required by various standards in 40 CFR parts 60, 61, and 
63 that apply to emission sources that would be controlled by these 
flares and MPGFs. These standards incorporate the flare design and 
operating requirements in 40 CFR part 60 and 63 General Provisions 
(i.e., 40 CFR 60.18(b) and 63.11(b)) into the individual new source 
performance standards (NSPS) and maximum achievable control technology 
(MACT) subparts, except for the Petroleum Refinery MACT, 40 CFR part 
63, subpart CC, which specifies its flare requirements within the 
subpart (i.e., 40 CFR 63.670). Four of the requests are for flares 
located at petroleum refineries, while the request from LACC, LLC is 
for a flare design at a chemical manufacturing facility. None of the

[[Page 46940]]

flares located at petroleum refineries can meet the flare tip velocity 
limits in the Petroleum Refinery MACT, 40 CFR part 63, subpart CC. In 
addition, flares at these refineries and at LACC's chemical plant that 
are subject to other 40 CFR part 60 and 63 standards cannot meet the 
flare tip velocity limits contained in the applicable General 
Provisions to 40 CFR part 60 and 63.
    This action provides a summary of the comments received as part of 
the public review process, our response to those comments, and our 
approval of these AMEL requests.

B. Regulatory Flare Requirements

    ExxonMobil, Marathon, Blanchard, and Chalmette provided the 
information specified in the flare AMEL framework set forth in the 
Petroleum Refinery MACT at 40 CFR 63.670(r) to support their AMEL 
requests. LACC provided the information specified in the flare AMEL 
framework finalized on April 21, 2016 (81 FR 23486), to support its 
AMEL request. The ExxonMobil Corporation Baytown Refinery in Baytown, 
Texas, is seeking an AMEL to operate a gas-assisted flare, Flare 26, 
during periods of startup, shutdown, upsets, and emergency events, as 
well as during fuel gas imbalance events. Marathon Petroleum Company, 
LP's Garyville, Louisiana Refinery, and Blanchard Refining, LLC's 
Galveston Bay Refinery (GBR) in Texas City, Texas, are seeking AMELs to 
operate their flares only during periods of startup, shutdown, upsets, 
and emergency events. Chalmette Refining, LLC in Chalmette, Louisiana, 
is seeking an AMEL to operate its flare, No. 1 Flare, during periods of 
upset and emergency events. LACC, LLC is seeking an AMEL to operate 
flares at its chemical plant in Lake Charles, Louisiana, during 
startups, shutdowns, upsets, and emergency events. See Table 1 for a 
list of regulations, by subparts, that each refinery and chemical plant 
has identified as applicable to the flares described above.

                                   Table 1--Summary of Applicable Rules That May Apply to Streams Controlled by Flares
--------------------------------------------------------------------------------------------------------------------------------------------------------
                                   Exxon Mobil
   Applicable rules with vent       Baytown,      Marathon      Blanchard     Chalmette               Rule citation from title       Provisions for
    streams going to control       Texas Flare   Garyville,   Refining GBR   No. 1 Flare     LACC       40 CFR that allow for     alternative means of
            device(s)                  26          LA MPGF        MPGF                                     use of a flare          emission limitation
--------------------------------------------------------------------------------------------------------------------------------------------------------
NSPS Subpart VV.................  ............            x             x   ............  ..........  60.482-10(d)............  60.484(a)-(f).
NSPS Subpart VVa................  ............            x             x   ............          x   60.482-10a(d)...........  60.484a(a)-(f).
NSPS Subpart NNN................  ............            x             x             x           x   60.662(b)...............  CAA section 111(h)(3).
NSPS Subpart QQQ................  ............            x             x   ............  ..........  60.692-5(c).............  42 U.S.C. 7411(h)(3).
NSPS Subpart RRR................  ............            x             x   ............          x   60.702(b)...............  CAA section 111(h)(3).
NSPS Subpart Kb.................  ............            x             x   ............          x   60.112b(a)(3)(ii).......  60.114b.
NESHAP Subpart V................  ............            x             x   ............          x   61.242-11(d)............  40 CFR 63.6(g); 42
                                                                                                                                 U.S.C. 7412(h)(3).
NESHAP Subpart J................  ............  ............  ............  ............          x   61.242-11(d)............  40 CFR 63.6(g); 42
                                                                                                                                 U.S.C. 7412(h)(3).
NESHAP Subpart Y................  ............            x             x   ............  ..........  61.271-(c)(2)...........  40 CFR 63.6(g); 40 CFR
                                                                                                                                 61.273; 42 U.S.C.
                                                                                                                                 7412(h)(3).
NESHAP Subpart BB...............  ............            x             x   ............  ..........  61.302(c)...............  40 CFR 63.6(g); 42
                                                                                                                                 U.S.C. 7412(h)(3).
NESHAP Subpart FF...............  ............            x             x   ............          x   61.349(a)(2)............  61.353(a); also see
                                                                                                                                 61.12(d).
NESHAP Subpart F................  ............            x             x   ............          x   63.103(a)...............  63.6(g); 42 U.S.C.
                                                                                                                                 7412(h)(3).
NESHAP Subpart G................  ............            x             x   ............          x   63.113(a)(1)(i),          63.6(g); 42 U.S.C.
                                                                                                       63.116(a)(2),             7412(h)(3).
                                                                                                       63.116(a)(3),
                                                                                                       63.119(e), 63.120(e)(1)
                                                                                                       through (4),
                                                                                                       63.126(b)(2)(i),
                                                                                                       63.128(b),
                                                                                                       63.139(c)(3),
                                                                                                       63.139(d)(3), 63.145(j).
NESHAP Subpart H................  ............            x             x   ............          x   63.172(d), 63.180(e)....  63.177; 42 U.S.C.
                                                                                                                                 7412(h)(3).
NESHAP Subpart SS...............  ............            x             x   ............          x   63.982(b)...............  CAA section 112(h)(3).
NESHAP Subpart CC...............            x             x             x             x   ..........  63.643(a)(1)............  63.670(r).
NESHAP Subpart UU...............  ............  ............  ............  ............          x   63.1034.................  63.1021(a)-(d).
NESHAP Subpart YY...............  ............  ............  ............  ............          x   Table 7 to 63.1103(e)     63.1113.
                                                                                                       cross-references to
                                                                                                       NESHAP subpart SS above.
NESHAP Subpart EEEE.............  ............            x             x   ............  ..........  63.2378(a),63.2382,       63.6(g); 42 U.S.C.
                                                                                                       63.2398.                  7412(h)(3).
--------------------------------------------------------------------------------------------------------------------------------------------------------

    The provisions for the NSPS and National Emission Standards for 
Hazardous Air Pollutants (NESHAP) cited in Table 1 that ensure flares 
meet certain specific requirements when used to satisfy the 
requirements of the NSPS or NESHAP were established as work practice 
standards pursuant to CAA sections 111(h)(1) or 112(h)(1). For 
standards established according to these provisions, CAA sections 
111(h)(3) and 112(h)(3) allow the EPA to permit the use of an AMEL by a 
source if, after notice and opportunity for comment,\1\ it is 
established to the Administrator's satisfaction that such an AMEL will 
achieve emission reductions at least equivalent to the reductions 
required under the CAA section 111(h)(1) or 112(h)(1) standard. As 
noted in Table 1, many of the NSPS and NESHAP in the table above also 
include specific regulatory provisions allowing sources to request an 
AMEL.
---------------------------------------------------------------------------

    \1\ CAA section 111(h)(3) specifically requires that the EPA 
provide an opportunity for a public hearing. The EPA provided an 
opportunity for a public hearing in the April 25, 2018, Federal 
Register action. However, no public hearing was requested.
---------------------------------------------------------------------------

II. Summary of Public Comments on the AMEL Requests

    The EPA received four public comments on this action. Specifically, 
the EPA received suggested changes and clarifications from LACC, LLC, 
Marathon Petroleum Company, LP (for itself and on behalf of its 
subsidiary, Blanchard Refining, LLC), and ExxonMobil Corporation. The 
EPA also received one comment that does not mention any of the AMEL 
requests at issue and is, therefore, outside the scope

[[Page 46941]]

of the action. As discussed in more detail below, we have modified or 
otherwise clarified certain operating conditions in response to 
comments.\2\ All of the comments within the scope of the AMEL requests 
were supportive of the EPA approving the AMEL requests, and none of the 
comments raised issues with the EPA's authority to approve these AMEL 
requests under the CAA. None of the commenters asserted that the EPA 
lacked authority to approve the AMEL requests or that the AMEL requests 
would not achieve at least equivalent emissions reductions as flares 
that meet the standards in the General Provisions or in the Petroleum 
Refinery MACT at 40 CFR 63.670(r).
---------------------------------------------------------------------------

    \2\ As explained below, we have clarified the reporting 
requirements for Exxon's Flare 26 in response to a comment by Exxon. 
We have similarly clarified Marathon's Garyville's and GBR's MPGFs 
reporting requirements as a result of this comment.
---------------------------------------------------------------------------

    Comment: LACC, LLC commented that the monitoring requirement in 
section (3) to install a video camera capable of continuously recording 
(i.e., at least one frame every 15 seconds with time and date stamps) 
images of the flare flame at a reasonable distance and suitable angle, 
will work for their MPGF, but not for their enclosed ground flare. LACC 
stated that it is not technically feasible to install a video camera 
and monitor the flare flame within the enclosed ground flare. 
Alternatively, LACC stated that it can monitor for the presence of 
visible emissions from the enclosed ground flare by using a video 
camera to monitor at the exit of the stack exhaust.
    Response: We agree that, although the camera would not be able to 
directly monitor visible emissions from the flare flame because of the 
enclosure, conducting visible emissions observations at the stack would 
be a reliable indicator of compliance with the requirements in section 
(3) below. Therefore, we accept this alternative and have made the 
appropriate change in section (3) below.
    Comment: Marathon Petroleum Company, LP commented that the 
operating conditions in Table 2 do not reflect what they requested in 
their AMEL for the MPGF at their Garyville refinery. They stated that 
they needed separate NHVcz limits for the pressure-assisted linear 
relief gas oxidizers (LRGO burners) and the steam-assisted steam 
kinetic energy combustors (SKEC burners) when both are being used 
simultaneously. Marathon explained that the SKEC burners would have a 
considerably different NHVcz value because of steam assist. This is 
because the steam assist is included in the NHVcz calculation for the 
SKEC burners, but not for the LRGO burners, given that the LRGO burners 
do not have steam assist.
    Response: The EPA acknowledges that the April notice did not 
reflect Marathon Petroleum Company, LP's supplemental request for the 
Garyville MPGF to maintain separate burner limits such that the SKEC 
burners would meet the NHVcz target from the SKEC equation and the LRGO 
burners would meet 600 British thermal units per standard cubic feet 
(BTU/scf). We discussed with Marathon its supplemental request upon 
receiving the comment. As we explained in that discussion, based on our 
review of the information provided by Marathon, the steam-to-vent gas 
ratio for the SKEC burners is not high enough to significantly affect 
the NHVcz during the high pressure flaring scenario. Therefore, we 
conclude that the burner requirements as set out in the April 25, 2018, 
AMEL document are appropriate. Marathon concurred with this conclusion 
in an email response after the comment period closed (available in 
Docket ID No. EPA-HQ-OAR-2014-0738 and EPA-HQ-OAR-2010-0682).
    Comment: Marathon Petroleum Company, LP commented that the 
requirement should be NHVvg = NHVcz with a limit of >=600 BTU/scf for 
the LH burner, and NHVcz >=600 BTU/scf for LRGO burners. Marathon notes 
that, as explained in its February 2, 2018, and March 27, 2018, 
supplemental letters, since the LH burner is air-assisted, therefore, 
the LH burner limitations provided in its request correspond to the 
NHVvg and not the NHVcz. Marathon further notes that the Petroleum 
Refinery requirements at 40 CFR 63.670(m)(1) states that NHVvg = NHVcz 
when there is no premix assist air flow.
    Response: For the reasons provided in Marathon's comment, we agree 
that for the LH burner, which is perimeter air assisted and not pre-mix 
air assisted, the NHVvg equals NHVcz. We, therefore, made this change 
in Table 2 below.
    Comment: ExxonMobil Corporation commented on a typographical 
correction in Table 2 for the Baytown, Texas, Flexicoker Flare 26. The 
proposed alternative operating condition was listed as >=270 BTU/scf 
NHVcz and velocity of <361 feet per second (ft/sec). However, the 
performance test results for the Flare 26 demonstrate that the 
destruction efficiency met 98 percent at 361 ft/sec.
    Response: We accept this correction and made the change in Table 2 
to <=361 ft/sec.
    Comment: ExxonMobil Corporation commented that the EPA should 
include a default molecular weight for pipeline natural gas that 
corresponds to an NHV of 920 BTU/scf listed in 40 CFR 63.670(j)(5).
    Response: We agree and are specifying the molecular weight of 
pipeline natural gas as 16.85 grams per gram mole (g/mol). It would be 
burdensome for Exxon to take samples of natural gas to determine 
molecular weight, when very little changes in molecular weight are 
expected. Therefore, we are specifying the molecular weight of natural 
gas of 16.85 can be used. This molecular weight is based on our default 
natural gas composition that was used to determine the net heating 
value in 40 CFR 63.670.
    Comment: ExxonMobil Corporation commented that the accuracy and 
calibration requirements in section (1)(f) of the initial Federal 
Register document should apply only to flares at chemical plants 
seeking AMEL approval since flares such as Exxon's Flare 26 is already 
subject to the accuracy and calibration requirements in the Petroleum 
Refinery MACT at 40 CFR 63.671(a)(1) and (4) and Table 13.
    Response: We agree and have clarified in section (1)(f) below that 
the accuracy and calibration requirements listed in Table 4 do not 
apply to refinery flares subject to requirements at 40 CFR 63.671(a)(1) 
and (4) and Table 13 of 40 CFR part 63, subpart CC.
    Comment: ExxonMobil Corporation commented that the Flare 26 follows 
the Petroleum Refinery MACT requirement at 40 CFR part 63, subpart CC, 
for pilot flame operations and does not use cross-lighting for the 
flare operation. They stated that the EPA should clarify in section (2) 
that the Flare 26 is only required to maintain flare pilots per the 
Petroleum Refinery MACT requirements in 40 CFR 63.670(b).
    Response: We agree that the requirements in section (2), which 
apply to flares that cross light, should not apply to Flare 26 because 
it does not use cross-lighting. We have made this change in section (2) 
below.
    Comment: ExxonMobil Corporation commented that the EPA should 
clarify which reporting requirements apply to the Flare 26 in section 
(6) and clarify that the reporting requirements for the flare tip 
velocity and NHVcz are applicable when regulated material is routed to 
the flare for at least 15 minutes.
    Response: While we believe that the records required in section 
(6)(c) are essentially the same as the reporting requirements in 
Petroleum Refinery NESHAP, 40 CFR part 63, subpart CC, section (6)(c) 
requires additional records related to the operation of MPGFs, which do 
not apply to Flare 26. Further,

[[Page 46942]]

we agree that the operating limits for NHVcz and Vtip apply whenever 
regulated material is routed to the flares for at least 15 minutes, as 
specified by 40 CFR part 63, subpart CC; Therefore, we are requiring 
that Flare 26 comply with the reporting requirements in the Petroleum 
Refinery NESHAP, 40 CFR part 63, subpart CC, instead of section (6) as 
part of this AMEL approval. However, MPGFs located at petroleum 
refineries must comply with the additional reporting requirements for 
MPGFs in (6)(c)(iv) and (v). To avoid other potential confusion, we are 
clarifying the applicability of section (6)(c) to all the flares 
covered in this notice. Specifically, section (6)(c) below provides 
that flares at refineries must meet the requirements in the Petroleum 
Refinery MACT in 40 CFR 63.655(g)(11)(i)-(iii), except that the 
applicable alternative operating conditions listed in Table 2 apply 
instead of the operating limits specified in 40 CFR 63.670(d) through 
(f). In addition, for refinery flares that are MPGFs, notification 
shall also include records specified in section (6)(c)(iv)-(v). For 
LACC MPGFs, the notification shall include the records specified in 
section (6)(c)(i)-(v).

III. AMEL for the Flares

    Based upon our review of the AMEL requests and the comments 
received through the public comment period, we are approving these AMEL 
requests and are establishing operating conditions for the flares at 
issue. The AMEL and the associated operating conditions are specified 
in Table 2 and accompanying paragraphs. These operating conditions will 
ensure that these flares will achieve emission reductions at least 
equivalent to flares complying with the flare requirements under the 
applicable NESHAP and NSPS identified in Table 1.

                                    Table 2--Alternative Operating Conditions
----------------------------------------------------------------------------------------------------------------
                                               Affected
    AMEL submitted          Company           facilities       Flare type(s)    Alternative operating conditions
----------------------------------------------------------------------------------------------------------------
11/7/17..............  ExxonMobil.......  Baytown, TX        Elevated gas-      >=270 BTU/scf NHV and velocity
                                           Flexicoker Flare   assist flare.      <=361 (ft/sec).
                                           26.
10/7/17..............  Marathon.........  Garyville, LA....  2 MPGFs..........  When both SKEC and LRGO burners
                                                                                 are being used, the higher of
                                                                                 >=600 BTU/scf NHV or >=127.27
                                                                                 ln(v)-110.87 NHV. When only the
                                                                                 SKEC burner is being used
                                                                                 >=127.27 ln(v)-110.87 NHV.
10/7/17..............  Marathon/          GBR (Texas City,   MPGF.............  NHV >=600 BTU/scf for the LH
                        Blanchard          TX).                                  burner, and NHV >=600 BTU/scf
                        Refining.                                                for LRGO burners.
9/19/17..............  Chalmette          Chalmette, LA....  Elevated multi-    >=1,000 BTU/scf NHV or LFL <=6.5
                        Refining.                             point flare.       vol%.
5/1/17...............  LACC.............  Lake Charles, LA.  2 MPGFs..........  >=1075 BTU/scf NHV for INDAIR
                                                                                 Burners; >=800 BTU/scf NHV for
                                                                                 LRGO only.
----------------------------------------------------------------------------------------------------------------

    (1) All flares must be operated such that the combustion zone gas 
net heating value (NHVcz) or the lower flammability in the combustion 
zone (LFLcz) as specified in Table 2 is met. Owners or operators must 
demonstrate compliance with the applicable NHVcz or LFLcz specified in 
Table 2 on a 15-minute block average. Owners or operators must 
calculate and monitor for the NHVcz or LFLcz according to the 
following:
    (a) Calculation of NHVcz
    (i) If an owner or operator elects to use a monitoring system 
capable of continuously measuring (i.e., at least once every 15 
minutes), calculating, and recording the individual component 
concentrations present in the flare vent gas, NHVvg shall be calculated 
using the following equation:

[GRAPHIC] [TIFF OMITTED] TN17SE18.002


Where:

NHVvg = Net heating value of flare vent gas, BTU/scf. Flare vent gas 
means all gas found just prior to the tip. This gas includes all 
flare waste gas (i.e., gas from facility operations that is directed 
to a flare for the purpose of disposing the gas), flare sweep gas, 
flare purge gas, and flare supplemental gas, but does not include 
pilot gas.
i = Individual component in flare vent gas.
n = Number of components in flare vent gas.
xi = Concentration of component i in flare vent gas, volume 
fraction.
NHVi = Net heating value of component i determined as the heat of 
combustion where the net enthalpy per mole of offgas is based on 
combustion at 25 degrees Celsius ([deg]C) and 1 atmosphere (or 
constant pressure) with water in the gaseous state from values 
published in the literature, and then the values converted to a 
volumetric basis using 20 [deg]C for ``standard temperature.'' Table 
3 summarizes component properties including net heating values.

    (ii) If the owner or operator uses a continuous net heating value 
monitor, the owner or operator may, at their discretion, install, 
operate, calibrate, and maintain a monitoring system capable of 
continuously measuring, calculating, and recording the hydrogen 
concentration in the flare vent gas. The owner or operator shall use 
the following equation to determine NHVvg for each sample measured via 
the net heating value monitoring system.

[GRAPHIC] [TIFF OMITTED] TN17SE18.003


    Where:

NHVvg = Net heating value of flare vent gas, BTU/scf.
NHVmeasured = Net heating value of flare vent gas stream as measured 
by the continuous net heating value monitoring system, BTU/scf.
xH2 = Concentration of hydrogen in flare vent gas at the time the 
sample was input into the net heating value monitoring system, 
volume fraction.
938 = Net correction for the measured heating value of hydrogen 
(1,212 -274), BTU/scf.

    (iii) For non-assisted flare burners, and the GBR LH burner, NHVvg 
= NHVcz. For assisted burners, such as the Marathon Garyville MPGF SKEC 
burners, and the Exxon Flare 26 gas-assisted burner, NHVcz is 
calculated using Equation 3.
[GRAPHIC] [TIFF OMITTED] TN17SE18.004

Where:

NHVcz = Net heating value of combustion

[[Page 46943]]

zone gas, BTU/scf.
NHVvg = Net heating value of flare vent gas for the 15-minute block 
period as determined according to (1)(a)(i), BTU/scf.
Qvg = Cumulative volumetric flow of flare vent gas during the 15-
minute block period, scf.
Qag = Cumulative volumetric flow of assist gas during the 15-minute 
block period, scf flow rate, scf.
NHVag = Net heating value of assist gas, BTU/scf; this is zero for 
air or for steam.

    (b) Calculation of LFLcz
    (i) The owner or operator shall determine LFLcz from compositional 
analysis data by using the following equation:
[GRAPHIC] [TIFF OMITTED] TN17SE18.005

Where:

LFLvg = Lower flammability limit of flare vent gas, volume percent 
(vol %).
n = Number of components in the vent gas.
i = Individual component in the vent gas.
[chi]i = Concentration of component i in the vent gas, vol %.
LFLi = Lower flammability limit of component i as determined using 
values published by the U.S. Bureau of Mines (Zabetakis, 1965), vol 
%. All inerts, including nitrogen, are assumed to have an infinite 
LFL (e.g., LFLN2 = [infin], so that [chi]N2/LFLN2 = 0). LFL values 
for common flare vent gas components are provided in Table 3.

    (ii) For non-assisted flare burners, LFLvg = LFLcz.
    (c) Calculation of Vtip
    For the ExxonMobil Flare 26, the owner or operator shall calculate 
the 15-minute block average Vtip by using the following equation:
[GRAPHIC] [TIFF OMITTED] TN17SE18.006

Where:

Vtip = Flare tip velocity, ft/sec.
Qvg = Cumulative volumetric flow of vent gas over 15-minute block 
average period, scf.
Area = Unobstructed area of the flare tip, square ft.
900 = Conversion factor, seconds per 15-minute block average.

    (d) For all flare systems specified in this document, the owner or 
operator shall install, operate, calibrate, and maintain a monitoring 
system capable of continuously measuring the volumetric flow rate of 
flare vent gas (Qvg), the volumetric flow rate of total assist steam 
(Qs), the volumetric flow rate of total assist air (Qa), and the 
volumetric flow rate of total assist gas (Qag).
    (i) The flow rate monitoring systems must be able to correct for 
the temperature and pressure of the system and output parameters in 
standard conditions (i.e., a temperature of 20 [deg]C 
(68[emsp14][deg]F) and a pressure of 1 atmosphere).
    (ii) Mass flow monitors may be used for determining volumetric flow 
rate of flare vent gas provided the molecular weight of the flare vent 
gas is determined using compositional analysis so that the mass flow 
rate can be converted to volumetric flow at standard conditions using 
the following equation:
[GRAPHIC] [TIFF OMITTED] TN17SE18.007

Where:

    Qvol = Volumetric flow rate, scf/sec.
    Qmass = Mass flow rate, pounds per sec.
    385.3 = Conversion factor, scf per pound-mole.
    MWt = Molecular weight of the gas at the flow monitoring 
location, pounds per pound-mole.

    (e) For each measurement produced by the monitoring system used to 
comply with (1)(a)(ii), the operator shall determine the 15-minute 
block average as the arithmetic average of all measurements made by the 
monitoring system within the 15-minute period.
    (f) The owner or operator must follow the accuracy and calibration 
procedures according to Table 4. Flares at refineries must meet the 
accuracy and calibration requirements in the Petroleum Refinery MACT at 
40 CFR 63.671(a)(1) and (4) and Table 13. Maintenance periods, 
instrument adjustments, or checks to maintain precision and accuracy 
and zero and span adjustments may not exceed 5 percent of the time the 
flare is receiving regulated material.

                                    Table 3--Individual Component Properties
----------------------------------------------------------------------------------------------------------------
                                                                  MW (pounds per
              Component                    Molecular formula        pound-mole)    NHV (BTU/scf)  LFL (volume %)
 
----------------------------------------------------------------------------------------------------------------
Acetylene...........................  C2H2......................           26.04           1,404             2.5
Benzene.............................  C6H6......................           78.11           3,591             1.3
1,2-Butadiene.......................  C4H6......................           54.09           2,794             2.0
1,3-Butadiene.......................  C4H6......................           54.09           2,690             2.0
iso-Butane..........................  C4H10.....................           58.12           2,957             1.8
n-Butane............................  C4H10.....................           58.12           2,968             1.8
cis-Butene..........................  C4H8......................           56.11           2,830             1.6
iso-Butene..........................  C4H8......................           56.11           2,928             1.8
trans-Butene........................  C4H8......................           56.11           2,826             1.7
Carbon Dioxide......................  CO2.......................           44.01               0         [infin]
Carbon Monoxide.....................  CO........................           28.01             316            12.5
Cyclopropane........................  C3H6......................           42.08           2,185             2.4
Ethane..............................  C2H6......................           30.07           1,595             3.0
Ethylene............................  C2H4......................           28.05           1,477             2.7
Hydrogen............................  H2........................            2.02         * 1,212             4.0
Hydrogen Sulfide....................  H2S.......................           34.08             587             4.0
Methane.............................  CH4.......................           16.04             896             5.0
Methyl-Acetylene....................  C3H4......................           40.06           2,088             1.7
Nitrogen............................  N2........................           28.01               0         [infin]
Oxygen..............................  O2........................           32.00               0         [infin]
Pentane+ (C5+)......................  C5H12.....................           72.15           3,655             1.4
Propadiene..........................  C3H4......................           40.06           2,066            2.16
Propane.............................  C3H8......................           44.10           2,281             2.1
Propylene...........................  C3H6......................           42.08           2,150             2.4

[[Page 46944]]

 
Water...............................  H2O.......................           18.02               0         [infin]
----------------------------------------------------------------------------------------------------------------
* The theoretical net heating value for hydrogen is 274 BTU/scf, but for the purposes of the flare requirement
  in this subpart, a net heating value of 1,212 BTU/scf shall be used.


                                 Table 4--Accuracy and Calibration Requirements
----------------------------------------------------------------------------------------------------------------
               Parameter                     Accuracy requirements              Calibration requirements
----------------------------------------------------------------------------------------------------------------
Flare Vent Gas Flow Rate..............  20 percent of flow  Performance evaluation biennially (every
                                         rate at velocities ranging      2 years) and following any period of
                                         from 0.1 to 1 foot per second.  more than 24 hours throughout which the
                                        5 percent of flow    flow rate exceeded the maximum rated
                                         rate at velocities greater      flow rate of the sensor, or the data
                                         than 1 foot per second.         recorder was off scale. Checks of all
                                                                         mechanical connections for leakage
                                                                         monthly. Visual inspections and checks
                                                                         of system operation every 3 months,
                                                                         unless the system has a redundant flow
                                                                         sensor.
                                                                        Select a representative measurement
                                                                         location where swirling flow or
                                                                         abnormal velocity distributions due to
                                                                         upstream and downstream disturbances at
                                                                         the point of measurement are minimized.
Flow Rate for All Flows Other Than      5 percent over the  Conduct a flow sensor calibration check
 Flare Vent Gas.                         normal range of flow measured   at least biennially (every 2 years);
                                         or 1.9 liters per minute (0.5   conduct a calibration check following
                                         gallons per minute),            any period of more than 24 hours
                                         whichever is greater, for       throughout which the flow rate exceeded
                                         liquid flow.                    the manufacturer's specified maximum
                                                                         rated flow rate or install a new flow
                                                                         sensor.
                                        5 percent over the  At least quarterly, inspect all
                                         normal range of flow measured   components for leakage, unless the
                                         or 280 liters per minute (10    continuous parameter monitoring system
                                         cubic feet per minute),         (CPMS) has a redundant flow sensor.
                                         whichever is greater, for gas
                                         flow.
                                        5 percent over the  Record the results of each calibration
                                         normal range measured for       check and inspection.
                                         mass flow.                     Locate the flow sensor(s) and other
                                                                         necessary equipment (such as
                                                                         straightening vanes) in a position that
                                                                         provides representative flow; reduce
                                                                         swirling flow or abnormal velocity
                                                                         distributions due to upstream and
                                                                         downstream disturbances.
Pressure..............................  5 percent over the  Review pressure sensor readings at least
                                         normal range measured or 0.12   once a week for straight-line
                                         kilopascals (0.5 inches of      (unchanging) pressure and perform
                                         water column), whichever is     corrective action to ensure proper
                                         greater.                        pressure sensor operation if blockage
                                                                         is indicated.
                                                                        Performance evaluation annually and
                                                                         following any period of more than 24
                                                                         hours throughout which the pressure
                                                                         exceeded the maximum rated pressure of
                                                                         the sensor, or the data recorder was
                                                                         off scale. Checks of all mechanical
                                                                         connections for leakage monthly. Visual
                                                                         inspection of all components for
                                                                         integrity, oxidation, and galvanic
                                                                         corrosion every 3 months, unless the
                                                                         system has a redundant pressure sensor.
                                                                        Select a representative measurement
                                                                         location that minimizes or eliminates
                                                                         pulsating pressure, vibration, and
                                                                         internal and external corrosion.
Net Heating Value by Calorimeter......  2 percent of span.  Calibration requirements--follow
                                                                         manufacturer's recommendations at a
                                                                         minimum.
                                                                        Temperature control (heated and/or
                                                                         cooled as necessary) the sampling
                                                                         system to ensure proper year-round
                                                                         operation.
                                                                        Where feasible, select a sampling
                                                                         location at least 2 equivalent
                                                                         diameters downstream from and 0.5
                                                                         equivalent diameters upstream from the
                                                                         nearest disturbance. Select the
                                                                         sampling location at least 2 equivalent
                                                                         duct diameters from the nearest control
                                                                         device, point of pollutant generation,
                                                                         air in-leakages, or other point at
                                                                         which a change in the pollutant
                                                                         concentration or emission rate occurs.
Net Heating Value by Gas Chromatograph  As specified in Performance     Follow the procedure in PS 9 of 40 CFR
                                         Standard (PS) 9 of 40 CFR       part 60, appendix B, except that a
                                         part 60, appendix B.            single daily mid-level calibration
                                                                         check can be used (rather than
                                                                         triplicate analysis), the multi-point
                                                                         calibration can be conducted quarterly
                                                                         (rather than monthly), and the sampling
                                                                         line temperature must be maintained at
                                                                         a minimum temperature of 60 [deg]C
                                                                         (rather than 120 [deg]C).
Hydrogen Analyzer.....................  2 percent over the  Specify calibration requirements in your
                                         concentration measured, or      site specific CPMS monitoring plan.
                                         0.1 volume, percent,            Calibration requirements--follow
                                         whichever is greater.           manufacturer's recommendations at a
                                                                         minimum.
                                                                        Specify the sampling location at least 2
                                                                         equivalent duct diameters from the
                                                                         nearest control device, point of
                                                                         pollutant generation, air in-leakages,
                                                                         or other point at which a change in the
                                                                         pollutant concentration occurs.
----------------------------------------------------------------------------------------------------------------

    (2) The flare system shall be operated with a flame present at all 
times when in use. Additionally, each stage that cross-lights must have 
at least two pilots with a continuously lit pilot flame, except for 
Chalmette's No. 1 Flare, which has one pilot for each stage, excluding 
stages 8A and 8B. Each pilot flame must be continuously monitored by a 
thermocouple or any other equivalent device used to detect the presence 
of a flame. The time, date, and duration of any complete loss of pilot 
flame on any of the burners must be recorded. Each monitoring device 
must be maintained or replaced at a frequency in accordance with the 
manufacturer's specifications. The ExxonMobil flare, Flare 26, and 
GBR's LH flare must meet the requirements in the Petroleum Refinery 
MACT at 40 CFR 63.670(b) instead of the requirements herein in section 
(2).
    (3) Flares at refineries shall comply with the Petroleum Refinery 
MACT requirements of 40 CFR 63.670(h). For LACC, LLC's MPGFs, the flare 
system shall be operated with no visible emissions except for periods 
not to exceed a total of 5 minutes during any

[[Page 46945]]

2 consecutive hours. A video camera that is capable of continuously 
recording (i.e., at least one frame every 15 seconds with time and date 
stamps) images of the flare flame and a reasonable distance above the 
flare flame at an angle suitable for visible emissions observations 
must be used to demonstrate compliance with this requirement. For 
LACC's enclosed ground flare, LACC must install a video camera that is 
capable of continuously recording (i.e., at least one frame every 15 
seconds with time and date stamps) the stack exhaust exit at a 
reasonable distance and at an angle suitable for visible emissions 
observation in order to demonstrate compliance with this requirement. 
The owner or operator must provide real-time video surveillance camera 
output to the control room or other continuously manned location where 
the video camera images may be viewed at any time.
    (4) For the MPGFs and Chalmette's No. 1 Flare, the owner or 
operator of a flare system shall install and operate pressure 
monitor(s) on the main flare header, as well as a valve position 
indicator monitoring system capable of monitoring and recording the 
position for each staging valve to ensure that the flare operates 
within the range of tested conditions or within the range of the 
manufacturer's specifications. Flares at refineries must meet the 
accuracy and calibration requirements in the Petroleum Refinery MACT at 
40 CFR 63.671(a)(1) and (4) and Table 13. The pressure monitor at LACC 
shall meet the accuracy and calibration requirements in Table 4. 
Maintenance periods, instrument adjustments or checks to maintain 
precision and accuracy, and zero and span adjustments may not exceed 5 
percent of the time the flare is receiving regulated material.
    (5) Recordkeeping Requirements
    (a) All data must be recorded and maintained for a minimum of 3 
years or for as long as required under applicable rule subpart(s), 
whichever is longer.
    (6) Reporting Requirements
    (a) The information specified in section III(6)(b) and (c) below 
must be reported in the timeline specified by the applicable rule 
subpart(s) for which the flare will control emissions.
    (b) Owners or operators shall include the final AMEL operating 
requirements for each flare in their initial Notification of Compliance 
status report.
    (c) The owner or operator shall notify the Administrator of periods 
of excess emissions in their Periodic Reports. The owner or operator of 
refinery flares shall meet the reporting requirements in the Petroleum 
Refinery MACT in 40 CFR 63.655(g)(11)(i)-(iii), except that the 
applicable alternative operating conditions listed in Table 2 apply 
instead of the operating limits specified in 40 CFR 63.670(d) through 
(f). In addition, for refinery flares that are MPGFs, notification 
shall also include records specified in section (iv)-(v) below. For 
LACC MPGFs, the notification shall include the records specified in 
section (i)-(v) below.
    (i) Records of each 15-minute block for all flares during which 
there was at least 1 minute when regulated material was routed to the 
flare and a complete loss of pilot flame on a stage of burners 
occurred, and for all flares, records of each 15-minute block during 
which there was at least 1 minute when regulated material was routed to 
the flare and a complete loss of pilot flame on an individual burner 
occurred.
    (ii) Records of visible emissions events (including the time and 
date stamp) that exceed more than 5 minutes in any 2-hour consecutive 
period.
    (iii) Records of each 15-minute block period for which an 
applicable combustion zone operating condition (i.e., NHVcz or LFLcz) 
is not met for the flare when regulated material is being combusted in 
the flare. Indicate the date and time for each period, the NHVcz and/or 
LFLcz operating parameter for the period, the type of monitoring system 
used to determine compliance with the operating parameters (e.g., gas 
chromatograph or calorimeter), and also indicate which high-pressure 
stages were in use.
    (iv) Records of when the pressure monitor(s) on the main flare 
header show the flare burners are operating outside the range of tested 
conditions or outside the range of the manufacturer's specifications. 
Indicate the date and time for each period, the pressure measurement, 
the stage(s) and number of flare burners affected, and the range of 
tested conditions or manufacturer's specifications.
    (v) Records of when the staging valve position indicator monitoring 
system indicates a stage of the flare should not be in operation and is 
or when a stage of the flare should be in operation and is not. 
Indicate the date and time for each period, whether the stage was 
supposed to be open, but was closed, or vice versa, and the stage(s) 
and number of flare burners affected.

    Dated: September 11, 2018.
Panagiotis Tsirigotis,
Director, Office of Air Quality Planning and Standards.
[FR Doc. 2018-20148 Filed 9-14-18; 8:45 am]
BILLING CODE 6560-50-P



                                                                         Federal Register / Vol. 83, No. 180 / Monday, September 17, 2018 / Notices                                            46939

                                               of the protest or intervention to the                   Refining, LLC; and LACC, LLC to                       LRGO linear relief gas oxidizer
                                               Federal Energy Regulatory Commission,                   operate certain flares at the refineries              MPGF multi-point ground flare
                                               888 First Street NE, Washington, DC                     and a chemical plant, as specified in                 NESHAP national emission standards for
                                                                                                                                                               hazardous air pollutants
                                               20426.                                                  this notice, is effective on September 17,            NHV net heating value
                                                  This filing is accessible on-line at                 2018.                                                 NHVcz net heating value of combustion
                                               http://www.ferc.gov, using the eLibrary                 ADDRESSES: The Environmental                            zone gas
                                               link and is available for electronic                    Protection Agency (EPA) has established               NHVvg net heating value of flare vent gas
                                               review in the Commission’s Public                       a docket for this action under Docket ID              NSPS new source performance standards
                                               Reference Room in Washington, DC.                       No. EPA–HQ–OAR–2014–0738. All                         OAQPS Office of Air Quality Planning and
                                               There is an eSubscription link on the                                                                           Standards
                                                                                                       documents in the docket are listed on                 scf standard cubic feet
                                               website that enables subscribers to                     the https://www.regulations.gov                       SKEC steam-assisted kinetic energy
                                               receive email notification when a                       website. Although listed, some                          combustor
                                               document is added to a subscribed                       information is not publicly available,                TCEQ Texas Commission on Environmental
                                               docket(s). For assistance with any FERC                 e.g., confidential business information                 Quality
                                               Online service, please email                            (CBI) or other information whose                      VOC volatile organic compounds
                                               FERCOnlineSupport@ferc.gov, or call                     disclosure is restricted by statute.                    Organization of This Document. The
                                               (866) 208–3676 (toll free). For TTY, call               Certain other material, such as                       information in this notice is organized
                                               (202) 502–8659.                                         copyrighted material, is not placed on                as follows:
                                                  Comment Date: 5:00 p.m. Eastern                      the internet and will be publicly
                                               Time on September 28, 2018.                                                                                   I. Background
                                                                                                       available only in hard copy form.                        A. Summary
                                                 Dated: September 11, 2018.                            Publicly available docket materials are                  B. Regulatory Flare Requirements
                                               Kimberly D. Bose,                                       available either electronically through               II. Summary of Public Comments on the
                                               Secretary.                                              http://www.regulations.gov or in hard                       AMEL Requests
                                                                                                       copy at EPA Docket Center, EPA WJC                    III. AMEL for the Flares
                                               [FR Doc. 2018–20101 Filed 9–14–18; 8:45 am]
                                               BILLING CODE 6717–01–P
                                                                                                       West Building, Room Number 3334,                      I. Background
                                                                                                       1301 Constitution Ave. NW,
                                                                                                       Washington, DC. The Public Reading                    A. Summary
                                                                                                       Room hours of operation are 8:30 a.m.                    In a Federal Register notice dated
                                               ENVIRONMENTAL PROTECTION
                                                                                                       to 4:30 p.m. Eastern Standard Time                    April 25, 2018, the EPA provided public
                                               AGENCY
                                                                                                       (EST), Monday through Friday. The                     notice and solicited comment on the
                                               [EPA–HQ–OAR–2014–0738 and EPA–HQ–                       telephone number for the Public                       requests under the CAA from
                                               OAR–2010–0682; FRL–9983–26–OAR]                         Reading Room is (202) 566–1744, and                   ExxonMobil Corporation; Marathon
                                                                                                       the telephone number for the Docket                   Petroleum Company, LP (for itself and
                                               Notice of Final Approval for an                         Center is (202) 566–1742.                             on behalf of its subsidiary, Blanchard
                                               Alternative Means of Emission                                                                                 Refining, LLC’s); and Chalmette
                                                                                                       FOR FURTHER INFORMATION CONTACT: For
                                               Limitation at ExxonMobil Corporation;                                                                         Refining, LLC for the operation of flares
                                               Marathon Petroleum Company, LP (for                     questions about this final action, contact
                                                                                                       Ms. Angie Carey, Sector Policies and                  and MPGFs at several refineries in
                                               Itself and on Behalf of Its Subsidiary,                                                                       Texas and Louisiana, and from LACC,
                                               Blanchard Refining, LLC); Chalmette                     Programs Division (E143–01), Office of
                                                                                                       Air Quality Planning and Standards,                   LLC to operate flares at a chemical plant
                                               Refining, LLC; and LACC, LLC                                                                                  in Louisiana (see 83 FR 18034). This
                                                                                                       U.S. Environmental Protection Agency,
                                               AGENCY: Environmental Protection                        Research Triangle Park, North Carolina                action solicited comment on all aspects
                                               Agency (EPA).                                           27711; telephone number: (919) 541–                   of the AMEL requests, including the
                                               ACTION: Notice; final approval.                         2187; fax number: (919) 541–0516; and                 operating conditions specified in that
                                                                                                       email address: carey.angela@epa.gov.                  action that are necessary to achieve a
                                               SUMMARY:    This notice announces our                   SUPPLEMENTARY INFORMATION: Preamble                   reduction in emissions of volatile
                                               approval of the Alternative Means of                    acronyms and abbreviations. We use                    organic compounds and organic
                                               Emission Limitation (AMEL) requests                     multiple acronyms and terms in this                   hazardous air pollutants at least
                                               under the Clean Air Act (CAA)                           preamble. While this list may not be                  equivalent to the reduction in emissions
                                               submitted from ExxonMobil                               exhaustive, to ease the reading of this               required by various standards in 40 CFR
                                               Corporation; Marathon Petroleum                         preamble and for reference purposes,                  parts 60, 61, and 63 that apply to
                                               Company, LP (for itself and on behalf of                the EPA defines the following terms and               emission sources that would be
                                               its subsidiary, Blanchard Refining, LLC);               acronyms here:                                        controlled by these flares and MPGFs.
                                               and Chalmette Refining, LLC to operate                                                                        These standards incorporate the flare
                                               flares and multi-point ground flares                    AMEL alternative means of emission                    design and operating requirements in 40
                                               (MPGFs) at several refineries in Texas                    limitation
                                                                                                       BTU/scf British thermal units per standard
                                                                                                                                                             CFR part 60 and 63 General Provisions
                                               and Louisiana, and from LACC, LLC to                      cubic foot                                          (i.e., 40 CFR 60.18(b) and 63.11(b)) into
                                               operate flares at a chemical plant in                   CAA Clean Air Act                                     the individual new source performance
                                               Louisiana. This approval notice                         CBI confidential business information                 standards (NSPS) and maximum
                                               specifies the operating conditions and                  CFR Code of Federal Regulations                       achievable control technology (MACT)
                                               monitoring, recordkeeping, and                          EPA Environmental Protection Agency                   subparts, except for the Petroleum
                                               reporting requirements that these                       Eqn equation                                          Refinery MACT, 40 CFR part 63, subpart
daltland on DSKBBV9HB2PROD with NOTICES




                                               facilities must follow to demonstrate                   g/mol grams per gram mole                             CC, which specifies its flare
                                               compliance with the approved AMEL.                      HAP hazardous air pollutants                          requirements within the subpart (i.e., 40
                                                                                                       HP high pressure
                                               DATES: The approval of the AMEL
                                                                                                       LFL lower flammability limit
                                                                                                                                                             CFR 63.670). Four of the requests are for
                                               requests from ExxonMobil Corporation;                   LFLcz lower flammability limit of                     flares located at petroleum refineries,
                                               Marathon Petroleum Company, LP (for                       combustion zone gas                                 while the request from LACC, LLC is for
                                               itself and on behalf of its subsidiary,                 LFLvg lower flammability limit of flare vent          a flare design at a chemical
                                               Blanchard Refining, LLC); Chalmette                       gas                                                 manufacturing facility. None of the


                                          VerDate Sep<11>2014   17:47 Sep 14, 2018   Jkt 244001   PO 00000   Frm 00030   Fmt 4703   Sfmt 4703   E:\FR\FM\17SEN1.SGM   17SEN1


                                               46940                         Federal Register / Vol. 83, No. 180 / Monday, September 17, 2018 / Notices

                                               flares located at petroleum refineries                                     specified in the flare AMEL framework                                                Texas, are seeking AMELs to operate
                                               can meet the flare tip velocity limits in                                  set forth in the Petroleum Refinery                                                  their flares only during periods of
                                               the Petroleum Refinery MACT, 40 CFR                                        MACT at 40 CFR 63.670(r) to support                                                  startup, shutdown, upsets, and
                                               part 63, subpart CC. In addition, flares                                   their AMEL requests. LACC provided                                                   emergency events. Chalmette Refining,
                                               at these refineries and at LACC’s                                          the information specified in the flare                                               LLC in Chalmette, Louisiana, is seeking
                                               chemical plant that are subject to other                                   AMEL framework finalized on April 21,                                                an AMEL to operate its flare, No. 1
                                               40 CFR part 60 and 63 standards cannot                                     2016 (81 FR 23486), to support its                                                   Flare, during periods of upset and
                                               meet the flare tip velocity limits                                         AMEL request. The ExxonMobil                                                         emergency events. LACC, LLC is seeking
                                               contained in the applicable General                                        Corporation Baytown Refinery in                                                      an AMEL to operate flares at its
                                               Provisions to 40 CFR part 60 and 63.
                                                                                                                          Baytown, Texas, is seeking an AMEL to                                                chemical plant in Lake Charles,
                                                  This action provides a summary of the
                                               comments received as part of the public                                    operate a gas-assisted flare, Flare 26,                                              Louisiana, during startups, shutdowns,
                                               review process, our response to those                                      during periods of startup, shutdown,                                                 upsets, and emergency events. See Table
                                               comments, and our approval of these                                        upsets, and emergency events, as well as                                             1 for a list of regulations, by subparts,
                                               AMEL requests.                                                             during fuel gas imbalance events.                                                    that each refinery and chemical plant
                                                                                                                          Marathon Petroleum Company, LP’s                                                     has identified as applicable to the flares
                                               B. Regulatory Flare Requirements                                           Garyville, Louisiana Refinery, and                                                   described above.
                                                 ExxonMobil, Marathon, Blanchard,                                         Blanchard Refining, LLC’s Galveston
                                               and Chalmette provided the information                                     Bay Refinery (GBR) in Texas City,
                                                             TABLE 1—SUMMARY OF APPLICABLE RULES THAT MAY APPLY TO STREAMS CONTROLLED BY FLARES
                                                  Applicable rules      Exxon Mobil              Marathon               Blanchard
                                                      with vent          Baytown,                                                             Chalmette                                   Rule citation from title 40 CFR                  Provisions for alternative means
                                                                                                 Garyville,              Refining                                       LACC
                                                  streams going to        Texas                                                               No. 1 Flare                                  that allow for use of a flare                        of emission limitation
                                                                                                 LA MPGF               GBR MPGF
                                                  control device(s)      Flare 26

                                               NSPS Subpart VV ....     ....................            x                      x              ....................   ................   60.482–10(d) ................................      60.484(a)–(f).
                                               NSPS Subpart VVa ..      ....................            x                      x              ....................          x           60.482–10a(d) ..............................       60.484a(a)–(f).
                                               NSPS Subpart NNN         ....................            x                      x                       x                    x           60.662(b) ......................................   CAA section 111(h)(3).
                                               NSPS Subpart QQQ         ....................            x                      x              ....................   ................   60.692–5(c) ..................................     42 U.S.C. 7411(h)(3).
                                               NSPS Subpart RRR         ....................            x                      x              ....................          x           60.702(b) ......................................   CAA section 111(h)(3).
                                               NSPS Subpart Kb ....     ....................            x                      x              ....................          x           60.112b(a)(3)(ii) ...........................      60.114b.
                                               NESHAP Subpart V         ....................            x                      x              ....................          x           61.242–11(d) ................................      40 CFR 63.6(g); 42 U.S.C.
                                                                                                                                                                                                                                             7412(h)(3).
                                               NESHAP Subpart J ..      ....................    ....................   ....................   ....................         x            61.242–11(d) ................................      40 CFR 63.6(g); 42 U.S.C.
                                                                                                                                                                                                                                             7412(h)(3).
                                               NESHAP Subpart Y         ....................            x                      x              ....................   ................   61.271–(c)(2) ...............................      40 CFR 63.6(g); 40 CFR 61.273;
                                                                                                                                                                                                                                             42 U.S.C. 7412(h)(3).
                                               NESHAP Subpart BB        ....................            x                      x              ....................   ................   61.302(c) ......................................   40 CFR 63.6(g); 42 U.S.C.
                                                                                                                                                                                                                                             7412(h)(3).
                                               NESHAP Subpart FF        ....................            x                      x              ....................         x            61.349(a)(2) .................................     61.353(a); also see 61.12(d).
                                               NESHAP Subpart F         ....................            x                      x              ....................         x            63.103(a) ......................................   63.6(g); 42 U.S.C. 7412(h)(3).
                                               NESHAP Subpart G         ....................            x                      x              ....................         x            63.113(a)(1)(i), 63.116(a)(2),                     63.6(g); 42 U.S.C. 7412(h)(3).
                                                                                                                                                                                          63.116(a)(3), 63.119(e),
                                                                                                                                                                                          63.120(e)(1) through (4),
                                                                                                                                                                                          63.126(b)(2)(i), 63.128(b),
                                                                                                                                                                                          63.139(c)(3), 63.139(d)(3),
                                                                                                                                                                                          63.145(j).
                                               NESHAP    Subpart   H    ....................             x                      x             ....................          x           63.172(d), 63.180(e) ....................          63.177; 42 U.S.C. 7412(h)(3).
                                               NESHAP    Subpart   SS   ....................             x                      x             ....................          x           63.982(b) ......................................   CAA section 112(h)(3).
                                               NESHAP    Subpart   CC            x                       x                      x                      x             ................   63.643(a)(1) .................................     63.670(r).
                                               NESHAP    Subpart   UU   ....................    ....................   ....................   ....................          x           63.1034 ........................................   63.1021(a)–(d).
                                               NESHAP    Subpart   YY   ....................    ....................   ....................   ....................          x           Table 7 to 63.1103(e) cross-ref-                   63.1113.
                                                                                                                                                                                          erences to NESHAP subpart
                                                                                                                                                                                          SS above.
                                               NESHAP Subpart           ....................            x                      x              ....................   ................   63.2378(a),63.2382, 63.2398 ......                 63.6(g); 42 U.S.C. 7412(h)(3).
                                                EEEE.



                                                  The provisions for the NSPS and                                         notice and opportunity for comment,1 it                                              regulatory provisions allowing sources
                                               National Emission Standards for                                            is established to the Administrator’s                                                to request an AMEL.
                                               Hazardous Air Pollutants (NESHAP)                                          satisfaction that such an AMEL will
                                                                                                                                                                                                               II. Summary of Public Comments on the
                                               cited in Table 1 that ensure flares meet                                   achieve emission reductions at least
                                                                                                                                                                                                               AMEL Requests
                                               certain specific requirements when used                                    equivalent to the reductions required
                                               to satisfy the requirements of the NSPS                                    under the CAA section 111(h)(1) or                                                      The EPA received four public
                                               or NESHAP were established as work                                         112(h)(1) standard. As noted in Table 1,                                             comments on this action. Specifically,
                                               practice standards pursuant to CAA                                         many of the NSPS and NESHAP in the                                                   the EPA received suggested changes and
                                               sections 111(h)(1) or 112(h)(1). For                                       table above also include specific                                                    clarifications from LACC, LLC,
daltland on DSKBBV9HB2PROD with NOTICES




                                               standards established according to these                                                                                                                        Marathon Petroleum Company, LP (for
                                               provisions, CAA sections 111(h)(3) and                                       1 CAA section 111(h)(3) specifically requires that
                                                                                                                                                                                                               itself and on behalf of its subsidiary,
                                               112(h)(3) allow the EPA to permit the                                                                                                                           Blanchard Refining, LLC), and
                                                                                                                          the EPA provide an opportunity for a public
                                               use of an AMEL by a source if, after                                       hearing. The EPA provided an opportunity for a                                       ExxonMobil Corporation. The EPA also
                                                                                                                          public hearing in the April 25, 2018, Federal                                        received one comment that does not
                                                                                                                          Register action. However, no public hearing was                                      mention any of the AMEL requests at
                                                                                                                          requested.                                                                           issue and is, therefore, outside the scope


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                                                                         Federal Register / Vol. 83, No. 180 / Monday, September 17, 2018 / Notices                                            46941

                                               of the action. As discussed in more                     but not for the LRGO burners, given that              natural gas that corresponds to an
                                               detail below, we have modified or                       the LRGO burners do not have steam                    NHV of 920 BTU/scf listed in 40 CFR
                                               otherwise clarified certain operating                   assist.                                               63.670(j)(5).
                                               conditions in response to comments.2                       Response: The EPA acknowledges                        Response: We agree and are
                                               All of the comments within the scope of                 that the April notice did not reflect                 specifying the molecular weight of
                                               the AMEL requests were supportive of                    Marathon Petroleum Company, LP’s                      pipeline natural gas as 16.85 grams per
                                               the EPA approving the AMEL requests,                    supplemental request for the Garyville                gram mole (g/mol). It would be
                                               and none of the comments raised issues                  MPGF to maintain separate burner                      burdensome for Exxon to take samples
                                               with the EPA’s authority to approve                     limits such that the SKEC burners                     of natural gas to determine molecular
                                               these AMEL requests under the CAA.                      would meet the NHVcz target from the                  weight, when very little changes in
                                               None of the commenters asserted that                    SKEC equation and the LRGO burners                    molecular weight are expected.
                                               the EPA lacked authority to approve the                 would meet 600 British thermal units                  Therefore, we are specifying the
                                               AMEL requests or that the AMEL                          per standard cubic feet (BTU/scf). We                 molecular weight of natural gas of 16.85
                                               requests would not achieve at least                     discussed with Marathon its                           can be used. This molecular weight is
                                               equivalent emissions reductions as                      supplemental request upon receiving                   based on our default natural gas
                                               flares that meet the standards in the                   the comment. As we explained in that                  composition that was used to determine
                                               General Provisions or in the Petroleum                  discussion, based on our review of the                the net heating value in 40 CFR 63.670.
                                               Refinery MACT at 40 CFR 63.670(r).                      information provided by Marathon, the                    Comment: ExxonMobil Corporation
                                                  Comment: LACC, LLC commented                         steam-to-vent gas ratio for the SKEC                  commented that the accuracy and
                                               that the monitoring requirement in                      burners is not high enough to                         calibration requirements in section (1)(f)
                                               section (3) to install a video camera                   significantly affect the NHVcz during the             of the initial Federal Register document
                                               capable of continuously recording (i.e.,                high pressure flaring scenario.                       should apply only to flares at chemical
                                               at least one frame every 15 seconds with                Therefore, we conclude that the burner                plants seeking AMEL approval since
                                               time and date stamps) images of the                     requirements as set out in the April 25,              flares such as Exxon’s Flare 26 is
                                               flare flame at a reasonable distance and                2018, AMEL document are appropriate.                  already subject to the accuracy and
                                               suitable angle, will work for their                     Marathon concurred with this                          calibration requirements in the
                                               MPGF, but not for their enclosed ground                 conclusion in an email response after                 Petroleum Refinery MACT at 40 CFR
                                               flare. LACC stated that it is not                       the comment period closed (available in               63.671(a)(1) and (4) and Table 13.
                                               technically feasible to install a video                 Docket ID No. EPA–HQ–OAR–2014–                           Response: We agree and have clarified
                                               camera and monitor the flare flame                      0738 and EPA–HQ–OAR–2010–0682).                       in section (1)(f) below that the accuracy
                                               within the enclosed ground flare.                          Comment: Marathon Petroleum                        and calibration requirements listed in
                                               Alternatively, LACC stated that it can                  Company, LP commented that the                        Table 4 do not apply to refinery flares
                                               monitor for the presence of visible                     requirement should be NHVvg = NHVcz                   subject to requirements at 40 CFR
                                               emissions from the enclosed ground                      with a limit of ≥600 BTU/scf for the LH               63.671(a)(1) and (4) and Table 13 of 40
                                               flare by using a video camera to monitor                burner, and NHVcz ≥600 BTU/scf for                    CFR part 63, subpart CC.
                                               at the exit of the stack exhaust.                       LRGO burners. Marathon notes that, as                    Comment: ExxonMobil Corporation
                                                  Response: We agree that, although the                explained in its February 2, 2018, and                commented that the Flare 26 follows the
                                               camera would not be able to directly                    March 27, 2018, supplemental letters,                 Petroleum Refinery MACT requirement
                                               monitor visible emissions from the flare                since the LH burner is air-assisted,                  at 40 CFR part 63, subpart CC, for pilot
                                               flame because of the enclosure,                         therefore, the LH burner limitations                  flame operations and does not use cross-
                                               conducting visible emissions                            provided in its request correspond to                 lighting for the flare operation. They
                                               observations at the stack would be a                    the NHVvg and not the NHVcz. Marathon                 stated that the EPA should clarify in
                                               reliable indicator of compliance with                   further notes that the Petroleum                      section (2) that the Flare 26 is only
                                               the requirements in section (3) below.                  Refinery requirements at 40 CFR                       required to maintain flare pilots per the
                                               Therefore, we accept this alternative                   63.670(m)(1) states that NHVvg = NHVcz                Petroleum Refinery MACT requirements
                                               and have made the appropriate change                    when there is no premix assist air flow.              in 40 CFR 63.670(b).
                                               in section (3) below.                                      Response: For the reasons provided in                 Response: We agree that the
                                                  Comment: Marathon Petroleum                          Marathon’s comment, we agree that for                 requirements in section (2), which apply
                                               Company, LP commented that the                          the LH burner, which is perimeter air                 to flares that cross light, should not
                                               operating conditions in Table 2 do not                  assisted and not pre-mix air assisted, the            apply to Flare 26 because it does not use
                                               reflect what they requested in their                    NHVvg equals NHVcz. We, therefore,                    cross-lighting. We have made this
                                               AMEL for the MPGF at their Garyville                    made this change in Table 2 below.                    change in section (2) below.
                                               refinery. They stated that they needed                     Comment: ExxonMobil Corporation                       Comment: ExxonMobil Corporation
                                               separate NHVcz limits for the pressure-                 commented on a typographical                          commented that the EPA should clarify
                                               assisted linear relief gas oxidizers                    correction in Table 2 for the Baytown,                which reporting requirements apply to
                                               (LRGO burners) and the steam-assisted                   Texas, Flexicoker Flare 26. The                       the Flare 26 in section (6) and clarify
                                               steam kinetic energy combustors (SKEC                   proposed alternative operating                        that the reporting requirements for the
                                               burners) when both are being used                       condition was listed as ≥270 BTU/scf                  flare tip velocity and NHVcz are
                                               simultaneously. Marathon explained                      NHVcz and velocity of <361 feet per                   applicable when regulated material is
                                               that the SKEC burners would have a                      second (ft/sec). However, the                         routed to the flare for at least 15
                                               considerably different NHVcz value                      performance test results for the Flare 26             minutes.
                                               because of steam assist. This is because                demonstrate that the destruction                         Response: While we believe that the
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                                               the steam assist is included in the                     efficiency met 98 percent at 361 ft/sec.              records required in section (6)(c) are
                                               NHVcz calculation for the SKEC burners,                    Response: We accept this correction                essentially the same as the reporting
                                                                                                       and made the change in Table 2 to ≤361                requirements in Petroleum Refinery
                                                 2 As explained below, we have clarified the
                                                                                                       ft/sec.                                               NESHAP, 40 CFR part 63, subpart CC,
                                               reporting requirements for Exxon’s Flare 26 in             Comment: ExxonMobil Corporation                    section (6)(c) requires additional records
                                               response to a comment by Exxon. We have similarly
                                               clarified Marathon’s Garyville’s and GBR’s MPGFs        commented that the EPA should include                 related to the operation of MPGFs,
                                               reporting requirements as a result of this comment.     a default molecular weight for pipeline               which do not apply to Flare 26. Further,


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                                               46942                            Federal Register / Vol. 83, No. 180 / Monday, September 17, 2018 / Notices

                                               we agree that the operating limits for                          (6)(c) to all the flares covered in this                  III. AMEL for the Flares
                                               NHVcz and Vtip apply whenever                                   notice. Specifically, section (6)(c) below                  Based upon our review of the AMEL
                                               regulated material is routed to the flares                      provides that flares at refineries must                   requests and the comments received
                                               for at least 15 minutes, as specified by                        meet the requirements in the Petroleum                    through the public comment period, we
                                               40 CFR part 63, subpart CC; Therefore,                          Refinery MACT in 40 CFR                                   are approving these AMEL requests and
                                               we are requiring that Flare 26 comply                           63.655(g)(11)(i)–(iii), except that the                   are establishing operating conditions for
                                               with the reporting requirements in the                          applicable alternative operating                          the flares at issue. The AMEL and the
                                               Petroleum Refinery NESHAP, 40 CFR                               conditions listed in Table 2 apply                        associated operating conditions are
                                               part 63, subpart CC, instead of section                         instead of the operating limits specified                 specified in Table 2 and accompanying
                                               (6) as part of this AMEL approval.                              in 40 CFR 63.670(d) through (f). In                       paragraphs. These operating conditions
                                               However, MPGFs located at petroleum                             addition, for refinery flares that are                    will ensure that these flares will achieve
                                               refineries must comply with the                                 MPGFs, notification shall also include                    emission reductions at least equivalent
                                               additional reporting requirements for                           records specified in section (6)(c)(iv)–                  to flares complying with the flare
                                               MPGFs in (6)(c)(iv) and (v). To avoid                           (v). For LACC MPGFs, the notification                     requirements under the applicable
                                               other potential confusion, we are                               shall include the records specified in                    NESHAP and NSPS identified in
                                               clarifying the applicability of section                         section (6)(c)(i)–(v).                                    Table 1.

                                                                                                         TABLE 2—ALTERNATIVE OPERATING CONDITIONS
                                                    AMEL                      Company                 Affected facilities           Flare type(s)                         Alternative operating conditions
                                                  submitted

                                               11/7/17 ...........      ExxonMobil ............      Baytown, TX                Elevated gas-assist         ≥270 BTU/scf NHVcz and velocity ≤361 (ft/sec).
                                                                                                       Flexicoker Flare           flare.
                                                                                                       26.
                                               10/7/17 ...........      Marathon ................    Garyville, LA ..........   2 MPGFs ................    When both SKEC and LRGO burners are being used, the
                                                                                                                                                              higher of ≥600 BTU/scf NHVcz or ≥127.27 ln(vvg)¥110.87
                                                                                                                                                              NHVcz. When only the SKEC burner is being used
                                                                                                                                                              ≥127.27 ln(vvg)¥110.87 NHVcz.
                                               10/7/17 ...........      Marathon/Blanchard           GBR (Texas City,           MPGF ....................   NHVvg ≥600 BTU/scf for the LH burner, and NHVcz ≥600
                                                                         Refining.                    TX).                                                    BTU/scf for LRGO burners.
                                               9/19/17 ...........      Chalmette Refining           Chalmette, LA ........     Elevated multi-point        ≥1,000 BTU/scf NHVcz or LFLcz ≤6.5 vol%.
                                                                                                                                  flare.
                                               5/1/17 .............     LACC .....................   Lake Charles, LA ...       2 MPGFs ...............     ≥1075 BTU/scf NHVcz for INDAIR Burners; ≥800 BTU/scf
                                                                                                                                                              NHVcz for LRGO only.



                                                  (1) All flares must be operated such                              gas), flare sweep gas, flare purge gas, and
                                               that the combustion zone gas net                                     flare supplemental gas, but does not
                                               heating value (NHVcz) or the lower                                   include pilot gas.
                                               flammability in the combustion zone                             i = Individual component in flare vent gas.
                                               (LFLcz) as specified in Table 2 is met.                         n = Number of components in flare vent gas.                 Where:
                                               Owners or operators must demonstrate                            xi = Concentration of component i in flare                NHVvg = Net heating value of flare vent gas,
                                               compliance with the applicable NHVcz                                 vent gas, volume fraction.                               BTU/scf.
                                               or LFLcz specified in Table 2 on a 15-                          NHVi = Net heating value of component i                   NHVmeasured = Net heating value of flare vent
                                               minute block average. Owners or                                      determined as the heat of combustion                     gas stream as measured by the
                                                                                                                    where the net enthalpy per mole of                       continuous net heating value monitoring
                                               operators must calculate and monitor                                                                                          system, BTU/scf.
                                               for the NHVcz or LFLcz according to the                              offgas is based on combustion at 25
                                                                                                                    degrees Celsius (°C) and 1 atmosphere                xH2 = Concentration of hydrogen in flare vent
                                               following:                                                                                                                    gas at the time the sample was input into
                                                  (a) Calculation of NHVcz                                          (or constant pressure) with water in the
                                                                                                                                                                             the net heating value monitoring system,
                                                  (i) If an owner or operator elects to                             gaseous state from values published in                   volume fraction.
                                               use a monitoring system capable of                                   the literature, and then the values                  938 = Net correction for the measured
                                               continuously measuring (i.e., at least                               converted to a volumetric basis using 20                 heating value of hydrogen (1,212 ¥274),
                                               once every 15 minutes), calculating, and                             °C for ‘‘standard temperature.’’ Table 3                 BTU/scf.
                                                                                                                    summarizes component properties
                                               recording the individual component                                                                                          (iii) For non-assisted flare burners,
                                                                                                                    including net heating values.
                                               concentrations present in the flare vent                                                                                  and the GBR LH burner, NHVvg =
                                               gas, NHVvg shall be calculated using the                          (ii) If the owner or operator uses a                    NHVcz. For assisted burners, such as the
                                               following equation:                                             continuous net heating value monitor,                     Marathon Garyville MPGF SKEC
                                                                                                               the owner or operator may, at their                       burners, and the Exxon Flare 26 gas-
                                                                                                                                                                         assisted burner, NHVcz is calculated
                                                                                                                                                                                                                         EN17SE18.004</GPH>




                                                                                                               discretion, install, operate, calibrate,
                                                                                                               and maintain a monitoring system                          using Equation 3.
                                                                                                               capable of continuously measuring,
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                                               Where:                                                          calculating, and recording the hydrogen
                                                                                                               concentration in the flare vent gas. The
                                                                                                                                                                                                                         EN17SE18.003</GPH>




                                               NHVvg = Net heating value of flare vent gas,
                                                  BTU/scf. Flare vent gas means all gas                        owner or operator shall use the
                                                  found just prior to the tip. This gas                        following equation to determine NHVvg
                                                  includes all flare waste gas (i.e., gas from                 for each sample measured via the net
                                                  facility operations that is directed to a                    heating value monitoring system.                          Where:
                                                                                                                                                                                                                         EN17SE18.002</GPH>




                                                  flare for the purpose of disposing the                                                                                 NHVcz = Net heating value of combustion



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                                                                                   Federal Register / Vol. 83, No. 180 / Monday, September 17, 2018 / Notices                                                                       46943

                                                   zone gas, BTU/scf.                                                       (ii) For non-assisted flare burners,                                weight of the flare vent gas is
                                               NHVvg = Net heating value of flare vent gas                                LFLvg = LFLcz.                                                        determined using compositional
                                                   for the 15-minute block period as                                        (c) Calculation of Vtip                                             analysis so that the mass flow rate can
                                                   determined according to (1)(a)(i), BTU/                                  For the ExxonMobil Flare 26, the                                    be converted to volumetric flow at
                                                   scf.                                                                   owner or operator shall calculate the 15-
                                               Qvg = Cumulative volumetric flow of flare
                                                                                                                                                                                                standard conditions using the following
                                                                                                                          minute block average Vtip by using the                                equation:
                                                   vent gas during the 15-minute block
                                                   period, scf.                                                           following equation:
                                               Qag = Cumulative volumetric flow of assist
                                                   gas during the 15-minute block period,
                                                   scf flow rate, scf.
                                               NHVag = Net heating value of assist gas, BTU/
                                                   scf; this is zero for air or for steam.
                                                                                                                                                                                                Where:
                                                 (b) Calculation of LFLcz                                                 Where:                                                                   Qvol = Volumetric flow rate, scf/sec.
                                                                                                                          Vtip = Flare tip velocity, ft/sec.                                       Qmass = Mass flow rate, pounds per sec.
                                                 (i) The owner or operator shall                                          Qvg = Cumulative volumetric flow of vent gas                             385.3 = Conversion factor, scf per pound-
                                               determine LFLcz from compositional                                              over 15-minute block average period, scf.                        mole.
                                               analysis data by using the following                                       Area = Unobstructed area of the flare tip,                               MWt = Molecular weight of the gas at the
                                               equation:                                                                       square ft.                                                       flow monitoring location, pounds per pound-
                                                                                                                          900 = Conversion factor, seconds per 15-                              mole.
                                                                                                                               minute block average.
                                                                                                                             (d) For all flare systems specified in                               (e) For each measurement produced
                                                                                                                          this document, the owner or operator                                  by the monitoring system used to
                                                                                                                          shall install, operate, calibrate, and                                comply with (1)(a)(ii), the operator shall
                                                                                                                          maintain a monitoring system capable of                               determine the 15-minute block average
                                                                                                                          continuously measuring the volumetric                                 as the arithmetic average of all
                                               Where:
                                                                                                                          flow rate of flare vent gas (Qvg), the                                measurements made by the monitoring
                                               LFLvg = Lower flammability limit of flare vent                                                                                                   system within the 15-minute period.
                                                    gas, volume percent (vol %).                                          volumetric flow rate of total assist steam
                                               n = Number of components in the vent gas.                                  (Qs), the volumetric flow rate of total                                 (f) The owner or operator must follow
                                               i = Individual component in the vent gas.                                  assist air (Qa), and the volumetric flow                              the accuracy and calibration procedures
                                               ci = Concentration of component i in the vent                              rate of total assist gas (Qag).                                       according to Table 4. Flares at refineries
                                                    gas, vol %.                                                              (i) The flow rate monitoring systems                               must meet the accuracy and calibration
                                               LFLi = Lower flammability limit of                                         must be able to correct for the                                       requirements in the Petroleum Refinery
                                                    component i as determined using values                                temperature and pressure of the system                                MACT at 40 CFR 63.671(a)(1) and (4)
                                                    published by the U.S. Bureau of Mines                                                                                                       and Table 13. Maintenance periods,
                                                    (Zabetakis, 1965), vol %. All inerts,
                                                                                                                          and output parameters in standard
                                                    including nitrogen, are assumed to have                               conditions (i.e., a temperature of 20 °C                              instrument adjustments, or checks to
                                                    an infinite LFL (e.g., LFLN2 = ∞, so that                             (68 °F) and a pressure of 1 atmosphere).                              maintain precision and accuracy and
                                                    cN2/LFLN2 = 0). LFL values for common                                    (ii) Mass flow monitors may be used                                zero and span adjustments may not
                                                    flare vent gas components are provided                                for determining volumetric flow rate of                               exceed 5 percent of the time the flare is
                                                    in Table 3.                                                           flare vent gas provided the molecular                                 receiving regulated material.

                                                                                                                  TABLE 3—INDIVIDUAL COMPONENT PROPERTIES
                                                                                                                                                                                                  MWi
                                                                                                                                                                          Molecular                               NHVi             LFLi
                                                                                                Component                                                                                      (pounds per
                                                                                                                                                                           formula                              (BTU/scf)      (volume %)
                                                                                                                                                                                               pound-mole)

                                               Acetylene .........................................................................................................    C2H2 ..............             26.04            1,404             2.5
                                               Benzene ...........................................................................................................    C6H6 ..............             78.11            3,591             1.3
                                               1,2-Butadiene ..................................................................................................       C4H6 ..............             54.09            2,794             2.0
                                               1,3-Butadiene ..................................................................................................       C4H6 ..............             54.09            2,690             2.0
                                               iso-Butane ........................................................................................................    C4H10 .............             58.12            2,957             1.8
                                               n-Butane ..........................................................................................................    C4H10 .............             58.12            2,968             1.8
                                               cis-Butene ........................................................................................................    C4H8 ..............             56.11            2,830             1.6
                                               iso-Butene ........................................................................................................    C4H8 ..............             56.11            2,928             1.8
                                               trans-Butene ....................................................................................................      C4H8 ..............             56.11            2,826             1.7
                                               Carbon Dioxide ................................................................................................        CO2 ................            44.01                0               ∞
                                               Carbon Monoxide ............................................................................................           CO .................            28.01              316            12.5
                                               Cyclopropane ...................................................................................................       C3H6 ..............             42.08            2,185             2.4
                                               Ethane .............................................................................................................   C2H6 ..............             30.07            1,595             3.0
                                               Ethylene ...........................................................................................................   C2H4 ..............             28.05            1,477             2.7
                                                                                                                                                                                                                                               EN17SE18.007</GPH>




                                               Hydrogen .........................................................................................................     H2 ...................           2.02          * 1,212             4.0
                                               Hydrogen Sulfide .............................................................................................         H2S ................            34.08              587             4.0
                                               Methane ...........................................................................................................    CH4 ................            16.04              896             5.0
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                                               Methyl-Acetylene .............................................................................................         C3H4 ..............             40.06            2,088             1.7
                                               Nitrogen ...........................................................................................................   N2 ...................          28.01                0               ∞
                                                                                                                                                                                                                                               EN17SE18.006</GPH>




                                               Oxygen ............................................................................................................    O2 ..................           32.00                0               ∞
                                               Pentane+ (C5+) ...............................................................................................         C5H12 .............             72.15            3,655             1.4
                                               Propadiene ......................................................................................................      C3H4 ..............             40.06            2,066            2.16
                                               Propane ...........................................................................................................    C3H8 ..............             44.10            2,281             2.1
                                                                                                                                                                                                                                               EN17SE18.005</GPH>




                                               Propylene .........................................................................................................    C3H6 ..............             42.08            2,150             2.4



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                                               46944                                   Federal Register / Vol. 83, No. 180 / Monday, September 17, 2018 / Notices

                                                                                                        TABLE 3—INDIVIDUAL COMPONENT PROPERTIES—Continued
                                                                                                                                                                                                   MWi
                                                                                                                                                                            Molecular                                 NHVi                 LFLi
                                                                                                 Component                                                                                      (pounds per
                                                                                                                                                                             formula            pound-mole)         (BTU/scf)          (volume %)

                                               Water ...............................................................................................................     H2O ................           18.02                    0                   ∞
                                                 * The theoretical net heating value for hydrogen is 274 BTU/scf, but for the purposes of the flare requirement in this subpart, a net heating
                                               value of 1,212 BTU/scf shall be used.

                                                                                                            TABLE 4—ACCURACY AND CALIBRATION REQUIREMENTS
                                                          Parameter                                          Accuracy requirements                                                                Calibration requirements

                                               Flare Vent Gas Flow Rate                 ±20 percent of flow rate at velocities ranging from 0.1                      Performance evaluation biennially (every 2 years) and following any period of
                                                                                          to 1 foot per second.                                                        more than 24 hours throughout which the flow rate exceeded the maximum
                                                                                        ±5 percent of flow rate at velocities greater than 1                           rated flow rate of the sensor, or the data recorder was off scale. Checks of all
                                                                                          foot per second.                                                             mechanical connections for leakage monthly. Visual inspections and checks
                                                                                                                                                                       of system operation every 3 months, unless the system has a redundant flow
                                                                                                                                                                       sensor.
                                                                                                                                                                     Select a representative measurement location where swirling flow or abnormal
                                                                                                                                                                       velocity distributions due to upstream and downstream disturbances at the
                                                                                                                                                                       point of measurement are minimized.
                                               Flow Rate for All Flows                  ±5 percent over the normal range of flow measured                            Conduct a flow sensor calibration check at least biennially (every 2 years); con-
                                                 Other Than Flare Vent                    or 1.9 liters per minute (0.5 gallons per minute),                           duct a calibration check following any period of more than 24 hours through-
                                                 Gas.                                     whichever is greater, for liquid flow.                                       out which the flow rate exceeded the manufacturer’s specified maximum rated
                                                                                                                                                                       flow rate or install a new flow sensor.
                                                                                        ±5 percent over the normal range of flow measured                            At least quarterly, inspect all components for leakage, unless the continuous pa-
                                                                                          or 280 liters per minute (10 cubic feet per minute),                         rameter monitoring system (CPMS) has a redundant flow sensor.
                                                                                          whichever is greater, for gas flow.
                                                                                        ±5 percent over the normal range measured for mass                           Record the results of each calibration check and inspection.
                                                                                          flow.                                                                      Locate the flow sensor(s) and other necessary equipment (such as straightening
                                                                                                                                                                       vanes) in a position that provides representative flow; reduce swirling flow or
                                                                                                                                                                       abnormal velocity distributions due to upstream and downstream disturb-
                                                                                                                                                                       ances.
                                               Pressure ............................    ±5 percent over the normal range measured or 0.12                            Review pressure sensor readings at least once a week for straight-line (un-
                                                                                          kilopascals (0.5 inches of water column), which-                             changing) pressure and perform corrective action to ensure proper pressure
                                                                                          ever is greater.                                                             sensor operation if blockage is indicated.
                                                                                                                                                                     Performance evaluation annually and following any period of more than 24
                                                                                                                                                                       hours throughout which the pressure exceeded the maximum rated pressure
                                                                                                                                                                       of the sensor, or the data recorder was off scale. Checks of all mechanical
                                                                                                                                                                       connections for leakage monthly. Visual inspection of all components for in-
                                                                                                                                                                       tegrity, oxidation, and galvanic corrosion every 3 months, unless the system
                                                                                                                                                                       has a redundant pressure sensor.
                                                                                                                                                                     Select a representative measurement location that minimizes or eliminates pul-
                                                                                                                                                                       sating pressure, vibration, and internal and external corrosion.
                                               Net Heating Value by Cal-                ±2 percent of span .......................................................   Calibration requirements—follow manufacturer’s recommendations at a min-
                                                 orimeter.                                                                                                             imum.
                                                                                                                                                                     Temperature control (heated and/or cooled as necessary) the sampling system
                                                                                                                                                                       to ensure proper year-round operation.
                                                                                                                                                                     Where feasible, select a sampling location at least 2 equivalent diameters
                                                                                                                                                                       downstream from and 0.5 equivalent diameters upstream from the nearest
                                                                                                                                                                       disturbance. Select the sampling location at least 2 equivalent duct diameters
                                                                                                                                                                       from the nearest control device, point of pollutant generation, air in-leakages,
                                                                                                                                                                       or other point at which a change in the pollutant concentration or emission
                                                                                                                                                                       rate occurs.
                                               Net Heating Value by Gas                 As specified in Performance Standard (PS) 9 of 40                            Follow the procedure in PS 9 of 40 CFR part 60, appendix B, except that a sin-
                                                 Chromatograph.                           CFR part 60, appendix B.                                                     gle daily mid-level calibration check can be used (rather than triplicate anal-
                                                                                                                                                                       ysis), the multi-point calibration can be conducted quarterly (rather than
                                                                                                                                                                       monthly), and the sampling line temperature must be maintained at a min-
                                                                                                                                                                       imum temperature of 60 °C (rather than 120 °C).
                                               Hydrogen Analyzer ............           ±2 percent over the concentration measured, or 0.1                           Specify calibration requirements in your site specific CPMS monitoring plan.
                                                                                          volume, percent, whichever is greater.                                       Calibration requirements—follow manufacturer’s recommendations at a min-
                                                                                                                                                                       imum.
                                                                                                                                                                     Specify the sampling location at least 2 equivalent duct diameters from the
                                                                                                                                                                       nearest control device, point of pollutant generation, air in-leakages, or other
                                                                                                                                                                       point at which a change in the pollutant concentration occurs.



                                                  (2) The flare system shall be operated                                    equivalent device used to detect the                                 the Petroleum Refinery MACT at 40 CFR
                                               with a flame present at all times when                                       presence of a flame. The time, date, and                             63.670(b) instead of the requirements
                                               in use. Additionally, each stage that                                        duration of any complete loss of pilot                               herein in section (2).
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                                               cross-lights must have at least two pilots                                   flame on any of the burners must be                                    (3) Flares at refineries shall comply
                                               with a continuously lit pilot flame,                                         recorded. Each monitoring device must                                with the Petroleum Refinery MACT
                                               except for Chalmette’s No. 1 Flare,                                          be maintained or replaced at a                                       requirements of 40 CFR 63.670(h). For
                                               which has one pilot for each stage,                                          frequency in accordance with the                                     LACC, LLC’s MPGFs, the flare system
                                               excluding stages 8A and 8B. Each pilot                                       manufacturer’s specifications. The                                   shall be operated with no visible
                                               flame must be continuously monitored                                         ExxonMobil flare, Flare 26, and GBR’s                                emissions except for periods not to
                                               by a thermocouple or any other                                               LH flare must meet the requirements in                               exceed a total of 5 minutes during any


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                                                                         Federal Register / Vol. 83, No. 180 / Monday, September 17, 2018 / Notices                                             46945

                                               2 consecutive hours. A video camera                     63.655(g)(11)(i)–(iii), except that the               ENVIRONMENTAL PROTECTION
                                               that is capable of continuously                         applicable alternative operating                      AGENCY
                                               recording (i.e., at least one frame every               conditions listed in Table 2 apply
                                                                                                                                                             [FRL–9983–85—Region 3]
                                               15 seconds with time and date stamps)                   instead of the operating limits specified
                                               images of the flare flame and a                         in 40 CFR 63.670(d) through (f). In                   Clean Water Act: West Virginia’s
                                               reasonable distance above the flare                     addition, for refinery flares that are                NPDES Program Revision
                                               flame at an angle suitable for visible                  MPGFs, notification shall also include
                                               emissions observations must be used to                  records specified in section (iv)–(v)                 AGENCY:  Environmental Protection
                                               demonstrate compliance with this                        below. For LACC MPGFs, the                            Agency (EPA).
                                               requirement. For LACC’s enclosed                        notification shall include the records                ACTION: Notice of revision, public
                                               ground flare, LACC must install a video                 specified in section (i)–(v) below.                   comment period, and opportunity to
                                               camera that is capable of continuously                     (i) Records of each 15-minute block                request a public hearing.
                                               recording (i.e., at least one frame every               for all flares during which there was at
                                               15 seconds with time and date stamps)                                                                         SUMMARY:   The State of West Virginia has
                                                                                                       least 1 minute when regulated material
                                               the stack exhaust exit at a reasonable                                                                        submitted revisions to its authorized
                                                                                                       was routed to the flare and a complete
                                               distance and at an angle suitable for                                                                         National Pollutant Discharge
                                                                                                       loss of pilot flame on a stage of burners
                                               visible emissions observation in order to                                                                     Elimination System (NPDES) program
                                                                                                       occurred, and for all flares, records of
                                               demonstrate compliance with this                                                                              for the U.S. Environmental Protection
                                                                                                       each 15-minute block during which
                                               requirement. The owner or operator                                                                            Agency’s (EPA) review. These revisions
                                                                                                       there was at least 1 minute when
                                               must provide real-time video                                                                                  consist of amendments to the West
                                                                                                       regulated material was routed to the
                                               surveillance camera output to the                                                                             Virginia Water Pollution Control Act
                                                                                                       flare and a complete loss of pilot flame
                                               control room or other continuously                                                                            codified in Senate Bill 357 (SB 357) and
                                                                                                       on an individual burner occurred.
                                               manned location where the video                                                                               to West Virginia’s Code of State
                                                                                                          (ii) Records of visible emissions                  Regulations codified as House Bill 2283
                                               camera images may be viewed at any
                                                                                                       events (including the time and date                   (HB 2283). The EPA has determined that
                                               time.
                                                  (4) For the MPGFs and Chalmette’s                    stamp) that exceed more than 5 minutes                the submitted revisions constitute a
                                               No. 1 Flare, the owner or operator of a                 in any 2-hour consecutive period.                     substantial revision to West Virginia’s
                                               flare system shall install and operate                     (iii) Records of each 15-minute block              authorized NPDES program.
                                               pressure monitor(s) on the main flare                   period for which an applicable                        Accordingly, the EPA is requesting
                                               header, as well as a valve position                     combustion zone operating condition                   public comment and providing a notice
                                               indicator monitoring system capable of                  (i.e., NHVcz or LFLcz) is not met for the             of an opportunity to request a public
                                               monitoring and recording the position                   flare when regulated material is being                hearing. Copies of SB357 and HB2283
                                               for each staging valve to ensure that the               combusted in the flare. Indicate the date             are available for public inspection as
                                               flare operates within the range of tested               and time for each period, the NHVcz                   indicated below.
                                               conditions or within the range of the                   and/or LFLcz operating parameter for the              DATES: Comments must be submitted in
                                               manufacturer’s specifications. Flares at                period, the type of monitoring system                 writing to EPA on or before October 17,
                                               refineries must meet the accuracy and                   used to determine compliance with the                 2018.
                                               calibration requirements in the                         operating parameters (e.g., gas
                                                                                                                                                             ADDRESSES: Comments on the WV
                                               Petroleum Refinery MACT at 40 CFR                       chromatograph or calorimeter), and also
                                                                                                       indicate which high-pressure stages                   NPDES Program revisions should be
                                               63.671(a)(1) and (4) and Table 13. The                                                                        sent to Francisco Cruz, Water Protection
                                               pressure monitor at LACC shall meet the                 were in use.
                                                                                                                                                             Division (3WP41), U.S. Environmental
                                               accuracy and calibration requirements                      (iv) Records of when the pressure                  Protection Agency Region 3, 1650 Arch
                                               in Table 4. Maintenance periods,                        monitor(s) on the main flare header                   Street, Philadelphia, PA 19103–2019 or
                                               instrument adjustments or checks to                     show the flare burners are operating                  email to cruz.francisco@epa.gov. Oral
                                               maintain precision and accuracy, and                    outside the range of tested conditions or             comments will not be considered.
                                               zero and span adjustments may not                       outside the range of the manufacturer’s               Underlying documents from the
                                               exceed 5 percent of the time the flare is               specifications. Indicate the date and                 administrative record for this decision
                                               receiving regulated material.                           time for each period, the pressure                    are available for public inspection at the
                                                  (5) Recordkeeping Requirements                       measurement, the stage(s) and number                  above address. Please contact Mr.
                                                  (a) All data must be recorded and                    of flare burners affected, and the range              Francisco Cruz to schedule an
                                               maintained for a minimum of 3 years or                  of tested conditions or manufacturer’s                inspection. The public, during the term
                                               for as long as required under applicable                specifications.                                       of this Federal Register notice, can
                                               rule subpart(s), whichever is longer.                      (v) Records of when the staging valve              request a public hearing. Such a hearing
                                                  (6) Reporting Requirements                           position indicator monitoring system
                                                  (a) The information specified in                                                                           will be held if there is significant public
                                                                                                       indicates a stage of the flare should not             interest based on requests received.
                                               section III(6)(b) and (c) below must be                 be in operation and is or when a stage
                                               reported in the timeline specified by the                                                                     FOR FURTHER INFORMATION CONTACT: For
                                                                                                       of the flare should be in operation and
                                               applicable rule subpart(s) for which the                                                                      additional information, contact
                                                                                                       is not. Indicate the date and time for
                                               flare will control emissions.                                                                                 Francisco Cruz at (215) 814–5734.
                                                                                                       each period, whether the stage was
                                                  (b) Owners or operators shall include                                                                      SUPPLEMENTARY INFORMATION: Section
                                                                                                       supposed to be open, but was closed, or
                                               the final AMEL operating requirements                   vice versa, and the stage(s) and number               402 of the Federal Clean Water Act
                                               for each flare in their initial Notification            of flare burners affected.                            (CWA) created the NPDES program
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                                               of Compliance status report.                                                                                  under which the EPA may issue permits
                                                  (c) The owner or operator shall notify                 Dated: September 11, 2018.                          for the discharge of pollutants into
                                               the Administrator of periods of excess                  Panagiotis Tsirigotis,                                waters of the United States under
                                               emissions in their Periodic Reports. The                Director, Office of Air Quality Planning and          conditions required by the CWA.
                                               owner or operator of refinery flares shall              Standards.                                            Section 402(b) allows states to assume
                                               meet the reporting requirements in the                  [FR Doc. 2018–20148 Filed 9–14–18; 8:45 am]           NPDES program responsibilities upon
                                               Petroleum Refinery MACT in 40 CFR                       BILLING CODE 6560–50–P                                approval by the EPA. On May 10, 1982,


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Document Created: 2018-09-15 01:37:53
Document Modified: 2018-09-15 01:37:53
CategoryRegulatory Information
CollectionFederal Register
sudoc ClassAE 2.7:
GS 4.107:
AE 2.106:
PublisherOffice of the Federal Register, National Archives and Records Administration
SectionNotices
ActionNotice; final approval.
DatesThe approval of the AMEL requests from ExxonMobil Corporation; Marathon Petroleum Company, LP (for itself and on behalf of its subsidiary, Blanchard Refining, LLC); Chalmette Refining, LLC; and LACC, LLC to operate certain flares at the refineries and a chemical plant, as specified in this notice, is effective on September 17, 2018.
ContactFor questions about this final action, contact Ms. Angie Carey, Sector Policies and Programs Division (E143- 01), Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency, Research Triangle Park, North Carolina 27711; telephone number: (919) 541-2187; fax number: (919) 541-0516; and email
FR Citation83 FR 46939 

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