80_FR_8053 80 FR 8023 - Receipt of Approval Requests for the Operation of Pressure-Assisted Multi-Point Ground Flare Technology

80 FR 8023 - Receipt of Approval Requests for the Operation of Pressure-Assisted Multi-Point Ground Flare Technology

ENVIRONMENTAL PROTECTION AGENCY

Federal Register Volume 80, Issue 30 (February 13, 2015)

Page Range8023-8030
FR Document2015-03064

On August 5, 2014, The Dow Chemical Company (Dow) requested an Alternative Means of Emission Limitation (AMEL) under the Clean Air Act (CAA) in order to operate pressure-assisted multi-point ground flares at its Propane Dehydrogenation Plant and its Light Hydrocarbons Plant at its Texas Operations site located in Freeport, Texas. On October 21, 2014, ExxonMobil Chemical Company (ExxonMobil) requested an AMEL under the CAA for its pressure-assisted multi-point ground flares at its' Olefins Plant in Baytown, Texas, and its' Plastics Plant in Mont Belvieu, Texas. In this document, the Environmental Protection Agency (EPA) is soliciting comment on all aspects of the AMEL requests and the resulting alternative operating conditions that are necessary to achieve a reduction in emissions of volatile organic compounds (VOC) and hazardous air pollutants (HAPs) at least equivalent to the reduction in emissions required by various standards in 40 CFR parts 60, 61 and 63 that apply to emission sources controlled by these pressure-assisted multi-point ground flares. These standards point to the operating requirements for flares in the General Provisions to parts 60 and 63, respectively, to comply with the emission reduction requirements. Because pressure-assisted multi-point ground flares cannot meet the velocity requirements in these General Provisions, Dow and ExxonMobil are seeking an AMEL.

Federal Register, Volume 80 Issue 30 (Friday, February 13, 2015)
[Federal Register Volume 80, Number 30 (Friday, February 13, 2015)]
[Proposed Rules]
[Pages 8023-8030]
From the Federal Register Online  [www.thefederalregister.org]
[FR Doc No: 2015-03064]


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ENVIRONMENTAL PROTECTION AGENCY

40 CFR Parts 60, 61, and 63

[EPA-HQ-OAR-2014-0738; FRL 9922-91-OAR]


Receipt of Approval Requests for the Operation of Pressure-
Assisted Multi-Point Ground Flare Technology

AGENCY: Environmental Protection Agency.

ACTION: Request for comments.

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[[Page 8024]]

SUMMARY: On August 5, 2014, The Dow Chemical Company (Dow) requested an 
Alternative Means of Emission Limitation (AMEL) under the Clean Air Act 
(CAA) in order to operate pressure-assisted multi-point ground flares 
at its Propane Dehydrogenation Plant and its Light Hydrocarbons Plant 
at its Texas Operations site located in Freeport, Texas. On October 21, 
2014, ExxonMobil Chemical Company (ExxonMobil) requested an AMEL under 
the CAA for its pressure-assisted multi-point ground flares at its' 
Olefins Plant in Baytown, Texas, and its' Plastics Plant in Mont 
Belvieu, Texas. In this document, the Environmental Protection Agency 
(EPA) is soliciting comment on all aspects of the AMEL requests and the 
resulting alternative operating conditions that are necessary to 
achieve a reduction in emissions of volatile organic compounds (VOC) 
and hazardous air pollutants (HAPs) at least equivalent to the 
reduction in emissions required by various standards in 40 CFR parts 
60, 61 and 63 that apply to emission sources controlled by these 
pressure-assisted multi-point ground flares. These standards point to 
the operating requirements for flares in the General Provisions to 
parts 60 and 63, respectively, to comply with the emission reduction 
requirements. Because pressure-assisted multi-point ground flares 
cannot meet the velocity requirements in these General Provisions, Dow 
and ExxonMobil are seeking an AMEL.

DATES: Comments. Written comments must be received on or before March 
30, 2015.
    Public Hearing. If requested by February 18, 2015, we will hold a 
public hearing on March 2, 2015, from 1:00 p.m. [Eastern Standard Time] 
to 5:00 p.m. [Eastern Standard Time] at EPA's Campus located in 
Research Triangle Park, NC. We will provide details on the public 
hearing on our Web site at: http://www.epa.gov/ttn/atw/groundflares/groundflarespg.html. To be clear, a public hearing will not be held 
unless someone specifically requests that the EPA hold a public hearing 
regarding these requests. Please contact Ms. Virginia Hunt of the 
Sector Policies and Programs Division (E143-01), Office of Air Quality 
Planning and Standards, Environmental Protection Agency, Research 
Triangle Park, NC 27711; telephone number: (919) 541-0832; email 
address: [email protected]; to request a public hearing, to 
register to speak at the public hearing or to inquire as to whether or 
not a public hearing will be held. The last day to pre-register in 
advance to speak at the public hearing will be February 25, 2015.

ADDRESSES: Submit your comments, identified by Docket ID No. EPA OAR- 
2014-0738, by one of the following methods:
     http://www.regulations.gov. Follow the on-line 
instructions for submitting comments.
     Email: [email protected]. Attention Docket ID Number 
EPA-HQ-OAR-2014-0738.
     Fax: (202) 566-9744. Attention Docket ID Number EPA-HQ-
OAR-2014-0738.
     Mail: U.S. Postal Service, send comments to: EPA Docket 
Center (EPA/DC), Attention Docket ID Number EPA-HQ-OAR-2014-0738, U.S. 
Environmental Protection Agency, Mailcode: 28221T, 1200 Pennsylvania 
Ave. NW., Washington, DC 20460.
     Hand Delivery: U.S. Environmental Protection Agency, EPA 
WJC West Building, Room 3334, 1301 Constitution Ave. NW., Washington, 
DC 20004. Attention Docket ID Number EPA-HQ-OAR-2014-0738. Such 
deliveries are only accepted during the Docket's normal hours of 
operation, and special arrangements should be made for deliveries of 
boxed information.
    Instructions. Direct your comments to Docket ID Number EPA-HQ-OAR-
2014-0738. The EPA's policy is that all comments received will be 
included in the public docket without change and may be made available 
online at http://www.regulations.gov, including any personal 
information provided, unless the comment includes information claimed 
to be confidential business information (CBI) or other information 
whose disclosure is restricted by statute. Do not submit information 
that you consider to be CBI or otherwise protected through http://www.regulations.gov or email. The http://www.regulations.gov Web site 
is an ``anonymous access'' system, which means the EPA will not know 
your identity or contact information unless you provide it in the body 
of your comment. If you send an email comment directly to the EPA 
without going through http://www.regulations.gov, your email address 
will be automatically captured and included as part of the comment that 
is placed in the public docket and made available on the Internet. If 
you submit an electronic comment, the EPA recommends that you include 
your name and other contact information in the body of your comment and 
with any disk or CD-ROM you submit. If the EPA cannot read your comment 
due to technical difficulties and cannot contact you for clarification, 
the EPA may not be able to consider your comment. Electronic files 
should not include special characters or any form of encryption and be 
free of any defects or viruses. For additional information about the 
EPA's public docket, visit the EPA Docket Center homepage at: http://www.epa.gov/dockets.
    Docket. The EPA has established a docket for this rulemaking under 
Docket ID Number EPA-HQ-OAR-2014-0738. All documents in the docket are 
listed in the regulations.gov index. Although listed in the index, some 
information is not publicly available, e.g., CBI or other information 
whose disclosure is restricted by statute. Certain other material, such 
as copyrighted material, is not placed on the Internet and will be 
publicly available only in hard copy. Publicly available docket 
materials are available either electronically in regulations.gov or in 
hard copy at the EPA Docket Center (EPA/DC), EPA WJC West Building, 
Room 3334, 1301 Constitution Ave. NW., Washington, DC. The Public 
Reading Room is open from 8:30 a.m. to 4:30 p.m., Monday through 
Friday, excluding legal holidays. The telephone number for the Public 
Reading Room is (202) 566-1744, and the telephone number for the EPA 
Docket Center is (202) 566-1742.

FOR FURTHER INFORMATION CONTACT: For questions about this proposed 
action, contact Ms. Brenda Shine, Sector Policies and Programs Division 
(E143-01), Office of Air Quality Planning and Standards (OAQPS), U.S. 
Environmental Protection Agency, Research Triangle Park, North Carolina 
27711; telephone number: (919) 541-3608; fax number: (919) 541-0246; 
and email address: [email protected].

SUPPLEMENTARY INFORMATION: 

Acronyms and Abbreviations

    We use multiple acronyms and terms in this document. While this 
list may not be exhaustive, to ease the reading of this document and 
for reference purposes, the EPA defines the following terms and 
acronyms here:

AMEL alternative means of emission limitation
BOP Baytown Olefins Plant
Btu/scf British thermal units per standard cubic feet
LFL lower flammability limit
LFLcz combustion zone lower flammability limit
LHC Light Hydrocarbons Unit
LRGO Linear relief gas oxidizer
MACT maximum achievable control technology
MBPP Mont Belvieu Plastics Plant
MPGF multi-point ground flare
NESHAP national emission standard for hazardous air pollutants

[[Page 8025]]

NHV net heating value
NHVcz combustion zone net heating value
NSPS new source performance standards
OAQPS Office of Air Quality Planning and Standards
PDH Propylene Dehydrogenation Unit
PFTIR passive fourier transform infrared
SKEC steam-assisted kinetic energy combustor

    Organization of This Document. The information in this document is 
organized as follows:

I. Statutory and Regulatory Background
    A. Flare Operating Requirements
    B. Alternative Means of Emission Limitation
II. Requests for Alternative Means of Emission Limitation
    A. Dow AMEL
    B. ExxonMobil AMEL
    C. EPA's Analysis of MPGF Burner Emission Tests
III. AMEL for Pressure-Assisted MPGF
IV. Request for Comments

I. Statutory and Regulatory Background

A. Flare Operating Requirements

    In their requests, Dow and ExxonMobil cite various regulatory 
requirements in 40 CFR parts 60, 61 and 63 that will apply to the 
different vent gas streams that will be collected and routed to their 
pressure-assisted multi-point ground flares (MPGF) at each plant. These 
requirements are included in Table 1.\1\ In all cases, these rules 
reference the flare operating requirements located in 40 CFR 60.18 and 
40 CFR 63.11.
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    \1\ EPA prepared Table 1 using the information provided in the 
requests, corrected as appropriate based on its own review of the 
regulations. However, the EPA has not independently verified whether 
Table 1 includes all of the regulatory requirements with which these 
plants must comply.

             Table 1--Summary of Applicable Rules That May Apply to Vents Streams Controlled by Pressure-Assisted Multi-Point Ground Flares
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                                                                                                                                        Provisions for
   Applicable rules with vent         Dow propane      Dow light hydro-       Exxon-Mobil      Exxon-Mobil Mont   Emission reduction   alternative means
    streams going to  control       dehydrogenation      carbons (LHC)      Baytown Olefins    Belvieu plastics       required and        of emission
             device                   (PDH) plant            plant               plant               plant           rule citation        limitation
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NSPS Subpart Kb.................  ..................                  X                   X   ..................  60.112b(a)(3)(ii)-  60.114b allows for
                                                                                                                   -Reduce VOC inlet   AMEL.
                                                                                                                   emissions by 95%;
                                                                                                                   If a flare is
                                                                                                                   used as a control
                                                                                                                   device, flare
                                                                                                                   must meet
                                                                                                                   requirements of
                                                                                                                   60.18.
NSPS Subparts VV/Vva............                  X                   X                   X   ..................  60.482-10a--Reduce  60.484(a) allows
                                                                                                                   VOC emissions by    for AMEL
                                                                                                                   95% or greater;
                                                                                                                   flare used to
                                                                                                                   comply with
                                                                                                                   subpart must meet
                                                                                                                   requirements of
                                                                                                                   60.18.
                                                                                                                  *Note--Under Dow
                                                                                                                   PDH Plant column,
                                                                                                                   NSPS subpart VVa
                                                                                                                   applies, but DOW
                                                                                                                   is opting to
                                                                                                                   comply with 40
                                                                                                                   CFR part 63,
                                                                                                                   subpart H (as
                                                                                                                   referenced by
                                                                                                                   Miscellaneous
                                                                                                                   Organic
                                                                                                                   NESHAP(MON) which
                                                                                                                   should satisfy
                                                                                                                   requirements in
                                                                                                                   subpart VVa.
NSPS Subpart DDD................  ..................  ..................  ..................                  X   60.562-1--Reduce    CAA section
                                                                                                                   emissions of        111(h)(3) allows
                                                                                                                   Total Organic       for AMEL.
                                                                                                                   Carbon (TOC) by
                                                                                                                   98%, or combust
                                                                                                                   in a flare that
                                                                                                                   meets the
                                                                                                                   requirements of
                                                                                                                   60.18.
NSPS Subpart NNN................                  X                   X                   X                   X   60.662- Reduce      CAA section
                                                                                                                   emissions of TOC    111(h)(3) allows
                                                                                                                   by 98%, or          for AMEL.
                                                                                                                   combust in a
                                                                                                                   flare that meets
                                                                                                                   the requirements
                                                                                                                   of 60.18.
NSPS Subpart RRR................                  X                   X                   X                   X   60.702--Reduce      CAA section
                                                                                                                   emissions of TOC    111(h)(3) allows
                                                                                                                   by 98%, or          for AMEL.
                                                                                                                   combust in a
                                                                                                                   flare that meets
                                                                                                                   the requirements
                                                                                                                   of 60.18.

[[Page 8026]]

 
NESHAP Subpart V................  ..................  ..................                  X   ..................  61.242-11(d)--flar  61.244 allows for
                                                                                                                   es used to comply   AMEL; also see
                                                                                                                   with subpart V      61.12(d).
                                                                                                                   must comply with
                                                                                                                   60.18.
NESHAP Subpart FF...............  ..................                  X                   X   ..................  61.349(a)--reduce   61.353 allows for
                                                                                                                   organic emissions   AMEL; also see
                                                                                                                   vented to control   61.12(d).
                                                                                                                   device by 95%; a
                                                                                                                   flare shall
                                                                                                                   comply with the
                                                                                                                   requirements of
                                                                                                                   60.18.
NESHAP Subparts F, G............  ..................  ..................                  X   ..................  63.102, 63.113,     63.102(b) allows
                                                                                                                   63.126--Reduce      for AMEL.
                                                                                                                   emissions of
                                                                                                                   Total Organic HAP
                                                                                                                   (TOHAP) by 98%,
                                                                                                                   or combust in a
                                                                                                                   flare that meets
                                                                                                                   the requirements
                                                                                                                   of 63.11(b).
                                                                                                                  63.120--Combust in
                                                                                                                   flare meeting
                                                                                                                   63.11. 63.139--
                                                                                                                   Reduce emissions
                                                                                                                   of TOHAP by 95%,
                                                                                                                   or combust in a
                                                                                                                   flare that meets
                                                                                                                   the requirements
                                                                                                                   of 63.11(b).
                                                                                                                   63.145(j)--Points
                                                                                                                   to sections of
                                                                                                                   63.11(b) for
                                                                                                                   flare control.
NESHAP Subpart H................                  X   ..................                  X   ..................  63.172--Reduce      63.177 allows for
                                                                                                                   organic HAP or      AMEL.
                                                                                                                   VOC by 95%;
                                                                                                                   flares used to
                                                                                                                   comply must meet
                                                                                                                   requirements of
                                                                                                                   63.11(b).
NESHAP Subpart SS...............                  X                   X                   X                   X   63.982(b) and       CAA section
                                                                                                                   63.987(a) require   112(h)(3) allows
                                                                                                                   that a flare        for AMEL.
                                                                                                                   meets the
                                                                                                                   requirements in
                                                                                                                   63.11(b).
NESHAP Subpart UU...............  ..................                  X   ..................  ..................  63.1034--Nonflare   63.1021 allows for
                                                                                                                   control devices     AMEL.
                                                                                                                   shall reduce
                                                                                                                   emissions by 95%;
                                                                                                                   flares shall
                                                                                                                   comply with
                                                                                                                   subpart SS.
NESHAP Subpart XX...............  ..................                  X   ..................  ..................  63.1091 requires    61.353 allows for
                                                                                                                   compliance with     AMEL; also see
                                                                                                                   subpart FF, which   61.12(d).
                                                                                                                   requires
                                                                                                                   compliance with
                                                                                                                   60.18.
NESHAP Subpart YY...............  ..................                  X                   X   ..................  Table 7 references  63.1113 allows for
                                                                                                                   subpart SS, which   AMEL.
                                                                                                                   requires
                                                                                                                   compliance with
                                                                                                                   60.18.
NESHAP Subpart EEEE.............  ..................  ..................                  X                   X   63.2378(a)          63.2346(g) allows
                                                                                                                   references          for AMEL; also
                                                                                                                   subpart SS, which   see Table 12
                                                                                                                   requires            which makes
                                                                                                                   compliance with     63.6(g)
                                                                                                                   60.18.              applicable to
                                                                                                                                       this subpart.

[[Page 8027]]

 
NESHAP Subpart FFFF.............                  X   ..................  ..................                  X   63.2450 requires    63.2540 and Table
                                                                                                                   compliance with     12 allow for AMEL
                                                                                                                   limits in Tables    by making 63.6(g)
                                                                                                                   1-7, which          applicable to
                                                                                                                   include reducing    this subpart.
                                                                                                                   total organic HAP
                                                                                                                   in vent streams
                                                                                                                   by either 95% or
                                                                                                                   98%, and provide
                                                                                                                   an option for
                                                                                                                   control using a
                                                                                                                   flare meeting
                                                                                                                   requirements of
                                                                                                                   63.982(b) which
                                                                                                                   requires meeting
                                                                                                                   63.987, which
                                                                                                                   requires a flare
                                                                                                                   to meet the
                                                                                                                   requirements of
                                                                                                                   63.11(b).
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    As shown in Table 1, the applicable rules require that control 
devices achieve destruction efficiencies of either 95 percent or 98 
percent either directly, or by reference, or allow control by flares 
meeting the flare operating requirements in 40 CFR 60.18 or 63.11. The 
flare operating requirements in 40 CFR 60.18 and 63.11 specify that 
flares shall be: (1) Steam-assisted air-assisted, or non-assisted; \2\ 
(2) operated at all times when emissions may be vented to them; (3) 
designed for and operated with no visible emissions (except for periods 
not to exceed a total of 5 minutes during any 2 consecutive hours); and 
(4) operated with the presence of a pilot flame at all times. The flare 
operating requirements in 40 CFR 60.18 and 63.11 also specify 
requirements for both the minimum heat content of gas combusted in the 
flare and the maximum exit velocity at the flare tip.\3\ These 
provisions specify maximum flare tip velocities based on flare type 
(non-assisted, steam-assisted or air-assisted) and the net heating 
value of the flare vent gas (see 40 CFR 60.18(c)(3), 63.11(b)(6)). 
These maximum flare tip velocities are required to ensure that the 
flame does not ``lift off'' or separate from the flare tip, which could 
cause flame instability and/or potentially result in a portion of the 
flare gas being released without proper combustion. Proper combustion 
for flares is considered to be 98 percent destruction efficiency or 
greater for HAPs and VOCs, as discussed in our recent proposal titled 
''Petroleum Refinery Sector Risk and Technology Review and New Source 
Performance Standards,'' 79 FR 36,880, 36,904-36,912 (June 30, 2014).
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    \2\ While Dow and ExxonMobil describe their flares as 
``pressure-assisted,'' these flares qualify as ``non-assisted'' 
flares under 40 CFR 60.18(b) or 63.11(b) because they do not employ 
assist gas.
    \3\ These requirements are not all inclusive. There are other 
requirements in 40 CFR 60.18 and 63.11 relating to monitoring and 
testing that are not described here.
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    The MPGF proposed by both Dow and ExxonMobil are conceptually 
similar yet inherently different in both flare head design and 
operation than the more traditional steam-assisted, air-assisted and 
non-assisted flare types currently able to comply with the flare 
operating requirements in 40 CFR 60.18 or 63.11. The MPGF technology 
operates by using the pressure upstream of each individual flare tip 
burner to enhance mixing with air at the flare tip due to high exit 
velocity, which allows the MPGF to operate with smokeless burning. The 
MPGF are constructed differently than normal elevated flares in that 
they consist of many rows of individual flare tips which are 
approximately 8 feet above ground level. The ground flare staging 
system opens and closes staging valves according to gas pressure such 
that stages containing multiple burners are activated as the flow and 
pressure increase or decrease in the header. While information supplied 
by Dow, and relied on by both Dow and ExxonMobil, indicates that the 
flare tips operate smokelessly and achieve high destruction 
efficiencies, the MPGF cannot meet the exit velocity requirements in 40 
CFR 60.18 and 40 CFR 63.11, which limit the exit velocity at the flare 
tip to a maximum of 400 feet per second. The exit velocities from MPGF 
typically range from 600 feet per second up to sonic velocity (which 
ranges from 700 to 1,400 feet per second for common hydrocarbon gases), 
or Mach =1 conditions. As a result, Dow and ExxonMobil are seeking an 
alternative means of complying with the flare operating requirements in 
40 CFR 60.18 and 63.11; specifically, the exit velocity requirements in 
40 CFR 60.18(c)(3), (c)(4), and (c)(5) and in 40 CFR 63.11(b)(6),(b)(7) 
and (b)(8).

B. Alternative Means of Emission Limitation

    As noted in Table 1, the specific rules in 40 CFR parts 60, 61 and 
63, or the General Provisions for parts 60, 61 and 63 of the CAA \4\ 
allow a facility to request an AMEL. These provisions allow the 
Administrator to permit the use of an alternative means of complying 
with an applicable standard, if the requestor demonstrates that the 
alternative achieves at least an equivalent reduction in emissions. The 
EPA must provide notice of the request and an opportunity for a public 
hearing on the request. After considering comments received, the EPA 
will issue a notice permitting the use of an

[[Page 8028]]

alternative means of emission limitation, if the Administrator 
determines that the alternative will achieve an equivalent reduction in 
emissions.
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    \4\ CAA section 111(h)(3) states: ``If after notice and 
opportunity for public hearing, any person establishes to the 
satisfaction of the Administrator that an alternative means of 
emission limitation will achieve a reduction in emissions of any air 
pollutant at least equivalent to the reduction in emissions of such 
air pollutant achieved under the requirements of paragraph (1), the 
Administrator shall permit the use of such alternative by the source 
for purposes of compliance with this section with respect to such 
pollutant.'' Section 112(h)(3) contains almost identical language.
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II. Requests for Alternative Means of Emission Limitation

A. Dow AMEL

    In its August 5, 2014, request, Dow indicates that it plans to 
construct and operate two new MPGFs at its Texas Operations site in 
Freeport, TX. One MPGF would be located at Dow's Propane 
Dehydrogenation Plant (PDH-1), scheduled to start-up in early 2015 and 
whose primary product is propylene. The other MPGF would be located at 
Dow's Light Hydrocarbons Plant (LHC-9), scheduled to start-up in early 
2017 and whose primary product is ethylene.
    The flare systems proposed for use by Dow at both plants consist of 
a staged design concept. The first stage, which is not at issue nor 
specifically part of the notice requesting an AMEL because it can meet 
the flare operating requirements of 40 CFR of 60.18 and 63.11, is a 
steam-assisted ground flare which has the primary function of 
controlling waste gases during periods of normal operation. The 
remaining stages consist of arrays of pressure-assisted flare tips (the 
MPGFs) and will control waste gases during periods of upset, 
maintenance, startup and shutdown (high-pressure, high flow periods). 
Pressure-assisted flares are also known as sonic flares because the 
exit velocity during periods of high-pressure feeds is at sonic 
velocities.
    At Dow, Stage 1 is the low pressure stage in which the flare acts 
as a steam-assisted flare. Stages 2 and beyond are activated for high-
pressure/high exit velocity flows. The flare system is surrounded by a 
panel type fence to protect nearby workers from the radiant heat from 
the flare system. At various times ranging from 2 hours for startup of 
processing equipment to 160 hours for a complete plant shutdown, Dow 
will have emissions from the MPGF for the following maintenance, start-
up and shutdown (MSS) activities: Perform plant start-up and shutdown, 
process equipment startup and shutdown, off-spec flaring, non-routine 
clearing and commissioning of process equipment and piping, fuel 
purging and flaring to maintain pressure of the net-gas system.
    Dow conducted testing on the two types of individual flare tips in 
its MPGF design to demonstrate that the MPGF can achieve good 
combustion efficiency under certain conditions and has proposed 
operating requirements for these MPGF that can achieve the emissions 
standards in the applicable NSPS and NESHAP. These proposed operating 
requirements are contained in Dow's request dated August 5, 2014, 
located in the docket for this document. A summary of test data and a 
complete copy of the emission testing report and appendices are 
available in the docket. The tests were conducted on individual flare 
tips because it is not possible to test the full field of MPGF because 
of the size and configuration of the full-scale MPGF installation 
(there are approximately 300 flare tips in the proposed array pattern 
that cover the size approximately equivalent to that of a football 
field in the actual installations). Although two flare tip types were 
tested during the effort, the results of one burner type, a steam-
assisted flare burner, John Zink model SKEC, are not discussed further 
as Dow is not seeking an AMEL for this burner because it operates at 
lower velocity and, thus, can meet the existing flare operating 
requirements.

B. ExxonMobil AMEL

    In its October 21, 2014, request, ExxonMobil indicates it plans to 
construct and operate two MPGFs, one at its Baytown Olefins Plant (BOP) 
in Baytown, TX, and the other at its Mont Belvieu Plastics Plant (MBPP) 
in Mont Belview, TX. Both of the proposed control strategies will be 
designed such that vent gases are routed to either a low pressure 
system, or in infrequent cases where high-pressure/high flow events 
occur, the high pressure MPGF. Both low pressure control systems at the 
BOP and MBPP consist of an elevated flare, but the MBPP low pressure 
control system also consists of three flameless thermal oxidizers. The 
elevated flares at both the BOP and MBPP will comply with 40 CFR 60.18 
and/or 40 CFR 63.11, as applicable.
    ExxonMobil did not supply any additional test data, but rather is 
relying on a series of publically available MPGF emissions tests, among 
them the 2013 test submitted by Dow, a 2012 test done by Marathon 
Petroleum Corporation, LP, a 2006 pipeline burner test done by Dow, and 
two earlier tests conducted by the EPA in the 1980s. ExxonMobil 
indicates that the BOP and MBPP burner tip designs will have comparable 
performance to the burners recently tested and submitted December 14, 
2014, supplemental application containing additional information on 
plans to use the John Zink LRGO burners for the MPGF installation at 
the MBPP, and ZEECO burners at the BOP. ExxonMobil asserts that the 
ZEECO burner design provides equivalent combustion efficiency and flame 
stability as that of the John Zink burners tested, although ExxonMobil 
has not supplied any data or information that could confirm this 
assertion of equivalency. We are requesting comment on this assertion 
as well as specifically soliciting data and comments from the public on 
burner design and performance of these MPGF burners.

C. EPA's Analysis of MPGF Burner Emission Tests

    Dow and ExxonMobil are proposing to follow all of the flare 
operating requirements contained in either 40 CFR 60.18 or 63.11, 
except for the exit velocity requirements. They are proposing to 
operate their high pressure MPGFs at higher velocity than the current 
requirements because their data indicate that these burners can operate 
with a stable flame at higher velocities and still achieve good 
combustion and destruction efficiencies. Instead of complying with the 
exit velocity requirements in 40 CFR 60.18 and 63.11, Dow and 
ExxonMobil are requesting that EPA grant their AMEL requests to allow 
them to operate the high pressure sections of their MPGFs such that the 
vent gas flowing to the flare tips is maintained with a net heating 
value that has been demonstrated to be equal to or greater than the 
values that were determined to achieve a reduction in emissions of 
pollutants being controlled by a steam-assisted, air-assisted or non-
assisted flare complying with the requirements of either 40 CFR 
63.11(b) or 40 CFR 60.18(b) during the burner emission tests.
    In the emission tests, the high pressure burners were subjected to 
a number of different operating conditions, and each set of conditions 
represented a separate test series. For purposes of this discussion, 
the relevant test results are those from Dow's 2013 test report, which 
are comprised of runs from test series P1 through P4 and were tested on 
John Zink's pressure assisted flare burner model LRGO-HC, as well as 
emissions data reported in Marathon's 2012 test report, which are from 
test series PA1 and PA2 and were tested on John Zink's pressure 
assisted flare burner model LRGO-D. These tests used the analytical 
technique of passive fourier transform infrared (PFTIR) spectroscopy to 
assess combustion efficiency. Dow's 2013 test report also presents data 
collected using an extractive method where flue gas was extracted from 
a collection hood that was suspended above the burner tip and analyzed 
using standard EPA methods.

[[Page 8029]]

The Marathon 2012 test report (see ``Performance Test of Steam-Assisted 
and Pressure-Assisted Ground Flare Burners with Passive FTIR--
Garyville'') and the Dow 2013 test report (see ``Report on Emissions 
Testing of Pressure Assisted LRGO-HC and Steam Assisted SKEC Burners'') 
are provided in the docket.
    The results of the PFTIR testing indicated that when a flame was 
present on the pressure-assisted flare burners tested that an average 
combustion efficiency of 99 percent or greater was always achieved. 
Each set of operating conditions tested by both Dow and Marathon for 
both combustion efficiency and flame stability generally consisted of a 
series of triplicate runs. In all, a total of 34 test runs were 
analyzed from these two tests (21 from Dow's P1 through P3 test series 
and 13 from Marathon's PA1 and PA2 test series). For test series P4, 
which was conducted as part of Dow's 2013 test using a 90 volume 
percent hydrogen/10 volume percent natural gas mixture, no combustion 
efficiency test was conducted; instead, a qualitative indication that 
the flame was stable at the conditions tested was made. We note that in 
Dow's 2013 test report that three of the 21 test runs were aborted 
because of loss of flame (which we refer to as flameout); only two of 
the three test runs (one in the P2H series and one in the P2L series) 
produced enough information before flameout to be analyzed in more 
detail. We requested more detailed information from Dow on the 
conditions that resulted in this loss of flame as it informs us of the 
conditions that would create a failure of the burners to sustain a 
stable flame and achieve good combustion. This document is included in 
the docket titled ``Supplement 1 to Dow report.'' Additionally, we also 
note that in Marathon's 2012 test report that two of the 13 test runs 
also experienced loss of flame (test PA1 Runs 4(2) and 4(4)). The 
results of all of these test runs are discussed in the memorandum 
titled ``Review of Available Test Data on Multipoint Ground Flares,'' 
located in the docket.
    There are two general conclusions from these test reports that are 
consistent with the earlier EPA 1985 study done on pressure-assisted 
flares (see conclusions on pages 2-19 and 2-22 in September 1985 EPA 
report titled ``Evaluation of the efficiency of industrial flares: 
Flare head design and gas composition''). The first is that ``flare 
head design can influence the flame stability curve.'' This is evident 
in Figures 2-3 and 2-5 of the 1985 EPA report where different stability 
curves were generated for the different flare heads (burners) tested 
over a range of differing exit velocities and flare gas net heating 
values. When comparing the current maximum flare tip velocity 
requirements in the general provisions with those tested on pressure-
assisted flare burners, this conclusion still holds true. The agency's 
current requirements would require that flares meet an increasing 
minimum net heating value with increasing velocity, all the way up to a 
minimum waste gas net heating value of 1,000 BTU/scf and maximum 
velocity of 400 feet per second. However, the recent test reports on 
pressure-assisted burners show that flame stability can be achieved at 
significantly higher velocities (i.e., sonic velocity) with waste gas 
net heating values below 1,000 BTU/scf. The second general conclusion 
made from EPA's 1985 study is that ``stable flare flames and high (>98-
99) combustion and destruction efficiencies are attained when flares 
are operated within operating envelopes specific to each flare burner 
and gas mixture tested. Operation beyond the edge of the operating 
envelope can result in rapid flame de-stabilization and a decrease in 
combustion and destruction efficiencies.'' The data where flameout of 
the burners occurred from test runs in both the Marathon 2012 test 
report and the Dow 2013 test report showed that the flare operating 
envelope was different for the different gas mixtures tested. 
Additionally, it was observed that combustion degradation beyond the 
edge of the operating envelope for pressure-assisted MPGF burners was 
so rapid that when a flame was present, the flare would still achieve a 
high level of combustion efficiency right up until the point of 
flameout.
    In order to assess the proper operating envelope for these flare 
types, the EPA evaluated both the net heating value (in BTU/scf), which 
is how the 40 CFR part 60 and 63 General Provisions currently address 
combustion zone properties, as well as the lower flammability limit 
(LFL) because the LFL may be a better indicator of performance than net 
heating value for some flare vent gas streams, notably those with the 
potential for high hydrogen content. Hydrogen is relatively flammable, 
but its net heating value is low on a BTU/scf basis when compared to 
other hydrocarbons. By using LFL, we eliminate the need to correct the 
hydrogen heat content or to select a lower BTU/scf limit for high 
hydrogen cases. Although Dow has requested operating limits in the form 
of BTU/scf and has presented the test data in BTU/scf, we believe it is 
important to consider both types of operating limits.
    Our review indicates that the LRGO burners tested achieve a high 
level of combustion efficiency when the lower flammability limit of 
waste gases burned in the flare is less than 6.5 volume percent (vol%) 
LFL or above 800 BTU/scf. We suggest the 6.5 vol% LFL based on the 
flammability of the stream during the flame out conditions experienced 
during the high pressure test run P2H1 (at 6.6 vol% LFL). The 
corresponding BTU content of the waste gas at this value was 789 BTU/
scf (according to Dow, the gas chromatograph analysis indicated this 
value was 746 BTU/scf, although the John Zink report based on measured 
flow rates indicated it was 789 BTU/scf). Dow's proposed operating 
conditions included startup/shutdown cases where the waste gas heat 
content could be as low as 690 BTU/scf and as high as 6.9 vol% LFL, and 
data from these tests indicate that good combustion can occur at these 
conditions. However, to establish the alternative operating 
requirements at a level that ensures good combustion and flame 
stability at all times under all operating conditions, we believe it is 
reasonable to establish the heat content requirements for BTU/scf above 
which there were no flame out observations. For LFL, that level would 
be set below which there are no flame out observations. This is because 
gas mixtures with a relatively high LFL are less flammable when 
released to the air than mixtures with a relatively low LFL. A gas 
mixture with a relatively high LFL requires a larger volume of the 
mixture to burn in a specific volume of air, than would a mixture of 
gases with a relatively low LFL being combusted in that same volume of 
air. We believe the flame out observations establish the limiting case 
because a flameout is a complete failure of the burner, indicating 
zero-percent combustion. Because of the quantity of waste gases 
potentially flared in the high-pressure zones of these MPGF, we believe 
it would be prudent to establish limits on the conservative side to 
prevent air emissions of unburned waste gas.
    We also reviewed whether we should consider velocity or burner 
operating pressure in describing conditions that should be met during 
the MPGF operation and whether we should require some testing to ensure 
that the individual burners will ignite properly when a new stage goes 
into service. Dow provided information on its process control system 
and indicated that cross-light testing (testing of burner ignition from 
pilots) of individual burners at its off-site test facility has been 
conducted

[[Page 8030]]

and the burners performed as expected. This discussion, titled 
``Process control system overview-multipoint ground flare system,'' is 
in the docket for this action. At this time, we are not considering any 
requirements for additional process control or ignition testing. 
However, we believe it would be important to require that cameras are 
installed and operated such that operators have a visual indication of 
flames from the flare at all times that the MPGF is operating and that 
this footage be available for inspection by the permitting agency, 
along with operational records of the waste gas flowrate, pressure in 
header and stages, pilot and waste gas composition.
    Because these flares are located at ground level, it is possible 
that ambient concentrations of pollutants could be higher than they 
would be under an alternative scenario where waste gases would be 
flared in an elevated flare, enabling greater dispersion and 
potentially lessening the impact to neighboring communities. To that 
end, we are soliciting comment on whether additional ambient monitoring 
is warranted to provide for immediate notification to emergency 
planning officials and the community during significant events and 
malfunctions of the system.

III. AMEL for Pressure-Assisted MPGF

    Considering the above requests from both Dow and ExxonMobil, we are 
seeking the public's input on the operating requirements for the 
proposed pressure-assisted MPGFs that would be used by both companies 
which would establish an AMEL that will achieve a reduction in 
emissions at least equivalent to the reduction in emissions being 
controlled by a steam-assisted, air-assisted or non-assisted flare 
complying with the requirements of either 40 CFR 63.11(b) or 40 CFR 
60.18(b). Information provided in the AMEL requests and the available 
emissions test data from the test reports described above indicate that 
the following list of operating requirements for pressure-assisted MPGF 
result in destruction efficiencies at least equivalent to destruction 
efficiencies expected from complying with the requirements of 40 CFR 
63.11(b) and 40 CFR 60.18(b) for the pressure-assisted MPGF being 
proposed for use by both Dow and ExxonMobil:
    1. The flare system must be designed and operated such that the net 
heating value of the combustion zone gas (NHVcz) for the 
pressure assisted flare burners meets a minimum heating value of 800 
BTU/scf or a lower flammability limit of the combustion zone gas 
(LFLcz) of less than or equal to 6.5 percent by volume under 
all conditions. We would expect owners or operators to calculate 
NHVcz and LFLcz in a manner similar to those in 
the currently proposed requirements of 79 FR 36980-40 CFR 63.670(l)-
(m).
    2. The flare system must be operated with a flame present at all 
times when in use. Each row of flare burners must have at least one 
pilot with a constant pilot flame. The pilot flame(s) must be 
continuously monitored by a thermocouple. The time, date and duration 
of any loss of pilot flame must be recorded. Each monitoring device 
must be maintained or replaced at a frequency in accordance with the 
manufacturer's specifications.
    3. The flare system must be operated with no visible emissions 
except for periods not to exceed a total of 5 minutes during any 2 
consecutive hours. A video camera can be used in order to conduct 
visible emission observations since operating personnel cannot enter 
the fenced area while the MPGF is operating.
    4. The operator must install and operate an on-line vent gas flow 
meter and an on-line gas chromatograph to measure the flow and 
composition of the vent gas to each flare. We would expect the operator 
to comply with similar monitoring and testing requirements and 
recordkeeping and reporting requirements for these monitoring systems 
as currently proposed in 79 FR 36980-40 CFR 63.670(i)-(j) and (l)-(m).
    5. The operator should install and operate pressure and/or flow 
monitors on each stage of the flare. We would expect the operator to 
comply with similar applicable monitoring and testing requirements and 
recordkeeping and reporting requirements for these monitoring systems 
as currently proposed in 79 FR 36980-40 CFR 63.670(i).

IV. Request for Comments

    We solicit comments on all aspects of these requests for an AMEL. 
We specifically seek comment regarding whether or not the potential 
alternative operating requirements listed in section III above would be 
adequate for ensuring that the MPGF will achieve good combustion at all 
times and enable the facilities to meet their applicable emission 
standards. Additionally, several other entities have indicated to us 
that they intend to make similar requests for the ability to operate 
pressure-assisted MPGFs. We are also soliciting comment on whether the 
requirements listed above, if followed by these other entities, could 
enable these other facilities to receive approval of their own AMELs. 
As noted in section II.B above, we also solicit comment and data on 
other pressure-assisted flare burner types. Commenters should include 
data or specific examples in support of their comments.

    Dated: February 3, 2015.
Janet G. McCabe,
Acting Assistant Administrator.
[FR Doc. 2015-03064 Filed 2-12-15; 8:45 am]
BILLING CODE 6560-50-P



                                                                                    Federal Register / Vol. 80, No. 30 / Friday, February 13, 2015 / Proposed Rules                                                               8023

                                                                                                                      TABLE 5—PM2.5 DESIGN VALUES—Continued
                                                                                                         Year                                                         2008–2010         2009–2011          2010–2012        2011–2013

                                                      North Birmingham ............................................................................................               29                27               26                24
                                                         1997 Annual PM2.5 NAAQS: 15 μg/m3.
                                                         2006 24-hour PM2.5 NAAQS: 35 μg/m3.


                                                        Given the current PM2.5                                               EPA has preliminarily determined                              • is not a significant regulatory action
                                                      concentrations and downward trend of                                  that Alabama’s November 14, 2014, SIP                        subject to Executive Order 13211 (66 FR
                                                      these concentrations in the Area and the                              revision, containing the noninterference                     28355, May 22, 2001);
                                                      results of Alabama’s mobile source                                    demonstration associated with the                               • is not subject to requirements of
                                                      modeling, EPA has preliminarily                                       State’s request for the change of the                        Section 12(d) of the National
                                                      determined that a change to 9.0 psi RVP                               Federal RVP requirements is consistent                       Technology Transfer and Advancement
                                                      fuel in the Birmingham Area would not                                 with the applicable provisions of the                        Act of 1995 (15 U.S.C. 272 note) because
                                                      interfere with maintenance of the 1997                                CAA. EPA is not proposing action today                       application of those requirements would
                                                      Annual PM2.5 NAAQS or the 2006 24-                                    to remove the Birmingham Area from                           be inconsistent with the CAA; and
                                                      hour PM2.5 NAAQS in the Area.11                                       the Federal 7.8 psi RVP requirement.                            • does not provide EPA with the
                                                      d. Noninterference Analysis for the 2010                              Any such proposal will occur in a                            discretionary authority to address, as
                                                      NO2 NAAQS                                                             separate and subsequent rulemaking.                          appropriate, disproportionate human
                                                                                                                                                                                         health or environmental effects, using
                                                         On February 17, 2012, EPA                                          VII. Statutory and Executive Order
                                                                                                                                                                                         practicable and legally permissible
                                                      designated all counties in Alabama as                                 Reviews
                                                                                                                                                                                         methods, under Executive Order 12898
                                                      unclassifiable/attainment for the 2010                                   Under the CAA, the Administrator is                       (59 FR 7629, February 16, 1994).
                                                      NO2 NAAQS. See 77 FR 9532. Based on                                   required to approve a SIP submittal that                        In addition, the SIP is not approved
                                                      the technical analysis in Alabama’s                                                                                                to apply on any Indian reservation land
                                                                                                                            complies with the provisions of the Act
                                                      November 14, 2014, SIP revision, the                                                                                               or in any other area where EPA or an
                                                                                                                            and applicable federal regulations. 42
                                                      potential increase in NOX emissions                                                                                                Indian tribe has demonstrated that a
                                                                                                                            U.S.C. 7410(k); 40 CFR 52.02(a). Thus,
                                                      associated with the change to 9.0 psi                                                                                              tribe has jurisdiction. In those areas of
                                                                                                                            in reviewing SIP submissions, EPA’s
                                                      RVP fuel in the Birmingham Area is                                                                                                 Indian country, the rule does not have
                                                                                                                            role is to approve state choices,
                                                      approximately 24 tons during high                                                                                                  tribal implications as specified by
                                                                                                                            provided that they meet the criteria of
                                                      ozone season. As discussed in section                                                                                              Executive Order 13175 (65 FR 67249,
                                                                                                                            the CAA. Accordingly, this proposed
                                                      V.a, above, the slight projected increase                                                                                          November 9, 2000) nor will it impose
                                                                                                                            action merely proposes to approve state
                                                      in mobile source NOX emissions due to                                                                                              substantial direct costs on tribal
                                                                                                                            law as meeting Federal requirements
                                                      the fuel switch will be negated by a                                                                                               governments or preempt tribal law.
                                                      decrease in tailpipe emissions due to                                 and does not propose to impose
                                                      fleet turnover. Given the current                                     additional requirements beyond those                         List of Subjects in 40 CFR Part 52
                                                      unclassifiable/attainment designation                                 imposed by state law. For that reason,
                                                                                                                            this proposed action:                                          Environmental protection, Air
                                                      and the results of Alabama’s mobile                                                                                                pollution control, Incorporation by
                                                      source modeling, EPA has preliminarily                                   • Is not a significant regulatory action
                                                                                                                            subject to review by the Office of                           reference, Intergovernmental relations,
                                                      determined that a change to 9.0 psi RVP                                                                                            Nitrogen dioxide, Ozone, Particulate
                                                      fuel in the Birmingham Area would not                                 Management and Budget under
                                                                                                                            Executive Orders 12866 (58 FR 51735,                         matter, Reporting and recordkeeping
                                                      interfere with maintenance of the 2010                                                                                             requirements and Volatile organic
                                                      NO2 NAAQS in the Area.                                                October 4, 1993) and 13563 (76 FR 3821,
                                                                                                                            January 21, 2011);                                           compounds.
                                                      VI. Proposed Action                                                                                                                   Authority: 42 U.S.C. 7401 et seq.
                                                                                                                               • does not impose an information
                                                        EPA is proposing to approve the State                               collection burden under the provisions                         Dated: February 4, 2015.
                                                      of Alabama’s noninterference                                          of the Paperwork Reduction Act (44                           V. Anne Heard,
                                                      demonstration, submitted on November                                  U.S.C. 3501 et seq.);                                        Acting Regional Administrator, Region 4.
                                                      14, 2014, in support of the State’s
                                                                                                                               • is certified as not having a                            [FR Doc. 2015–02942 Filed 2–12–15; 8:45 am]
                                                      request that EPA change the Federal
                                                                                                                            significant economic impact on a                             BILLING CODE 6560–50–P
                                                      RVP requirements for the Birmingham
                                                      Area from 7.8 psi to 9.0 psi.                                         substantial number of small entities
                                                      Specifically, EPA is proposing to find                                under the Regulatory Flexibility Act (5
                                                                                                                            U.S.C. 601 et seq.);                                         ENVIRONMENTAL PROTECTION
                                                      that this change in the RVP
                                                                                                                               • does not contain any unfunded                           AGENCY
                                                      requirements for the Birmingham Area
                                                      will not interfere with attainment or                                 mandate or significantly or uniquely
                                                                                                                                                                                         40 CFR Parts 60, 61, and 63
                                                      maintenance of any NAAQS or with any                                  affect small governments, as described
                                                      other applicable requirement of the                                   in the Unfunded Mandates Reform Act                          [EPA–HQ–OAR–2014–0738; FRL 9922–91–
                                                                                                                            of 1995 (Pub. L. 104–4);
wreier-aviles on DSK5TPTVN1PROD with PROPOSALS




                                                      CAA.                                                                                                                               OAR]
                                                                                                                               • does not have Federalism
                                                        11 EPA has also preliminarily determined that a
                                                                                                                            implications as specified in Executive                       Receipt of Approval Requests for the
                                                      change to 9.0 psi RVP fuel in the Birmingham Area                     Order 13132 (64 FR 43255, October 7,                         Operation of Pressure-Assisted Multi-
                                                      would not interfere with maintenance of the
                                                      Annual PM10 NAAQS of 150 mg/m3 given the                              1999);                                                       Point Ground Flare Technology
                                                      results of Alabama’s mobile source modeling and                          • is not an economically significant                      AGENCY:  Environmental Protection
                                                      the fact that the Area is currently attaining the PM10
                                                      standard. Because PM2.5 is a component of PM10,
                                                                                                                            regulatory action based on health or                         Agency.
                                                      this preliminary determination is further supported                   safety risks subject to Executive Order
                                                                                                                                                                                         ACTION: Request for comments.
                                                      by the downward trend in PM2.5 identified above.                      13045 (62 FR 19885, April 23, 1997);


                                                 VerDate Sep<11>2014       13:53 Feb 12, 2015        Jkt 235001     PO 00000       Frm 00044      Fmt 4702      Sfmt 4702   E:\FR\FM\13FEP1.SGM   13FEP1


                                                      8024                    Federal Register / Vol. 80, No. 30 / Friday, February 13, 2015 / Proposed Rules

                                                      SUMMARY:   On August 5, 2014, The Dow                   in advance to speak at the public                     you for clarification, the EPA may not
                                                      Chemical Company (Dow) requested an                     hearing will be February 25, 2015.                    be able to consider your comment.
                                                      Alternative Means of Emission                           ADDRESSES: Submit your comments,                      Electronic files should not include
                                                      Limitation (AMEL) under the Clean Air                   identified by Docket ID No. EPA OAR–                  special characters or any form of
                                                      Act (CAA) in order to operate pressure-                 2014–0738, by one of the following                    encryption and be free of any defects or
                                                      assisted multi-point ground flares at its               methods:                                              viruses. For additional information
                                                      Propane Dehydrogenation Plant and its                     • http://www.regulations.gov. Follow                about the EPA’s public docket, visit the
                                                      Light Hydrocarbons Plant at its Texas                   the on-line instructions for submitting               EPA Docket Center homepage at:
                                                      Operations site located in Freeport,                    comments.                                             http://www.epa.gov/dockets.
                                                      Texas. On October 21, 2014,                               • Email: a-and-r-docket@epa.gov.                       Docket. The EPA has established a
                                                      ExxonMobil Chemical Company                             Attention Docket ID Number EPA–HQ–                    docket for this rulemaking under Docket
                                                      (ExxonMobil) requested an AMEL under                    OAR–2014–0738.                                        ID Number EPA–HQ–OAR–2014–0738.
                                                      the CAA for its pressure-assisted multi-                  • Fax: (202) 566–9744. Attention                    All documents in the docket are listed
                                                      point ground flares at its’ Olefins Plant               Docket ID Number EPA–HQ–OAR–                          in the regulations.gov index. Although
                                                      in Baytown, Texas, and its’ Plastics                    2014–0738.                                            listed in the index, some information is
                                                      Plant in Mont Belvieu, Texas. In this                     • Mail: U.S. Postal Service, send                   not publicly available, e.g., CBI or other
                                                      document, the Environmental                             comments to: EPA Docket Center (EPA/                  information whose disclosure is
                                                      Protection Agency (EPA) is soliciting                   DC), Attention Docket ID Number EPA–                  restricted by statute. Certain other
                                                      comment on all aspects of the AMEL                                                                            material, such as copyrighted material,
                                                                                                              HQ–OAR–2014–0738, U.S.
                                                                                                                                                                    is not placed on the Internet and will be
                                                      requests and the resulting alternative                  Environmental Protection Agency,
                                                                                                                                                                    publicly available only in hard copy.
                                                      operating conditions that are necessary                 Mailcode: 28221T, 1200 Pennsylvania
                                                                                                                                                                    Publicly available docket materials are
                                                      to achieve a reduction in emissions of                  Ave. NW., Washington, DC 20460.
                                                                                                                                                                    available either electronically in
                                                      volatile organic compounds (VOC) and                      • Hand Delivery: U.S. Environmental
                                                                                                                                                                    regulations.gov or in hard copy at the
                                                      hazardous air pollutants (HAPs) at least                Protection Agency, EPA WJC West
                                                                                                                                                                    EPA Docket Center (EPA/DC), EPA WJC
                                                      equivalent to the reduction in emissions                Building, Room 3334, 1301 Constitution
                                                                                                                                                                    West Building, Room 3334, 1301
                                                      required by various standards in 40 CFR                 Ave. NW., Washington, DC 20004.
                                                                                                                                                                    Constitution Ave. NW., Washington,
                                                      parts 60, 61 and 63 that apply to                       Attention Docket ID Number EPA–HQ–
                                                                                                                                                                    DC. The Public Reading Room is open
                                                      emission sources controlled by these                    OAR–2014–0738. Such deliveries are
                                                                                                                                                                    from 8:30 a.m. to 4:30 p.m., Monday
                                                      pressure-assisted multi-point ground                    only accepted during the Docket’s
                                                                                                                                                                    through Friday, excluding legal
                                                      flares. These standards point to the                    normal hours of operation, and special
                                                                                                                                                                    holidays. The telephone number for the
                                                      operating requirements for flares in the                arrangements should be made for
                                                                                                                                                                    Public Reading Room is (202) 566–1744,
                                                      General Provisions to parts 60 and 63,                  deliveries of boxed information.
                                                                                                                                                                    and the telephone number for the EPA
                                                      respectively, to comply with the                          Instructions. Direct your comments to
                                                                                                                                                                    Docket Center is (202) 566–1742.
                                                      emission reduction requirements.                        Docket ID Number EPA–HQ–OAR–
                                                                                                                                                                    FOR FURTHER INFORMATION CONTACT: For
                                                      Because pressure-assisted multi-point                   2014–0738. The EPA’s policy is that all
                                                                                                              comments received will be included in                 questions about this proposed action,
                                                      ground flares cannot meet the velocity
                                                                                                              the public docket without change and                  contact Ms. Brenda Shine, Sector
                                                      requirements in these General                                                                                 Policies and Programs Division (E143–
                                                      Provisions, Dow and ExxonMobil are                      may be made available online at
                                                                                                              http://www.regulations.gov, including                 01), Office of Air Quality Planning and
                                                      seeking an AMEL.                                                                                              Standards (OAQPS), U.S.
                                                                                                              any personal information provided,
                                                      DATES:  Comments. Written comments                      unless the comment includes                           Environmental Protection Agency,
                                                      must be received on or before March 30,                 information claimed to be confidential                Research Triangle Park, North Carolina
                                                      2015.                                                   business information (CBI) or other                   27711; telephone number: (919) 541–
                                                         Public Hearing. If requested by                      information whose disclosure is                       3608; fax number: (919) 541–0246; and
                                                      February 18, 2015, we will hold a public                restricted by statute. Do not submit                  email address: shine.brenda@epa.gov.
                                                      hearing on March 2, 2015, from 1:00                     information that you consider to be CBI               SUPPLEMENTARY INFORMATION:
                                                      p.m. [Eastern Standard Time] to 5:00                    or otherwise protected through http://                Acronyms and Abbreviations
                                                      p.m. [Eastern Standard Time] at EPA’s                   www.regulations.gov or email. The
                                                                                                                                                                      We use multiple acronyms and terms
                                                      Campus located in Research Triangle                     http://www.regulations.gov Web site is
                                                                                                                                                                    in this document. While this list may
                                                      Park, NC. We will provide details on the                an ‘‘anonymous access’’ system, which
                                                                                                                                                                    not be exhaustive, to ease the reading of
                                                      public hearing on our Web site at:                      means the EPA will not know your
                                                                                                                                                                    this document and for reference
                                                      http://www.epa.gov/ttn/atw/                             identity or contact information unless
                                                                                                                                                                    purposes, the EPA defines the following
                                                      groundflares/groundflarespg.html. To be                 you provide it in the body of your
                                                                                                                                                                    terms and acronyms here:
                                                      clear, a public hearing will not be held                comment. If you send an email
                                                      unless someone specifically requests                    comment directly to the EPA without                   AMEL alternative means of emission
                                                      that the EPA hold a public hearing                      going through http://                                     limitation
                                                                                                                                                                    BOP Baytown Olefins Plant
                                                      regarding these requests. Please contact                www.regulations.gov, your email                       Btu/scf British thermal units per standard
                                                      Ms. Virginia Hunt of the Sector Policies                address will be automatically captured                    cubic feet
                                                      and Programs Division (E143–01), Office                 and included as part of the comment                   LFL lower flammability limit
wreier-aviles on DSK5TPTVN1PROD with PROPOSALS




                                                      of Air Quality Planning and Standards,                  that is placed in the public docket and               LFLcz combustion zone lower flammability
                                                      Environmental Protection Agency,                        made available on the Internet. If you                    limit
                                                      Research Triangle Park, NC 27711;                       submit an electronic comment, the EPA                 LHC Light Hydrocarbons Unit
                                                      telephone number: (919) 541–0832;                       recommends that you include your                      LRGO Linear relief gas oxidizer
                                                      email address: hunt.virginia@epa.gov; to                name and other contact information in                 MACT maximum achievable control
                                                                                                                                                                        technology
                                                      request a public hearing, to register to                the body of your comment and with any                 MBPP Mont Belvieu Plastics Plant
                                                      speak at the public hearing or to inquire               disk or CD–ROM you submit. If the EPA                 MPGF multi-point ground flare
                                                      as to whether or not a public hearing                   cannot read your comment due to                       NESHAP national emission standard for
                                                      will be held. The last day to pre-register              technical difficulties and cannot contact                 hazardous air pollutants



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                                                                                Federal Register / Vol. 80, No. 30 / Friday, February 13, 2015 / Proposed Rules                                                                                     8025

                                                      NHV net heating value                                                    B. Alternative Means of Emission                                            requirements in 40 CFR parts 60, 61 and
                                                      NHVcz combustion zone net heating value                                     Limitation                                                               63 that will apply to the different vent
                                                      NSPS new source performance standards                                 II. Requests for Alternative Means of
                                                                                                                                                                                                           gas streams that will be collected and
                                                      OAQPS Office of Air Quality Planning and                                    Emission Limitation
                                                                                                                               A. Dow AMEL                                                                 routed to their pressure-assisted multi-
                                                         Standards
                                                                                                                               B. ExxonMobil AMEL                                                          point ground flares (MPGF) at each
                                                      PDH Propylene Dehydrogenation Unit
                                                      PFTIR passive fourier transform infrared
                                                                                                                               C. EPA’s Analysis of MPGF Burner                                            plant. These requirements are included
                                                                                                                                  Emission Tests                                                           in Table 1.1 In all cases, these rules
                                                      SKEC steam-assisted kinetic energy                                    III. AMEL for Pressure-Assisted MPGF
                                                         combustor                                                                                                                                         reference the flare operating
                                                                                                                            IV. Request for Comments
                                                                                                                                                                                                           requirements located in 40 CFR 60.18
                                                        Organization of This Document. The                                                                                                                 and 40 CFR 63.11.
                                                                                                                            I. Statutory and Regulatory Background
                                                      information in this document is
                                                      organized as follows:                                                 A. Flare Operating Requirements
                                                      I. Statutory and Regulatory Background                                  In their requests, Dow and
                                                         A. Flare Operating Requirements                                    ExxonMobil cite various regulatory

                                                      TABLE 1—SUMMARY OF APPLICABLE RULES THAT MAY APPLY TO VENTS STREAMS CONTROLLED BY PRESSURE-ASSISTED
                                                                                           MULTI-POINT GROUND FLARES
                                                       Applicable
                                                       rules with                                                                                                                                                                          Provisions for
                                                                         Dow propane                         Dow light                     Exxon-Mobil                    Exxon-Mobil Mont                    Emission reduction
                                                      vent streams                                                                                                                                                                      alternative means
                                                                        dehydrogenation                    hydro-carbons                  Baytown Olefins                  Belvieu plastics                     required and
                                                        going to                                                                                                                                                                            of emission
                                                                          (PDH) plant                       (LHC) plant                        plant                            plant                            rule citation
                                                         control                                                                                                                                                                             limitation
                                                         device

                                                      NSPS Sub-        ..............................                X                                X                   ..............................    60.112b(a)(3)(ii)—Re-      60.114b allows for
                                                       part Kb.                                                                                                                                               duce VOC inlet emis-       AMEL.
                                                                                                                                                                                                              sions by 95%; If a
                                                                                                                                                                                                              flare is used as a
                                                                                                                                                                                                              control device, flare
                                                                                                                                                                                                              must meet require-
                                                                                                                                                                                                              ments of 60.18.
                                                      NSPS Sub-                     X                                X                                X                   ..............................    60.482–10a—Reduce          60.484(a) allows
                                                       parts VV/                                                                                                                                              VOC emissions by           for AMEL
                                                       Vva.                                                                                                                                                   95% or greater; flare
                                                                                                                                                                                                              used to comply with
                                                                                                                                                                                                              subpart must meet
                                                                                                                                                                                                              requirements of
                                                                                                                                                                                                              60.18.
                                                                                                                                                                                                            *Note—Under Dow
                                                                                                                                                                                                              PDH Plant column,
                                                                                                                                                                                                              NSPS subpart VVa
                                                                                                                                                                                                              applies, but DOW is
                                                                                                                                                                                                              opting to comply with
                                                                                                                                                                                                              40 CFR part 63, sub-
                                                                                                                                                                                                              part H (as referenced
                                                                                                                                                                                                              by Miscellaneous Or-
                                                                                                                                                                                                              ganic
                                                                                                                                                                                                              NESHAP(MON)
                                                                                                                                                                                                              which should satisfy
                                                                                                                                                                                                              requirements in sub-
                                                                                                                                                                                                              part VVa.
                                                      NSPS Sub-        ..............................   ..............................   ..............................                X                    60.562–1—Reduce            CAA section
                                                       part DDD.                                                                                                                                              emissions of Total        111(h)(3) allows
                                                                                                                                                                                                              Organic Carbon            for AMEL.
                                                                                                                                                                                                              (TOC) by 98%, or
                                                                                                                                                                                                              combust in a flare
                                                                                                                                                                                                              that meets the re-
                                                                                                                                                                                                              quirements of 60.18.
                                                      NSPS Sub-                     X                                X                                X                                X                    60.662- Reduce emis-       CAA section
                                                       part NNN.                                                                                                                                              sions of TOC by           111(h)(3) allows
                                                                                                                                                                                                              98%, or combust in a      for AMEL.
                                                                                                                                                                                                              flare that meets the
                                                                                                                                                                                                              requirements of
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                                                                                                                                                                                                              60.18.
                                                      NSPS Sub-                     X                                X                                X                                X                    60.702—Reduce emis-        CAA section
                                                       part RRR.                                                                                                                                              sions of TOC by           111(h)(3) allows
                                                                                                                                                                                                              98%, or combust in a      for AMEL.
                                                                                                                                                                                                              flare that meets the
                                                                                                                                                                                                              requirements of
                                                                                                                                                                                                              60.18.

                                                        1 EPA prepared Table 1 using the information                        based on its own review of the regulations.                                    whether Table 1 includes all of the regulatory
                                                      provided in the requests, corrected as appropriate                    However, the EPA has not independently verified                                requirements with which these plants must comply.



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                                                      8026                      Federal Register / Vol. 80, No. 30 / Friday, February 13, 2015 / Proposed Rules

                                                      TABLE 1—SUMMARY OF APPLICABLE RULES THAT MAY APPLY TO VENTS STREAMS CONTROLLED BY PRESSURE-ASSISTED
                                                                                     MULTI-POINT GROUND FLARES—Continued
                                                       Applicable
                                                       rules with                                                                                                                                                                         Provisions for
                                                                         Dow propane                     Dow light hydro-                  Exxon-Mobil                    Exxon-Mobil Mont                   Emission reduction
                                                      vent streams                                                                                                                                                                     alternative means
                                                                        dehydrogenation                   carbons (LHC)                   Baytown Olefins                  Belvieu plastics                    required and
                                                        going to                                                                                                                                                                           of emission
                                                                          (PDH) plant                         plant                            plant                            plant                           rule citation
                                                         control                                                                                                                                                                            limitation
                                                         device

                                                      NESHAP           ..............................   ..............................                X                   ..............................   61.242–11(d)—flares         61.244 allows for
                                                       Subpart V.                                                                                                                                            used to comply with         AMEL; also see
                                                                                                                                                                                                             subpart V must com-         61.12(d).
                                                                                                                                                                                                             ply with 60.18.
                                                      NESHAP           ..............................                X                                X                   ..............................   61.349(a)—reduce or-        61.353 allows for
                                                       Subpart                                                                                                                                               ganic emissions vent-       AMEL; also see
                                                       FF.                                                                                                                                                   ed to control device        61.12(d).
                                                                                                                                                                                                             by 95%; a flare shall
                                                                                                                                                                                                             comply with the re-
                                                                                                                                                                                                             quirements of 60.18.
                                                      NESHAP           ..............................   ..............................                X                   ..............................   63.102, 63.113,             63.102(b) allows
                                                       Subparts                                                                                                                                              63.126—Reduce               for AMEL.
                                                       F, G.                                                                                                                                                 emissions of Total
                                                                                                                                                                                                             Organic HAP
                                                                                                                                                                                                             (TOHAP) by 98%, or
                                                                                                                                                                                                             combust in a flare
                                                                                                                                                                                                             that meets the re-
                                                                                                                                                                                                             quirements of
                                                                                                                                                                                                             63.11(b).
                                                                                                                                                                                                           63.120—Combust in
                                                                                                                                                                                                             flare meeting 63.11.
                                                                                                                                                                                                             63.139—Reduce
                                                                                                                                                                                                             emissions of TOHAP
                                                                                                                                                                                                             by 95%, or combust
                                                                                                                                                                                                             in a flare that meets
                                                                                                                                                                                                             the requirements of
                                                                                                                                                                                                             63.11(b). 63.145(j)—
                                                                                                                                                                                                             Points to sections of
                                                                                                                                                                                                             63.11(b) for flare con-
                                                                                                                                                                                                             trol.
                                                      NESHAP                        X                   ..............................                X                   ..............................   63.172—Reduce or-           63.177 allows for
                                                       Subpart H.                                                                                                                                            ganic HAP or VOC            AMEL.
                                                                                                                                                                                                             by 95%; flares used
                                                                                                                                                                                                             to comply must meet
                                                                                                                                                                                                             requirements of
                                                                                                                                                                                                             63.11(b).
                                                      NESHAP                        X                                X                                X                                X                   63.982(b) and               CAA section
                                                       Subpart                                                                                                                                               63.987(a) require that     112(h)(3) allows
                                                       SS.                                                                                                                                                   a flare meets the re-      for AMEL.
                                                                                                                                                                                                             quirements in
                                                                                                                                                                                                             63.11(b).
                                                      NESHAP           ..............................                X                   ..............................   ..............................   63.1034—Nonflare con-       63.1021 allows for
                                                       Subpart                                                                                                                                               trol devices shall re-      AMEL.
                                                       UU.                                                                                                                                                   duce emissions by
                                                                                                                                                                                                             95%; flares shall
                                                                                                                                                                                                             comply with subpart
                                                                                                                                                                                                             SS.
                                                      NESHAP           ..............................                X                   ..............................   ..............................   63.1091 requires com-       61.353 allows for
                                                       Subpart                                                                                                                                               pliance with subpart        AMEL; also see
                                                       XX.                                                                                                                                                   FF, which requires          61.12(d).
                                                                                                                                                                                                             compliance with
                                                                                                                                                                                                             60.18.
                                                      NESHAP           ..............................                X                                X                   ..............................   Table 7 references sub-     63.1113 allows for
                                                       Subpart                                                                                                                                               part SS, which re-          AMEL.
                                                       YY.                                                                                                                                                   quires compliance
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                                                                                                                                                                                                             with 60.18.
                                                      NESHAP           ..............................   ..............................                X                                X                   63.2378(a) references       63.2346(g) allows
                                                       Subpart                                                                                                                                               subpart SS, which re-       for AMEL; also
                                                       EEEE.                                                                                                                                                 quires compliance           see Table 12
                                                                                                                                                                                                             with 60.18.                 which makes
                                                                                                                                                                                                                                         63.6(g) applica-
                                                                                                                                                                                                                                         ble to this sub-
                                                                                                                                                                                                                                         part.




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                                                                               Federal Register / Vol. 80, No. 30 / Friday, February 13, 2015 / Proposed Rules                                                                         8027

                                                      TABLE 1—SUMMARY OF APPLICABLE RULES THAT MAY APPLY TO VENTS STREAMS CONTROLLED BY PRESSURE-ASSISTED
                                                                                     MULTI-POINT GROUND FLARES—Continued
                                                       Applicable
                                                       rules with                                                                                                                                                           Provisions for
                                                                          Dow propane              Dow light hydro-                  Exxon-Mobil                    Exxon-Mobil Mont        Emission reduction
                                                      vent streams                                                                                                                                                       alternative means
                                                                         dehydrogenation            carbons (LHC)                   Baytown Olefins                  Belvieu plastics         required and
                                                        going to                                                                                                                                                             of emission
                                                                           (PDH) plant                  plant                            plant                            plant                rule citation
                                                         control                                                                                                                                                              limitation
                                                         device

                                                      NESHAP                      X               ..............................   ..............................          X             63.2450 requires com-          63.2540 and Table
                                                       Subpart                                                                                                                             pliance with limits in         12 allow for
                                                       FFFF.                                                                                                                               Tables 1–7, which in-          AMEL by mak-
                                                                                                                                                                                           clude reducing total           ing 63.6(g) appli-
                                                                                                                                                                                           organic HAP in vent            cable to this
                                                                                                                                                                                           streams by either              subpart.
                                                                                                                                                                                           95% or 98%, and
                                                                                                                                                                                           provide an option for
                                                                                                                                                                                           control using a flare
                                                                                                                                                                                           meeting requirements
                                                                                                                                                                                           of 63.982(b) which
                                                                                                                                                                                           requires meeting
                                                                                                                                                                                           63.987, which re-
                                                                                                                                                                                           quires a flare to meet
                                                                                                                                                                                           the requirements of
                                                                                                                                                                                           63.11(b).



                                                         As shown in Table 1, the applicable                          proper combustion. Proper combustion                              per second. The exit velocities from
                                                      rules require that control devices                              for flares is considered to be 98 percent                         MPGF typically range from 600 feet per
                                                      achieve destruction efficiencies of either                      destruction efficiency or greater for                             second up to sonic velocity (which
                                                      95 percent or 98 percent either directly,                       HAPs and VOCs, as discussed in our                                ranges from 700 to 1,400 feet per second
                                                      or by reference, or allow control by                            recent proposal titled ’’Petroleum                                for common hydrocarbon gases), or
                                                      flares meeting the flare operating                              Refinery Sector Risk and Technology                               Mach =1 conditions. As a result, Dow
                                                      requirements in 40 CFR 60.18 or 63.11.                          Review and New Source Performance                                 and ExxonMobil are seeking an
                                                      The flare operating requirements in 40                          Standards,’’ 79 FR 36,880, 36,904–                                alternative means of complying with the
                                                      CFR 60.18 and 63.11 specify that flares                         36,912 (June 30, 2014).                                           flare operating requirements in 40 CFR
                                                      shall be: (1) Steam-assisted air-assisted,                         The MPGF proposed by both Dow and                              60.18 and 63.11; specifically, the exit
                                                      or non-assisted; 2 (2) operated at all                          ExxonMobil are conceptually similar yet                           velocity requirements in 40 CFR
                                                      times when emissions may be vented to                           inherently different in both flare head                           60.18(c)(3), (c)(4), and (c)(5) and in 40
                                                      them; (3) designed for and operated                             design and operation than the more                                CFR 63.11(b)(6),(b)(7) and (b)(8).
                                                      with no visible emissions (except for                           traditional steam-assisted, air-assisted
                                                      periods not to exceed a total of 5                              and non-assisted flare types currently                            B. Alternative Means of Emission
                                                      minutes during any 2 consecutive                                able to comply with the flare operating                           Limitation
                                                      hours); and (4) operated with the                               requirements in 40 CFR 60.18 or 63.11.                               As noted in Table 1, the specific rules
                                                      presence of a pilot flame at all times.                         The MPGF technology operates by using                             in 40 CFR parts 60, 61 and 63, or the
                                                      The flare operating requirements in 40                          the pressure upstream of each                                     General Provisions for parts 60, 61 and
                                                      CFR 60.18 and 63.11 also specify                                individual flare tip burner to enhance                            63 of the CAA 4 allow a facility to
                                                      requirements for both the minimum                               mixing with air at the flare tip due to                           request an AMEL. These provisions
                                                      heat content of gas combusted in the                            high exit velocity, which allows the                              allow the Administrator to permit the
                                                      flare and the maximum exit velocity at                          MPGF to operate with smokeless                                    use of an alternative means of
                                                      the flare tip.3 These provisions specify                        burning. The MPGF are constructed                                 complying with an applicable standard,
                                                      maximum flare tip velocities based on                           differently than normal elevated flares                           if the requestor demonstrates that the
                                                      flare type (non-assisted, steam-assisted                        in that they consist of many rows of                              alternative achieves at least an
                                                      or air-assisted) and the net heating value                      individual flare tips which are                                   equivalent reduction in emissions. The
                                                      of the flare vent gas (see 40 CFR                               approximately 8 feet above ground                                 EPA must provide notice of the request
                                                      60.18(c)(3), 63.11(b)(6)). These                                level. The ground flare staging system                            and an opportunity for a public hearing
                                                      maximum flare tip velocities are                                opens and closes staging valves                                   on the request. After considering
                                                      required to ensure that the flame does                          according to gas pressure such that                               comments received, the EPA will issue
                                                      not ‘‘lift off’’ or separate from the flare                     stages containing multiple burners are                            a notice permitting the use of an
                                                      tip, which could cause flame instability                        activated as the flow and pressure
                                                      and/or potentially result in a portion of                       increase or decrease in the header.                                 4 CAA section 111(h)(3) states: ‘‘If after notice and
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                                                      the flare gas being released without                            While information supplied by Dow,                                opportunity for public hearing, any person
                                                                                                                      and relied on by both Dow and                                     establishes to the satisfaction of the Administrator
                                                                                                                                                                                        that an alternative means of emission limitation
                                                        2 While Dow and ExxonMobil describe their flares              ExxonMobil, indicates that the flare tips                         will achieve a reduction in emissions of any air
                                                      as ‘‘pressure-assisted,’’ these flares qualify as ‘‘non-        operate smokelessly and achieve high                              pollutant at least equivalent to the reduction in
                                                      assisted’’ flares under 40 CFR 60.18(b) or 63.11(b)             destruction efficiencies, the MPGF                                emissions of such air pollutant achieved under the
                                                      because they do not employ assist gas.                          cannot meet the exit velocity                                     requirements of paragraph (1), the Administrator
                                                        3 These requirements are not all inclusive. There                                                                               shall permit the use of such alternative by the
                                                      are other requirements in 40 CFR 60.18 and 63.11
                                                                                                                      requirements in 40 CFR 60.18 and 40                               source for purposes of compliance with this section
                                                      relating to monitoring and testing that are not                 CFR 63.11, which limit the exit velocity                          with respect to such pollutant.’’ Section 112(h)(3)
                                                      described here.                                                 at the flare tip to a maximum of 400 feet                         contains almost identical language.



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                                                      8028                    Federal Register / Vol. 80, No. 30 / Friday, February 13, 2015 / Proposed Rules

                                                      alternative means of emission                           these MPGF that can achieve the                       combustion efficiency and flame
                                                      limitation, if the Administrator                        emissions standards in the applicable                 stability as that of the John Zink burners
                                                      determines that the alternative will                    NSPS and NESHAP. These proposed                       tested, although ExxonMobil has not
                                                      achieve an equivalent reduction in                      operating requirements are contained in               supplied any data or information that
                                                      emissions.                                              Dow’s request dated August 5, 2014,                   could confirm this assertion of
                                                                                                              located in the docket for this document.              equivalency. We are requesting
                                                      II. Requests for Alternative Means of                   A summary of test data and a complete                 comment on this assertion as well as
                                                      Emission Limitation                                     copy of the emission testing report and               specifically soliciting data and
                                                      A. Dow AMEL                                             appendices are available in the docket.               comments from the public on burner
                                                         In its August 5, 2014, request, Dow                  The tests were conducted on individual                design and performance of these MPGF
                                                                                                              flare tips because it is not possible to              burners.
                                                      indicates that it plans to construct and
                                                                                                              test the full field of MPGF because of
                                                      operate two new MPGFs at its Texas                                                                            C. EPA’s Analysis of MPGF Burner
                                                                                                              the size and configuration of the full-
                                                      Operations site in Freeport, TX. One                                                                          Emission Tests
                                                                                                              scale MPGF installation (there are
                                                      MPGF would be located at Dow’s                                                                                   Dow and ExxonMobil are proposing
                                                                                                              approximately 300 flare tips in the
                                                      Propane Dehydrogenation Plant (PDH–                                                                           to follow all of the flare operating
                                                                                                              proposed array pattern that cover the
                                                      1), scheduled to start-up in early 2015                                                                       requirements contained in either 40 CFR
                                                                                                              size approximately equivalent to that of
                                                      and whose primary product is                                                                                  60.18 or 63.11, except for the exit
                                                                                                              a football field in the actual
                                                      propylene. The other MPGF would be                                                                            velocity requirements. They are
                                                                                                              installations). Although two flare tip
                                                      located at Dow’s Light Hydrocarbons                                                                           proposing to operate their high pressure
                                                                                                              types were tested during the effort, the
                                                      Plant (LHC–9), scheduled to start-up in                 results of one burner type, a steam-                  MPGFs at higher velocity than the
                                                      early 2017 and whose primary product                    assisted flare burner, John Zink model                current requirements because their data
                                                      is ethylene.                                            SKEC, are not discussed further as Dow                indicate that these burners can operate
                                                         The flare systems proposed for use by                                                                      with a stable flame at higher velocities
                                                                                                              is not seeking an AMEL for this burner
                                                      Dow at both plants consist of a staged                                                                        and still achieve good combustion and
                                                                                                              because it operates at lower velocity
                                                      design concept. The first stage, which is               and, thus, can meet the existing flare                destruction efficiencies. Instead of
                                                      not at issue nor specifically part of the               operating requirements.                               complying with the exit velocity
                                                      notice requesting an AMEL because it                                                                          requirements in 40 CFR 60.18 and
                                                      can meet the flare operating                            B. ExxonMobil AMEL                                    63.11, Dow and ExxonMobil are
                                                      requirements of 40 CFR of 60.18 and                        In its October 21, 2014, request,                  requesting that EPA grant their AMEL
                                                      63.11, is a steam-assisted ground flare                 ExxonMobil indicates it plans to                      requests to allow them to operate the
                                                      which has the primary function of                       construct and operate two MPGFs, one                  high pressure sections of their MPGFs
                                                      controlling waste gases during periods                  at its Baytown Olefins Plant (BOP) in                 such that the vent gas flowing to the
                                                      of normal operation. The remaining                      Baytown, TX, and the other at its Mont                flare tips is maintained with a net
                                                      stages consist of arrays of pressure-                   Belvieu Plastics Plant (MBPP) in Mont                 heating value that has been
                                                      assisted flare tips (the MPGFs) and will                Belview, TX. Both of the proposed                     demonstrated to be equal to or greater
                                                      control waste gases during periods of                   control strategies will be designed such              than the values that were determined to
                                                      upset, maintenance, startup and                         that vent gases are routed to either a low            achieve a reduction in emissions of
                                                      shutdown (high-pressure, high flow                      pressure system, or in infrequent cases               pollutants being controlled by a steam-
                                                      periods). Pressure-assisted flares are                  where high-pressure/high flow events                  assisted, air-assisted or non-assisted
                                                      also known as sonic flares because the                  occur, the high pressure MPGF. Both                   flare complying with the requirements
                                                      exit velocity during periods of high-                   low pressure control systems at the BOP               of either 40 CFR 63.11(b) or 40 CFR
                                                      pressure feeds is at sonic velocities.                  and MBPP consist of an elevated flare,                60.18(b) during the burner emission
                                                         At Dow, Stage 1 is the low pressure                  but the MBPP low pressure control                     tests.
                                                      stage in which the flare acts as a steam-               system also consists of three flameless                  In the emission tests, the high
                                                      assisted flare. Stages 2 and beyond are                 thermal oxidizers. The elevated flares at             pressure burners were subjected to a
                                                      activated for high-pressure/high exit                   both the BOP and MBPP will comply                     number of different operating
                                                      velocity flows. The flare system is                     with 40 CFR 60.18 and/or 40 CFR 63.11,                conditions, and each set of conditions
                                                      surrounded by a panel type fence to                     as applicable.                                        represented a separate test series. For
                                                      protect nearby workers from the radiant                    ExxonMobil did not supply any                      purposes of this discussion, the relevant
                                                      heat from the flare system. At various                  additional test data, but rather is relying           test results are those from Dow’s 2013
                                                      times ranging from 2 hours for startup                  on a series of publically available MPGF              test report, which are comprised of runs
                                                      of processing equipment to 160 hours                    emissions tests, among them the 2013                  from test series P1 through P4 and were
                                                      for a complete plant shutdown, Dow                      test submitted by Dow, a 2012 test done               tested on John Zink’s pressure assisted
                                                      will have emissions from the MPGF for                   by Marathon Petroleum Corporation, LP,                flare burner model LRGO–HC, as well as
                                                      the following maintenance, start-up and                 a 2006 pipeline burner test done by                   emissions data reported in Marathon’s
                                                      shutdown (MSS) activities: Perform                      Dow, and two earlier tests conducted by               2012 test report, which are from test
                                                      plant start-up and shutdown, process                    the EPA in the 1980s. ExxonMobil                      series PA1 and PA2 and were tested on
                                                      equipment startup and shutdown, off-                    indicates that the BOP and MBPP                       John Zink’s pressure assisted flare
                                                      spec flaring, non-routine clearing and                  burner tip designs will have comparable               burner model LRGO–D. These tests used
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                                                      commissioning of process equipment                      performance to the burners recently                   the analytical technique of passive
                                                      and piping, fuel purging and flaring to                 tested and submitted December 14,                     fourier transform infrared (PFTIR)
                                                      maintain pressure of the net-gas system.                2014, supplemental application                        spectroscopy to assess combustion
                                                         Dow conducted testing on the two                     containing additional information on                  efficiency. Dow’s 2013 test report also
                                                      types of individual flare tips in its                   plans to use the John Zink LRGO                       presents data collected using an
                                                      MPGF design to demonstrate that the                     burners for the MPGF installation at the              extractive method where flue gas was
                                                      MPGF can achieve good combustion                        MBPP, and ZEECO burners at the BOP.                   extracted from a collection hood that
                                                      efficiency under certain conditions and                 ExxonMobil asserts that the ZEECO                     was suspended above the burner tip and
                                                      has proposed operating requirements for                 burner design provides equivalent                     analyzed using standard EPA methods.


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                                                                              Federal Register / Vol. 80, No. 30 / Friday, February 13, 2015 / Proposed Rules                                          8029

                                                      The Marathon 2012 test report (see                      were generated for the different flare                scf, we believe it is important to
                                                      ‘‘Performance Test of Steam-Assisted                    heads (burners) tested over a range of                consider both types of operating limits.
                                                      and Pressure-Assisted Ground Flare                      differing exit velocities and flare gas net              Our review indicates that the LRGO
                                                      Burners with Passive FTIR—Garyville’’)                  heating values. When comparing the                    burners tested achieve a high level of
                                                      and the Dow 2013 test report (see                       current maximum flare tip velocity                    combustion efficiency when the lower
                                                      ‘‘Report on Emissions Testing of                        requirements in the general provisions                flammability limit of waste gases burned
                                                      Pressure Assisted LRGO–HC and Steam                     with those tested on pressure-assisted                in the flare is less than 6.5 volume
                                                      Assisted SKEC Burners’’) are provided                   flare burners, this conclusion still holds            percent (vol%) LFL or above 800 BTU/
                                                      in the docket.                                          true. The agency’s current requirements               scf. We suggest the 6.5 vol% LFL based
                                                         The results of the PFTIR testing                     would require that flares meet an                     on the flammability of the stream during
                                                      indicated that when a flame was present                 increasing minimum net heating value                  the flame out conditions experienced
                                                      on the pressure-assisted flare burners                  with increasing velocity, all the way up              during the high pressure test run P2H1
                                                      tested that an average combustion                       to a minimum waste gas net heating                    (at 6.6 vol% LFL). The corresponding
                                                      efficiency of 99 percent or greater was                 value of 1,000 BTU/scf and maximum                    BTU content of the waste gas at this
                                                      always achieved. Each set of operating                  velocity of 400 feet per second.                      value was 789 BTU/scf (according to
                                                      conditions tested by both Dow and                       However, the recent test reports on                   Dow, the gas chromatograph analysis
                                                      Marathon for both combustion                            pressure-assisted burners show that                   indicated this value was 746 BTU/scf,
                                                      efficiency and flame stability generally                flame stability can be achieved at                    although the John Zink report based on
                                                      consisted of a series of triplicate runs.               significantly higher velocities (i.e., sonic          measured flow rates indicated it was
                                                      In all, a total of 34 test runs were                    velocity) with waste gas net heating                  789 BTU/scf). Dow’s proposed operating
                                                      analyzed from these two tests (21 from                  values below 1,000 BTU/scf. The second                conditions included startup/shutdown
                                                      Dow’s P1 through P3 test series and 13                  general conclusion made from EPA’s                    cases where the waste gas heat content
                                                      from Marathon’s PA1 and PA2 test                        1985 study is that ‘‘stable flare flames              could be as low as 690 BTU/scf and as
                                                      series). For test series P4, which was                  and high (>98–99) combustion and                      high as 6.9 vol% LFL, and data from
                                                      conducted as part of Dow’s 2013 test                    destruction efficiencies are attained                 these tests indicate that good
                                                      using a 90 volume percent hydrogen/10                   when flares are operated within                       combustion can occur at these
                                                      volume percent natural gas mixture, no                  operating envelopes specific to each                  conditions. However, to establish the
                                                      combustion efficiency test was                          flare burner and gas mixture tested.                  alternative operating requirements at a
                                                      conducted; instead, a qualitative                       Operation beyond the edge of the                      level that ensures good combustion and
                                                      indication that the flame was stable at                 operating envelope can result in rapid                flame stability at all times under all
                                                      the conditions tested was made. We                      flame de-stabilization and a decrease in              operating conditions, we believe it is
                                                      note that in Dow’s 2013 test report that                combustion and destruction                            reasonable to establish the heat content
                                                      three of the 21 test runs were aborted                  efficiencies.’’ The data where flameout               requirements for BTU/scf above which
                                                      because of loss of flame (which we refer                of the burners occurred from test runs                there were no flame out observations.
                                                      to as flameout); only two of the three                  in both the Marathon 2012 test report                 For LFL, that level would be set below
                                                      test runs (one in the P2H series and one                and the Dow 2013 test report showed                   which there are no flame out
                                                      in the P2L series) produced enough                      that the flare operating envelope was                 observations. This is because gas
                                                      information before flameout to be                       different for the different gas mixtures              mixtures with a relatively high LFL are
                                                      analyzed in more detail. We requested                                                                         less flammable when released to the air
                                                                                                              tested. Additionally, it was observed
                                                      more detailed information from Dow on                                                                         than mixtures with a relatively low LFL.
                                                                                                              that combustion degradation beyond the
                                                      the conditions that resulted in this loss                                                                     A gas mixture with a relatively high LFL
                                                                                                              edge of the operating envelope for
                                                      of flame as it informs us of the                                                                              requires a larger volume of the mixture
                                                                                                              pressure-assisted MPGF burners was so
                                                      conditions that would create a failure of                                                                     to burn in a specific volume of air, than
                                                                                                              rapid that when a flame was present, the
                                                      the burners to sustain a stable flame and                                                                     would a mixture of gases with a
                                                                                                              flare would still achieve a high level of
                                                      achieve good combustion. This                                                                                 relatively low LFL being combusted in
                                                                                                              combustion efficiency right up until the
                                                      document is included in the docket                                                                            that same volume of air. We believe the
                                                                                                              point of flameout.
                                                      titled ‘‘Supplement 1 to Dow report.’’                                                                        flame out observations establish the
                                                      Additionally, we also note that in                         In order to assess the proper operating            limiting case because a flameout is a
                                                      Marathon’s 2012 test report that two of                 envelope for these flare types, the EPA               complete failure of the burner,
                                                      the 13 test runs also experienced loss of               evaluated both the net heating value (in              indicating zero-percent combustion.
                                                      flame (test PA1 Runs 4(2) and 4(4)). The                BTU/scf), which is how the 40 CFR part                Because of the quantity of waste gases
                                                      results of all of these test runs are                   60 and 63 General Provisions currently                potentially flared in the high-pressure
                                                      discussed in the memorandum titled                      address combustion zone properties, as                zones of these MPGF, we believe it
                                                      ‘‘Review of Available Test Data on                      well as the lower flammability limit                  would be prudent to establish limits on
                                                      Multipoint Ground Flares,’’ located in                  (LFL) because the LFL may be a better                 the conservative side to prevent air
                                                      the docket.                                             indicator of performance than net                     emissions of unburned waste gas.
                                                         There are two general conclusions                    heating value for some flare vent gas                    We also reviewed whether we should
                                                      from these test reports that are                        streams, notably those with the                       consider velocity or burner operating
                                                      consistent with the earlier EPA 1985                    potential for high hydrogen content.                  pressure in describing conditions that
                                                      study done on pressure-assisted flares                  Hydrogen is relatively flammable, but                 should be met during the MPGF
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                                                      (see conclusions on pages 2–19 and 2–                   its net heating value is low on a BTU/                operation and whether we should
                                                      22 in September 1985 EPA report titled                  scf basis when compared to other                      require some testing to ensure that the
                                                      ‘‘Evaluation of the efficiency of                       hydrocarbons. By using LFL, we                        individual burners will ignite properly
                                                      industrial flares: Flare head design and                eliminate the need to correct the                     when a new stage goes into service. Dow
                                                      gas composition’’). The first is that                   hydrogen heat content or to select a                  provided information on its process
                                                      ‘‘flare head design can influence the                   lower BTU/scf limit for high hydrogen                 control system and indicated that cross-
                                                      flame stability curve.’’ This is evident in             cases. Although Dow has requested                     light testing (testing of burner ignition
                                                      Figures 2–3 and 2–5 of the 1985 EPA                     operating limits in the form of BTU/scf               from pilots) of individual burners at its
                                                      report where different stability curves                 and has presented the test data in BTU/               off-site test facility has been conducted


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                                                      8030                    Federal Register / Vol. 80, No. 30 / Friday, February 13, 2015 / Proposed Rules

                                                      and the burners performed as expected.                  volume under all conditions. We would                 of their own AMELs. As noted in
                                                      This discussion, titled ‘‘Process control               expect owners or operators to calculate               section II.B above, we also solicit
                                                      system overview-multipoint ground                       NHVcz and LFLcz in a manner similar to                comment and data on other pressure-
                                                      flare system,’’ is in the docket for this               those in the currently proposed                       assisted flare burner types. Commenters
                                                      action. At this time, we are not                        requirements of 79 FR 36980–40 CFR                    should include data or specific
                                                      considering any requirements for                        63.670(l)–(m).                                        examples in support of their comments.
                                                      additional process control or ignition                     2. The flare system must be operated                 Dated: February 3, 2015.
                                                      testing. However, we believe it would be                with a flame present at all times when
                                                                                                                                                                    Janet G. McCabe,
                                                      important to require that cameras are                   in use. Each row of flare burners must
                                                                                                              have at least one pilot with a constant               Acting Assistant Administrator.
                                                      installed and operated such that
                                                      operators have a visual indication of                   pilot flame. The pilot flame(s) must be               [FR Doc. 2015–03064 Filed 2–12–15; 8:45 am]
                                                      flames from the flare at all times that the             continuously monitored by a                           BILLING CODE 6560–50–P
                                                      MPGF is operating and that this footage                 thermocouple. The time, date and
                                                      be available for inspection by the                      duration of any loss of pilot flame must
                                                      permitting agency, along with                           be recorded. Each monitoring device                   DEPARTMENT OF HEALTH AND
                                                      operational records of the waste gas                    must be maintained or replaced at a                   HUMAN SERVICES
                                                      flowrate, pressure in header and stages,                frequency in accordance with the
                                                      pilot and waste gas composition.                        manufacturer’s specifications.                        National Institutes of Health
                                                         Because these flares are located at                     3. The flare system must be operated
                                                      ground level, it is possible that ambient               with no visible emissions except for                  42 CFR Part 11
                                                      concentrations of pollutants could be                   periods not to exceed a total of 5                    [Docket Number NIH–2011–0003]
                                                      higher than they would be under an                      minutes during any 2 consecutive
                                                      alternative scenario where waste gases                  hours. A video camera can be used in                  RIN 0925–AA52
                                                      would be flared in an elevated flare,                   order to conduct visible emission
                                                      enabling greater dispersion and                         observations since operating personnel                Clinical Trials Registration and Results
                                                      potentially lessening the impact to                     cannot enter the fenced area while the                Submission
                                                      neighboring communities. To that end,                   MPGF is operating.                                    AGENCY:  National Institutes of Health,
                                                      we are soliciting comment on whether                       4. The operator must install and                   Department of Health and Human
                                                      additional ambient monitoring is                        operate an on-line vent gas flow meter                Services.
                                                      warranted to provide for immediate                      and an on-line gas chromatograph to
                                                                                                                                                                    ACTION: Proposed rule; extension of
                                                      notification to emergency planning                      measure the flow and composition of
                                                                                                              the vent gas to each flare. We would                  comment period; request for comments.
                                                      officials and the community during
                                                      significant events and malfunctions of                  expect the operator to comply with                    SUMMARY:   The Department of Health and
                                                      the system.                                             similar monitoring and testing                        Human Services (HHS) is extending the
                                                                                                              requirements and recordkeeping and                    public comment period for the Notice of
                                                      III. AMEL for Pressure-Assisted MPGF                    reporting requirements for these                      Proposed Rulemaking (NPRM) on
                                                         Considering the above requests from                  monitoring systems as currently                       Clinical Trials Registration and Results
                                                      both Dow and ExxonMobil, we are                         proposed in 79 FR 36980–40 CFR                        Submission. The proposed rule was
                                                      seeking the public’s input on the                       63.670(i)–(j) and (l)–(m).                            published on November 21, 2014 (79 FR
                                                      operating requirements for the proposed                    5. The operator should install and                 69566) with a deadline for public
                                                      pressure-assisted MPGFs that would be                   operate pressure and/or flow monitors                 comments of February 19, 2015. The
                                                      used by both companies which would                      on each stage of the flare. We would                  comment period is being extended to
                                                      establish an AMEL that will achieve a                   expect the operator to comply with                    provide additional time for commenters
                                                      reduction in emissions at least                         similar applicable monitoring and                     to prepare their responses. The
                                                      equivalent to the reduction in emissions                testing requirements and recordkeeping                comment period will close at 5 p.m.
                                                      being controlled by a steam-assisted, air-              and reporting requirements for these                  Eastern Standard Time (EST) on March
                                                      assisted or non-assisted flare complying                monitoring systems as currently                       23, 2015.
                                                      with the requirements of either 40 CFR                  proposed in 79 FR 36980–40 CFR
                                                      63.11(b) or 40 CFR 60.18(b). Information                                                                      DATES: Comments on the NPRM must be
                                                                                                              63.670(i).
                                                      provided in the AMEL requests and the                                                                         received before 5 p.m. EST on March 23,
                                                      available emissions test data from the                  IV. Request for Comments                              2015 in order to ensure we will be able
                                                      test reports described above indicate                      We solicit comments on all aspects of              to consider the comments when
                                                      that the following list of operating                    these requests for an AMEL. We                        preparing the final rule and policy.
                                                      requirements for pressure-assisted                      specifically seek comment regarding                   ADDRESSES: Individuals and
                                                      MPGF result in destruction efficiencies                 whether or not the potential alternative              organizations interested in submitting
                                                      at least equivalent to destruction                      operating requirements listed in section              comments on the NPRM, identified by
                                                      efficiencies expected from complying                    III above would be adequate for                       RIN 0925–AA52 and Docket Number
                                                      with the requirements of 40 CFR                         ensuring that the MPGF will achieve                   NIH–2011–0003, may do so by any of
                                                      63.11(b) and 40 CFR 60.18(b) for the                    good combustion at all times and enable               the following methods:
                                                      pressure-assisted MPGF being proposed                   the facilities to meet their applicable                 • Electronic Submissions: Use
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                                                      for use by both Dow and ExxonMobil:                     emission standards. Additionally,                     Federal eRulemaking Portal: http://
                                                         1. The flare system must be designed                 several other entities have indicated to              www.regulations.gov. Follow the
                                                      and operated such that the net heating                  us that they intend to make similar                   instructions for submitting comments.
                                                      value of the combustion zone gas                        requests for the ability to operate                   NIH is no longer accepting comments
                                                      (NHVcz) for the pressure assisted flare                 pressure-assisted MPGFs. We are also                  submitted directly by email. The NIH
                                                      burners meets a minimum heating value                   soliciting comment on whether the                     encourages you to continue to submit
                                                      of 800 BTU/scf or a lower flammability                  requirements listed above, if followed                electronic comments by using the
                                                      limit of the combustion zone gas (LFLcz)                by these other entities, could enable                 Federal eRulemaking Portal: http://
                                                      of less than or equal to 6.5 percent by                 these other facilities to receive approval            www.regulations.gov.


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Document Created: 2015-12-18 13:17:39
Document Modified: 2015-12-18 13:17:39
CategoryRegulatory Information
CollectionFederal Register
sudoc ClassAE 2.7:
GS 4.107:
AE 2.106:
PublisherOffice of the Federal Register, National Archives and Records Administration
SectionProposed Rules
ActionRequest for comments.
DatesComments. Written comments must be received on or before March 30, 2015.
ContactFor questions about this proposed action, contact Ms. Brenda Shine, Sector Policies and Programs Division (E143-01), Office of Air Quality Planning and Standards (OAQPS), U.S. Environmental Protection Agency, Research Triangle Park, North Carolina 27711; telephone number: (919) 541-3608; fax number: (919) 541-0246;
FR Citation80 FR 8023 
CFR Citation40 CFR 60
40 CFR 61
40 CFR 63

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