83_FR_50219 83 FR 50026 - Protection of Stratospheric Ozone: Determination 34 for Significant New Alternatives Policy Program

83 FR 50026 - Protection of Stratospheric Ozone: Determination 34 for Significant New Alternatives Policy Program

ENVIRONMENTAL PROTECTION AGENCY

Federal Register Volume 83, Issue 193 (October 4, 2018)

Page Range50026-50035
FR Document2018-21463

This determination of acceptability expands the list of acceptable substitutes pursuant to the U.S. Environmental Protection Agency's (EPA) Significant New Alternatives Policy (SNAP) program. This action lists as acceptable additional substitutes for use in the refrigeration and air conditioning, foam blowing, fire suppression, cleaning solvents, and aerosols sectors.

Federal Register, Volume 83 Issue 193 (Thursday, October 4, 2018)
[Federal Register Volume 83, Number 193 (Thursday, October 4, 2018)]
[Rules and Regulations]
[Pages 50026-50035]
From the Federal Register Online  [www.thefederalregister.org]
[FR Doc No: 2018-21463]


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ENVIRONMENTAL PROTECTION AGENCY

40 CFR Part 82

[EPA-HQ-OAR-2003-0118; FRL-9984-77-OAR]
RIN 2060-AG12


Protection of Stratospheric Ozone: Determination 34 for 
Significant New Alternatives Policy Program

AGENCY: Environmental Protection Agency (EPA).

ACTION: Determination of acceptability.

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SUMMARY: This determination of acceptability expands the list of 
acceptable substitutes pursuant to the U.S. Environmental Protection 
Agency's (EPA) Significant New Alternatives Policy (SNAP) program. This 
action lists as acceptable additional substitutes for use in the 
refrigeration and air conditioning, foam blowing, fire suppression, 
cleaning solvents, and aerosols sectors.

DATES: This determination is applicable on October 4, 2018.

ADDRESSES: EPA established a docket for this action under Docket ID No. 
EPA-HQ-OAR-2003-0118 (continuation of Air Docket A-91-42). All 
electronic documents in the docket are listed in the index at 
www.regulations.gov. Although listed in the index, some information is 
not publicly available, i.e., Confidential Business Information (CBI) 
or other information whose disclosure is restricted by statute. 
Publicly available docket materials are available either electronically 
at www.regulations.gov or in hard copy at the EPA Air Docket (Nos. A-
91-42 and EPA-HQ-OAR-2003-0118), EPA Docket Center (EPA/DC), William J. 
Clinton West, Room 3334, 1301 Constitution Avenue NW, Washington, DC 
20460. The Public Reading Room is open from 8:30 a.m. to 4:30 p.m., 
Monday through Friday, excluding legal holidays. The telephone number 
for the Public Reading Room is (202) 566-1744, and the telephone number 
for the Air Docket is (202) 566-1742.

FOR FURTHER INFORMATION CONTACT: Gerald Wozniak by telephone at (202) 
343-9624, by email at [email protected], or by mail at U.S. 
Environmental Protection Agency, Mail Code 6205T, 1200 Pennsylvania 
Avenue NW, Washington, DC 20460. Overnight or courier deliveries should 
be sent to the office location at 1201 Constitution Avenue NW, 
Washington, DC 20004.
    For more information on the Agency's process for administering the 
SNAP program or criteria for the evaluation of substitutes, refer to 
the initial SNAP rulemaking published in the Federal Register on March 
18, 1994 (59 FR 13044). Notices and rulemakings under the SNAP program, 
as well as other EPA publications on protection of stratospheric ozone, 
are available at EPA's Ozone Layer Protection website at www.epa.gov/ozone-layer-protection including the SNAP portion at www.epa.gov/snap/.

SUPPLEMENTARY INFORMATION: 

Table of Contents

I. Listing of New Acceptable Substitutes
    A. Refrigeration and Air Conditioning
    B. Foam Blowing
    C. Fire Suppression and Explosion Protection
    D. Cleaning Solvents
    E. Aerosols
Appendix A: Summary of Decisions for New Acceptable Substitutes


[[Page 50027]]



I. Listing of New Acceptable Substitutes \1\
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    \1\ On April 27, 2018 (83 FR 18431) EPA provided information on 
the Agency's plan to address the decision of the Court of Appeals 
for the District of Columbia Circuit in the case of Mexichem Fluor, 
Inc. v. EPA. That decision vacated the 2015 Rule (80 FR 42870) ``to 
the extent it requires manufacturers to replace HFCs with a 
substitute substance'' and remanded the rule to EPA for further 
proceedings. EPA plans to issue a proposed rule to address the 
court's vacatur and remand in early 2019.
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    This action is limited to listing as acceptable additional 
substitutes for use in the refrigeration and air conditioning, foam 
blowing, fire suppression, cleaning solvents, and aerosols sectors. 
This action presents EPA's most recent decision to list as acceptable 
several substitutes throughout different SNAP end-uses. New substitutes 
are:
     R-448A in ice skating rinks (retrofit equipment only);
     R-449A in ice skating rinks (retrofit equipment only);
     R-449B in ice skating rinks (retrofit equipment only);
     R-450A in ice skating rinks (new and retrofit equipment);
     R-513A in ice skating rinks (new and retrofit equipment);
     Acetone/isopentane blend in rigid polyurethane and 
polyisocyanurate laminated boardstock;
     Powdered Aerosol E in total flooding fire suppression 
(normally occupied areas); and
     HFO-1336mzz(Z) in electronics cleaning, metals cleaning, 
and precision cleaning and aerosol solvents.
    EPA's review of certain substitutes listed in this document is 
pending for other end-uses. Listing in the end-uses and applications in 
this document does not prejudge EPA's listing decision for these 
substitutes for other end-uses. For many of the substitutes being added 
through this document to the acceptable lists for specific end-uses, 
there are other listed substitutes for the end-use whose overall risk 
is comparable except that they have a lower risk in one SNAP criterion, 
for example toxicity or global warming potential (GWP). However, for 
the end-uses addressed in this action, those alternatives have not yet 
proven feasible in those specific end-uses.
    For additional information on SNAP, visit the SNAP portion of EPA's 
Ozone Layer Protection website at: www.epa.gov/snap. Copies of the full 
lists of acceptable substitutes for ozone depleting substances (ODS) in 
all industrial sectors are available at www.epa.gov/snap/substitutes-sector. For more information on the Agency's process for administering 
the SNAP program or criteria for evaluation of substitutes, refer to 
the initial SNAP rulemaking published March 18, 1994 (59 FR 13044), 
codified at 40 CFR part 82, subpart G. SNAP decisions and the 
appropriate Federal Register citations are found at: www.epa.gov/snap/snap-regulations. Substitutes listed as unacceptable; acceptable, 
subject to narrowed use limits; or acceptable, subject to use 
conditions are also listed in the appendices to 40 CFR part 82, subpart 
G.
    The sections below discuss each substitute listing in detail. 
Appendix A contains tables summarizing this action's listing decisions. 
The statements in the ``Further Information'' column in the tables 
provide additional information but these are not legally binding under 
section 612 of the Clean Air Act (CAA). In addition, the ``Further 
Information'' column may not include a comprehensive list of other 
legal obligations you may need to meet when using the substitute. 
Although you are not required to follow recommendations in the 
``Further Information'' column of the table to use a substitute 
consistent with section 612 of the CAA, some of these statements may 
refer to obligations that are enforceable or binding under federal or 
state programs other than the SNAP program. In many instances, the 
information simply refers to standard operating practices in existing 
industry standards and/or building codes. When using these substitutes, 
EPA strongly encourages you to apply the information in this column. 
Many of these recommendations, if adopted, would not require 
significant changes to existing operating practices.
    You can find submissions to EPA for the substitutes listed in this 
document, as well as other materials supporting the decisions in this 
action, in Docket EPA-HQ-OAR-2003-0118 at www.regulations.gov.

A. Refrigeration and Air Conditioning

1. R-448A
    EPA's decision: EPA finds R-448A acceptable as a substitute for use 
in:
 Ice Skating Rinks (Retrofit Equipment Only)
    R-448A, marketed under the trade name Solstice[supreg] N-40, is a 
weighted blend of 26 percent hydrofluorocarbon (HFC)-32, which is also 
known as difluoromethane (Chemical Abstracts Service Registry Number 
[CAS Reg. No.] 75-10-5); 26 percent HFC-125, which is also known as 
1,1,1,2,2-pentafluoroethane (CAS Reg. No. 354-33-6); 21 percent HFC-
134a, which is also known as 1,1,1,2-tetrafluoroethane (CAS Reg. No. 
811-97-2); 20 percent hydrofluoroolefin (HFO)-1234yf, which is also 
known as 2,3,3,3-tetrafluoroprop-1-ene (CAS Reg. No 754-12-1); and 
seven percent HFO-1234ze(E), which is also known as trans-1,3,3,3-
tetrafluoroprop-1-ene (CAS Reg. No. 29118-24-9).
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Documentation for 
Notice 30 Listing of R-448A (N-40) in Certain Refrigeration and Air 
Conditioning End-Uses Submission Received May 29, 2014.'' EPA performed 
assessments to examine the health and environmental risks of this 
substitute. These assessments are available in Docket EPA-HQ-OAR-2003-
0118 under the following name:
 ``Risk Screen on Substitutes in Ice Skating Rinks Substitute: 
R-448A (Solstice[supreg] N-40)''
    EPA previously listed R-448A as an acceptable refrigerant in a 
number of other refrigeration and air conditioning end-uses (e.g., July 
16, 2015, 80 FR 42053; October 11, 2016, 81 FR 70029; July 21, 2017, 82 
FR 33809).
    Environmental information: R-448A has an ozone depletion potential 
(ODP) of zero. Its components, HFC-32, HFC-125, HFC-134a, HFO-1234yf, 
and HFO-1234ze(E) have GWPs of 675; 3,500; 1,430; one to four; 
2 3 and one to six; \4\ respectively. If these values are 
weighted by mass percentage, then R-448A has a GWP of about 1,390. The 
components of R-448A are excluded from the definition of volatile 
organic compounds (VOC) under CAA regulations (see 40 CFR 51.100(s)) 
addressing the development of state implementation plans (SIPs) to 
attain and maintain the National Ambient Air Quality Standards (NAAQS). 
Knowingly venting or releasing this refrigerant blend is limited by the 
venting prohibition under section 608(c)(2) of

[[Page 50028]]

the CAA, codified at 40 CFR 82.154(a)(1).
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    \2\ Hodnebrog [Oslash]., Etminan, M., Fuglestvedt, J.S., 
Marston, G., Myhre, G., Nielsen, C.J., Shine, K.P., Wallington, 
T.J.: Global Warming Potentials and Radiative Efficiencies of 
Halocarbons and Related Compounds: A Comprehensive Review, Reviews 
of Geophysics, 51, 300-378, doi:10.1002/rog.20013, 2013.
    \3\ Nielsen, O.J., Javadi, M.S., Sulbaek Andersen, M.P., Hurley, 
M.D., Wallington, T.J., Singh, R. Atmospheric chemistry of 
CF3CF=CH2: Kinetics and mechanisms of gas-
phase reactions with Cl atoms, OH radicals, and O3. 
Chemical Physics Letters 439, 18-22, 2007.
    \4\ Hodnebrog et al., 2013 and Atmospheric chemistry of trans-
CF3CH=CHF: products and mechanisms of hydroxyl radical and chlorine 
atom initiated oxidation'', M.S. Javadi, R. S[oslash]ndergaard, O.J. 
Nielsen, M.D., Hurley, and T.J. Wellington, Atmospheric Chemistry 
and Physics Discussions 8, 1069-1088, 2008.
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    Flammability information: R-448A, as formulated and even 
considering the worst-case fractionation for flammability, is not 
flammable.
    Toxicity and exposure data: Potential health effects of exposure to 
this substitute include drowsiness or dizziness. The substitute may 
also irritate the skin or eyes or cause frostbite. At sufficiently high 
concentrations, the substitute may cause irregular heartbeat. The 
substitute could cause asphyxiation if air is displaced by vapors in a 
confined space. These potential health effects are common to many 
refrigerants.
    The American Industrial Hygiene Association (AIHA) has established 
workplace environmental exposure limits (WEELs) of 1,000 ppm as an 
eight-hour time-weighted (TWA) for HFC-32, HFC-125, and HFC-134a; 500 
ppm for HFO-1234yf; and 800 ppm for HFO-1234ze(E), the components of R-
448A. The manufacturer of R-448A recommends an acceptable exposure 
limit (AEL) of 890 ppm on an 8-hour TWA for the blend. EPA anticipates 
that users will be able to meet the AIHA WEELs and manufacturer's AEL 
and address potential health risks by following requirements and 
recommendations in the manufacturer's safety data sheet (SDS), in the 
American Society for Heating, Refrigerating, and Air-Conditioning 
Engineers (ASHRAE) Standard 15, and other safety precautions common to 
the refrigeration and air conditioning industry.
    Comparison to other substitutes in this end-use: R-448A has an ODP 
of zero, comparable to or lower than other listed substitutes in this 
end-use, with ODPs ranging from zero to 0.098.
    R-448A's GWP of 1,390 is lower than or comparable to that of 
acceptable substitutes for ice skating rinks (retrofit), such as HFC-
134a, R-407C, and R-507A, with GWPs ranging from 1,430 to 3,990. R-
448A's GWP is higher than the GWPs of other acceptable substitutes for 
ice skating rinks (retrofit), including R-401A and R-401B with GWPs 
ranging from 1,182 to 1,288.
    Flammability and toxicity risks are comparable to or lower than 
flammability and toxicity risks of other available substitutes in the 
same end-use. Toxicity risks can be minimized by use consistent with 
the AIHA WEELs, ASHRAE 15 and other industry standards, recommendations 
in the manufacturer's SDS, and other safety precautions common in the 
refrigeration and air conditioning industry.
    EPA finds R-448A acceptable in the end-use listed above because it 
does not pose greater overall environmental and human health risk than 
other available substitutes in the same end-use.
2. R-449A
    EPA's decision: EPA finds R-449A acceptable as a substitute for use 
in:
 Ice Skating Rinks (Retrofit Equipment Only)
    R-449A, marketed under the trade name Opteon[supreg] XP 40, is a 
weighted blend of 24.3 percent HFC-32, which is also known as 
difluoromethane (CAS Reg. No. 75-10-5); 24.7 percent HFC-125, which is 
also known as 1,1,1,2,2-pentafluoroethane (CAS Reg. No. 354-33-6); 25.7 
percent HFC-134a, which is also known as 1,1,1,2-tetrafluoroethane (CAS 
Reg. No. 811-97-2); and 25.3 percent HFO-1234yf, which is also known as 
2,3,3,3-tetrafluoroprop-1-ene (CAS Reg. No. 754-12-1).
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Documentation for 
Notice 30 Listing of R-449A (XP40) in Certain Refrigeration and Air 
Conditioning End-Uses. SNAP Submission Received August 6, 2014.'' EPA 
performed assessments to examine the health and environmental risks of 
this substitute. These assessments are available in Docket EPA-HQ-OAR-
2003-0118 under the following name:
 ``Risk Screen on Substitutes in Ice Skating Rinks Substitute: 
R-449A (Opteon[supreg] XP40)''
    EPA previously listed R-449A as an acceptable refrigerant in a 
number of other refrigeration and air conditioning end-uses (e.g., July 
16, 2015, 80 FR 42053; October 11, 2016, 81 FR 70029; July 21, 2017, 82 
FR 33809).
    Environmental information: R-449A has an ODP of zero. Its 
components, HFC-32, HFC-125, HFC-134a, and HFO-1234yf, have GWPs of 
675; 3,500; 1,430; and one to four,\5\ respectively. If these values 
are weighted by mass percentage, then R-449A has a GWP of about 1,400. 
The components of R-449A are excluded from the definition of VOC under 
CAA regulations (see 40 CFR 51.100(s)) addressing the development of 
SIPs to attain and maintain the NAAQS. Knowingly venting or releasing 
this refrigerant blend is limited by the venting prohibition under 
section 608(c)(2) of the CAA, codified at 40 CFR 82.154(a)(1).
---------------------------------------------------------------------------

    \5\ Hodnebrog et al., 2013 and Nielsen et al., 2007. Op. cit.
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    Flammability information: R-449A, as formulated and even 
considering the worst-case fractionation for flammability, is not 
flammable.
    Toxicity and exposure data: Potential health effects of exposure to 
this substitute include drowsiness or dizziness. The substitute may 
also irritate the skin or eyes or cause frostbite. At sufficiently high 
concentrations, the substitute may cause irregular heartbeat. The 
substitute could cause asphyxiation if air is displaced by vapors in a 
confined space. These potential health effects are common to many 
refrigerants.
    The AIHA has established WEELs of 1,000 ppm as an 8-hr TWA for HFC-
32, HFC-125, and HFC-134a and 500 ppm for HFO-1234yf, the components of 
R-449A. The manufacturer of R-449A recommends an AEL of 830 ppm on an 
8-hour TWA for the blend. EPA anticipates that users will be able to 
meet each of the AIHA WEELs and the manufacturer's AEL and address 
potential health risks by following requirements and recommendations in 
the manufacturer's SDS, in ASHRAE 15, and other safety precautions 
common to the refrigeration and air conditioning industry.
    Comparison to other substitutes in this end-use: R-449A has an ODP 
of zero, comparable to or lower than the other listed substitutes in 
this end-use, with ODPs ranging from zero to 0.098.
    R-449A's GWP of 1,400 is lower than or comparable to that of 
acceptable substitutes for ice skating rinks (retrofit), such as HFC-
134a, R-407C, and R-507A with GWPs ranging from 1,430 to 3,990. R-
449A's GWP is higher than the GWPs of other acceptable substitutes for 
ice skating rinks (retrofit), including R-401A and R-401B with GWPs 
ranging from 1,182 to 1,288.
    Flammability and toxicity risks are comparable to or lower than 
flammability and toxicity risks of other available substitutes in the 
same end-uses. Toxicity risks can be minimized by use consistent with 
the AIHA WEELs, ASHRAE 15 and other industry standards, recommendations 
in the manufacturer's SDS, and other safety precautions common in the 
refrigeration and air conditioning industry.
    EPA finds R-449A acceptable in the end-use listed above because it 
does not pose greater overall environmental and human health risk than 
other available substitutes in the same end-use.
3. R-449B
    EPA's decision: EPA finds R-449B acceptable as a substitute for use 
in:

[[Page 50029]]

 Ice Skating Rinks (Retrofit Equipment Only)
    R-449B, marketed under the trade name Forane[supreg] 449B, is a 
weighted blend of 25.2 percent HFC-32, which is also known as 
difluoromethane (CAS Reg. No. 75-10-5); 24.3 percent HFC-125, which is 
also known as 1,1,1,2,2-pentafluoroethane (CAS Reg. No. 354-33-6); 27.3 
percent HFC-134a, which is also known as 1,1,1,2-tetrafluoroethane (CAS 
Reg. No. 811-97-2); and 23.2 percent HFO-1234yf, which is also known as 
2,3,3,3-tetrafluoroprop-1-ene (CAS Reg. No. 754-12-1).
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Documentation for 
Notice 32 Listing of R-449B in Refrigeration and Air Conditioning. SNAP 
Submission Received October 2, 2015.'' EPA performed assessments to 
examine the health and environmental risks of this substitute. These 
assessments are available in Docket EPA-HQ-OAR-2003-0118 under the 
following name:
 ``Risk Screen on Substitutes in Ice Skating Rinks Substitute: 
R-449B (Forane[supreg] 449B)''
    EPA previously listed R-449B as an acceptable refrigerant in a 
number of other refrigeration and air conditioning end-uses (e.g., 
October 11, 2016, 81 FR 70029; July 21, 2017, 82 FR 33809).
    Environmental information: R-449B has an ODP of zero. Its 
components, HFC-32, HFC-125, HFC-134a, and HFO-1234yf, have GWPs of 
675; 3,500; 1,430; and one to four,\6\ respectively. If these values 
are weighted by mass percentage, then R-449B has a GWP of about 1,410. 
The components of R-449B are excluded from the definition of VOC under 
CAA regulations (see 40 CFR 51.100(s)) addressing the development of 
SIPs to attain and maintain the NAAQS. Knowingly venting or releasing 
this refrigerant blend is limited by the venting prohibition under 
section 608(c)(2) of the CAA, codified at 40 CFR 82.154(a)(1).
---------------------------------------------------------------------------

    \6\ Hodnebrog et al., 2013 and Nielsen et al., 2007. Op. cit.
---------------------------------------------------------------------------

    Flammability information: R-449B, as formulated and even 
considering the worst-case fractionation for flammability, is not 
flammable.
    Toxicity and exposure data: Potential health effects of exposure to 
this substitute include drowsiness or dizziness. The substitute may 
also irritate the skin or eyes or cause frostbite. At sufficiently high 
concentrations, the substitute may cause irregular heartbeat. The 
substitute could cause asphyxiation if air is displaced by vapors in a 
confined space. These potential health effects are common to many 
refrigerants.
    The AIHA has established WEELs of 1,000 ppm as an 8-hr TWA for HFC-
32, HFC-125, and HFC-134a and 500 ppm for HFO-1234yf, the components of 
R-449B. The manufacturer of R-449B recommends an AEL of 865 ppm on an 
8-hour TWA for the blend. EPA anticipates that users will be able to 
meet each of the AIHA WEELs and the manufacturer's AEL and address 
potential health risks by following requirements and recommendations in 
the manufacturer's SDS, in ASHRAE 15, and other safety precautions 
common to the refrigeration and air conditioning industry.
    Comparison to other substitutes in this end-use: R-449B has an ODP 
of zero, comparable to or lower than the other listed substitutes in 
this end-use, with ODPs ranging from zero to 0.098.
    R-449B's GWP of 1,410 is lower than or comparable to that of 
acceptable substitutes for ice skating rinks (retrofit), such as HFC-
134a, R-407C, and R-507A with GWPs ranging from 1,430 to 3,990. R-
449B's GWP is higher than the GWPs of other acceptable substitutes for 
ice skating rinks (retrofit), including R-401A and R-401B with GWPs 
ranging from 1,182 to 1,288.
    Flammability and toxicity risks are comparable to or lower than 
flammability and toxicity risks of other available substitutes in the 
same end-use. Toxicity risks can be minimized by use consistent with 
the AIHA WEELs, ASHRAE 15 and other industry standards, recommendations 
in the manufacturer's SDS, and other safety precautions common in the 
refrigeration and air conditioning industry.
    EPA finds R-449B acceptable in the end-use listed above because it 
does not pose greater overall environmental and human health risk than 
other available substitutes in the same end-use.
4. R-450A
    EPA's decision: EPA finds R-450A acceptable as a substitute for use 
in:
 Ice Skating Rinks (New and Retrofit Equipment)
    R-450A, marketed under the trade name Solstice[supreg] N-13, is a 
weighted blend of 42 percent HFC-134a, which is also known as 1,1,1,2 
tetrafluoroethane (CAS Reg. No. 811-97-2), and 58 percent HFO-
1234ze(E), which is also known as trans-1,3,3,3-tetrafluoropro-l-ene 
(CAS Reg. No. 29118-24-9).
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Materials for 
Notice 30 Listing of R-450A in Vending Machines.'' EPA performed an 
assessment to examine the health and environmental risks of this 
substitute. This assessment is available in Docket EPA-HQ-OAR-2003-0118 
under the following name:
 ``Risk Screen on Substitutes for Use in Ice Skating Rinks 
Substitute: R-450A''
    EPA previously listed R-450A as acceptable for use as a refrigerant 
in several refrigeration and air conditioning end-uses (October 21, 
2014, 79 FR 62863; July 16, 2015, 80 FR 42053).
    Environmental information: R-450A has an ODP of zero. Its 
components, HFC-134a and HFO-1234ze(E), have GWPs of 1,430 and one to 
six,\7\ respectively. If these values are weighted by mass percentage, 
then R-450A has a GWP of about 600. The components of R-450A are both 
excluded from the definition of VOC under CAA regulations (see 40 CFR 
51.100(s)) addressing the development of SIPs to attain and maintain 
the NAAQS. Knowingly venting or releasing this refrigerant blend is 
limited by the venting prohibition under section 608(c)(2) of the CAA, 
codified at 40 CFR 82.154(a)(1).
---------------------------------------------------------------------------

    \7\ Hodnebrog et al., 2013 and Nielsen et al., 2007. Op. cit.
---------------------------------------------------------------------------

    Flammability information: R-450A, as formulated and even 
considering the worst-case fractionation for flammability, is not 
flammable.
    Toxicity and exposure data: Potential health effects of exposure to 
this substitute include drowsiness or dizziness. The substitute may 
also irritate the skin or eyes or cause frostbite. At sufficiently high 
concentrations, the substitute may cause irregular heartbeat. The 
substitute could cause asphyxiation if air is displaced by vapors in a 
confined space. These potential health effects are common to many 
refrigerants.
    The AIHA has established WEELs of 1,000 ppm and 800 ppm as an 8-
hour TWA for HFC-134a and HFO-1234ze(E), respectively, the components 
of R-450A. The manufacturer of R-450A recommends an AEL of 880 ppm on 
an 8-hour TWA for the blend. EPA anticipates that users will be able to 
meet each of the manufacturer's AEL and AIHA WEELs and address 
potential health risks by following requirements and recommendations in 
the manufacturer's SDS, in ASHRAE 15, and other safety precautions 
common to the refrigeration and air conditioning industry.

[[Page 50030]]

    Comparison to other substitutes in this end-use: R-450A has an ODP 
of zero, comparable to other listed substitutes in this end-use, with 
ODPs ranging from zero to 0.098.
    R-450A's GWP of 600 is lower than that of other acceptable 
substitutes (for new and retrofit use for ice skating rinks) such as 
HFC-134a, R-407C, and R-507A with GWPs ranging from 1,430 to 3,990. R-
450A's GWP is higher than the GWPs of other acceptable substitutes for 
new ice skating rinks, including ammonia absorption, ammonia vapor 
compression and carbon dioxide with GWPs ranging from zero to 1.
    Flammability and toxicity risks are comparable to or lower than 
flammability and toxicity risks of other available substitutes in the 
same end-use. Toxicity risks can be minimized by use consistent with 
the AIHA WEELs, ASHRAE 15, and other industry standards, 
recommendations in the manufacturer's SDS, and other safety precautions 
common in the refrigeration and air conditioning industry.
    EPA finds R-450A acceptable in the end-use listed above because it 
does not pose greater overall environmental and human health risk than 
other available substitutes in the same end-use.
5. R-513A
    EPA's decision: EPA finds R-513A acceptable as a substitute for use 
in:
 Ice Skating Rinks (New and Retrofit Equipment)
    R-513A, marketed under the trade name Opteon[supreg] XP 10, is a 
weighted blend of 44 percent HFC-134a, which is also known as 1,1,1,2 
tetrafluoroethane (CAS Reg. No. 811-97-2), and 56 percent HFO-1234yf, 
which is also known as 2,3,3,3-tetrafluoroprop-1-ene (CAS Reg. No. 754-
12-1).
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Documentation for 
Notice 30 Listing of R-513A (XP10) in Certain Refrigeration and Air 
Conditioning End-Uses. SNAP Submission Received July 24, 2014.'' EPA 
performed an assessment to examine the health and environmental risks 
of this substitute. This assessment is available in Docket EPA-HQ-OAR-
2003-0118 under the following name:
 ``Risk Screen on Substitutes for Use in Ice Skating Rinks 
Substitute: R-513A''
    EPA previously listed R-513A as acceptable for use as a refrigerant 
in several refrigeration and air conditioning end-uses (July 16, 2015, 
80 FR 42053; May 23, 2016, 81 FR 32241; July 21, 2017, 82 FR 33809).
    Environmental information: R-513A has an ODP of zero. Its 
components, HFC-134a and HFO-1234yf, have GWPs of 1,430 and one to 
four,\8\ respectively. If these values are weighted by mass percentage, 
then R-513A has a GWP of about 630. The components of R-513A are both 
excluded from the definition of VOC under CAA regulations (see 40 CFR 
51.100(s)) addressing the development of SIPs to attain and maintain 
the NAAQS. Knowingly venting or releasing this refrigerant blend is 
limited by the venting prohibition under section 608(c)(2) of the CAA, 
codified at 40 CFR 82.154(a)(1).
---------------------------------------------------------------------------

    \8\ Hodnebrog et al., 2013 and Nielsen et al., 2007. Op. cit.
---------------------------------------------------------------------------

    Flammability information: R-513A, as formulated and even 
considering the worst-case fractionation for flammability, is not 
flammable.
    Toxicity and exposure data: Potential health effects of exposure to 
this substitute include drowsiness or dizziness. The substitute may 
also irritate the skin or eyes or cause frostbite. At sufficiently high 
concentrations, the substitute may cause irregular heartbeat. The 
substitute could cause asphyxiation if air is displaced by vapors in a 
confined space. These potential health effects are common to many 
refrigerants.
    The AIHA has established WEELs of 1,000 ppm and 500 ppm as an 8-
hour TWA for HFC-134a and HFO-1234yf, respectively, the components of 
R-513A. The manufacturer of R-513A recommends an AEL of 653 ppm on an 
8-hour TWA for the blend. EPA anticipates that users will be able to 
meet each of the manufacturer's AEL and AIHA WEELs and address 
potential health risks by following requirements and recommendations in 
the manufacturer's SDS, in ASHRAE 15, and other safety precautions 
common to the refrigeration and air conditioning industry.
    Comparison to other substitutes in this end-use: R-513A has an ODP 
of zero, comparable to other listed substitutes in this end-use, with 
ODPs ranging from zero to 0.098.
    R-513A's GWP of 630 is lower than that of other acceptable 
substitutes for new and retrofit use for ice skating rinks, such as 
HFC-134a, R-407C, and R-507A with GWPs ranging from 1,430 to 3,990. R-
513A's GWP is higher than the GWPs of other acceptable substitutes for 
new ice skating rinks, including ammonia absorption, ammonia vapor 
compression and carbon dioxide with GWPs ranging from zero to 1.
    Flammability and toxicity risks are comparable to or lower than 
flammability and toxicity risks of other available substitutes in the 
same end-use. Toxicity risks can be minimized by use consistent with 
the AIHA WEELs, ASHRAE 15, and other industry standards, 
recommendations in the manufacturer's SDS, and other safety precautions 
common in the refrigeration and air conditioning industry.
    EPA finds R-513A acceptable in the end-use listed above because it 
does not pose greater overall environmental and human health risk than 
other available substitutes in the same end-use.

B. Foam Blowing

1. Acetone/Isopentane Blend
    EPA's decision: EPA finds Acetone/Isopentane blend acceptable as a 
substitute for use in:
 Rigid Polyurethane and Polyisocyanurate Laminated Boardstock
    Acetone/Isopentane, is a weighted blend of 10-30 percent acetone 
(CAS Reg. No. 67-64-1) and 70-90 percent isopentane (CAS Reg. No. 78-
78-4).
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Documentation for 
Notice 34 Listing of Acetone/Isopentane blend in rigid polyurethane and 
polyisocyanurate laminated boardstock. SNAP Submission Received August 
8, 2017.'' EPA performed an assessment to examine the health and 
environmental risks of this substitute. This assessment is available in 
Docket EPA-HQ-OAR-2003-0118 under the following name:
 ``Risk Screen on Substitutes for Use in Rigid Polyurethane and 
Polyisocyanurate Laminated Boardstock Substitute: Acetone/Isopentane 
Blend''
    EPA previously listed acetone as acceptable for use as a foam-
blowing agent in flexible polyurethane and in integral skin 
polyurethane (March 18, 1994, 59 FR 13044; February 24, 1998, 63 FR 
9151). EPA previously listed C3-C6 light saturated hydrocarbons, which 
include isopentane, as acceptable for use as a foam-blowing agent in a 
number of foam-blowing end-uses. (August 26, 1994, 59 FR 44240; April 
11, 2000, 65 FR 19327).
    Environmental information: Acetone/isopentane blend has an ODP of 
zero. Its components, acetone and isopentane, have GWPs of 0.5 and <10, 
respectively.\9\ Acetone is excluded from

[[Page 50031]]

the definition of VOC under CAA regulations (see 40 CFR 51.100(s)) 
addressing the development of SIPs to attain and maintain the NAAQS, 
while isopentane is defined as VOC under those regulations.
---------------------------------------------------------------------------

    \9\ GWP for acetone comes from IPCC, 2007. GWP for isopentane is 
estimated based on GWP of butane from IPCC, 2007 and the relative 
atmospheric lifetimes of butane and isopentane from: Safeguarding 
the Ozone Layer and the Global Climate System. IPCC/TEAP, 2005--Bert 
Metz, Lambert Kuijpers, Susan Solomon, Stephen O. Anderson, Ogunlade 
Davidson, Jose Pons, David de Jager, Tahl Kestin, Martin Manning, 
and Leo Meyer (Eds.). Cambridge University Press, UK. pp 478. 
Available from Cambridge University Press, The Edinburgh Building 
Shaftesbury Road, Cambridge CB2 2RU ENGLAND Available online at 
https://www.ipcc.ch/report/sroc.
---------------------------------------------------------------------------

    Flammability information: Acetone/isopentane blend is flammable.
    Toxicity and exposure data: Potential health effects of exposure to 
this substitute include drowsiness or dizziness. Higher concentrations 
may cause central nervous system depression and loss of consciousness. 
The substitute may also irritate the skin or eyes. The substitute could 
cause asphyxiation if air is displaced by vapors in a confined space. 
These potential health effects are common to many foam-blowing agents.
    For acetone, the Occupational Safety and Health Administration 
(OSHA) has established a permissible exposure limit (PEL) of 1000 ppm 
and the American Conference of Governmental Industrial Hygienists 
(ACGIH) has established a threshold limit value (TLV) of 750 ppm, both 
on an 8-hr TWA. For isopentane, ACGIH has established a TLV of 600 ppm 
on an 8-hr TWA. EPA anticipates that users will be able to meet the 
ACGIH's TLVs for both components and address potential health risks by 
following requirements and recommendations in the manufacturer's SDS 
and other safety precautions common to the foam-blowing industry.
    Comparison to other substitutes in this end-use: Acetone/isopentane 
blend has an ODP of zero, comparable to other listed substitutes in 
this end-use, with ODPs ranging from zero to 0.012.
    For rigid polyurethane and polyisocyanurate laminated boardstock, 
acetone/isopentane blend's GWP of <10 is comparable to the GWPs of 
other acceptable substitutes for rigid polyurethane and 
polyisocyanurate laminated boardstock, including EcomateTM, 
CO2, HFO-1336mzz(Z) and C3-C6 light saturated hydrocarbons 
with GWPs ranging from less than 1 to approximately 12.
    Flammability and toxicity risks are comparable to or lower than 
flammability and toxicity risks of other available substitutes in the 
same end-use. Toxicity risks can be minimized by use consistent with 
the ACGIH TLVs, recommendations in the manufacturer's SDS, and other 
safety precautions common in the foam-blowing industry.
    EPA finds acetone/isopentane blend acceptable in the end-use listed 
above because it does not pose greater overall environmental and human 
health risk than other available substitutes in the same end-use.

C. Fire Suppression and Explosion Protection

1. Powdered Aerosol E (FireProTM)
    EPA's decision: EPA finds Powdered Aerosol E acceptable as a 
substitute for:
 Total Flooding Uses
    Powdered Aerosol E is generated in an automated manufacturing 
process during which the chemicals, in powder form, are mixed and then 
supplied to end users as a solid contained within a fire extinguisher. 
In the presence of heat, the solid converts to an aerosol consisting 
mainly of potassium salts. EPA previously listed Powdered Aerosol E as 
acceptable subject to use conditions in areas that are not normally 
occupied (71 FR 56359; September 27, 2006). Based on a review of 
additional information from the submitter to support the safe use of 
Powdered Aerosol E in normally occupied spaces, EPA now determines that 
Powdered Aerosol E is also acceptable for use in total flooding systems 
for normally occupied spaces, and EPA is adding Powdered Aerosol E to 
the list of acceptable substitutes for total flooding uses, which would 
include both unoccupied and occupied spaces. In a subsequent rulemaking 
EPA will remove the previous listing as acceptable subject to use 
conditions. In the ``Further Information'' column of the tables 
summarizing today's listing decisions and found at the end of this 
document, we also state that use of this agent should continue to be in 
accordance with the safety guidelines in the latest edition of the 
National Fire Protection Association (NFPA) 2010 Standard for Aerosol 
Extinguishing Systems.
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Documentation for 
Notice 34 Listing of Powdered Aerosol E (FirePro) in Fire Suppression. 
SNAP Submission Received November 17, 2016.'' EPA performed an 
assessment to examine the health and environmental risks of this 
substitute. This assessment is available in Docket EPA-HQ-OAR-2003-0118 
under the following name:
 ``Risk Screen on Substitutes for Total Flooding Systems in 
Occupied Spaces Substitute: Powdered Aerosol E (FirePro)''
    Environmental information: The active ingredients of Powdered 
Aerosol E are solids both before and after use; thus, their ODP and GWP 
are both zero. The gaseous post-activation products for Powdered 
Aerosol E also have zero ODP and GWPs of 120 or less. The solid active 
ingredients and particulate post-activation products do not participate 
in atmospheric photochemical reactions and are not VOCs. The gaseous 
post-activation products are either not organic or excluded from the 
definition of VOC under CAA regulations (see 40 CFR 51.100(s)) 
addressing the development of SIPs to attain and maintain the NAAQS.
    Flammability information: Powdered Aerosol E's post-activation 
products are nonflammable.
    Toxicity and exposure data: Exposure to Powdered Aerosol E after 
activation may cause temporary, mild irritation of the mucous membrane. 
If eye or skin contact occurs, end users should flush eyes with water 
or wash skin with soap and water. If inhaled, end users should be 
removed and exposed to fresh air. Exposure to the post-discharge 
products is expected to be below the relevant workplace exposure limits 
for those compounds. Because it is housed in a hermetically sealed 
container, exposure should not occur unless the system is activated.
    The post-activation components of the proposed substitute are 
common compounds that are not expected to exceed immediately dangerous 
to life or health (IDLH) levels from the National Institute for 
Occupational Safety and Health (NIOSH) that apply to occupational and 
end use exposure.
    Information on additional safety recommendations: The discharge of 
the aerosol results in a reduction of visibility in the protected space 
due to the uniform distribution of the particulate generated. Use 
according to the NFPA 2010 Standard will reduce any safety risks due to 
reduced visibility. In addition, EPA recommends that cross-zone 
detection systems and abort switches located near an exit from the 
protected space be employed; improved detection systems within the 
protected space and manual abort switches outside of the space could 
help avoid inadvertent discharge.
    In the ``Further Information'' column of the tables summarizing 
today's listing decisions, EPA recommends the following for 
establishments manufacturing Powdered Aerosol E and

[[Page 50032]]

filling containers to be used in total flooding applications:

--Workers should use appropriate safety and protective equipment (e.g., 
protective gloves, tightly sealed goggles, protective work clothing, 
and particulate-removing respirators using NIOSH type N95 or better 
filters) consistent with OSHA guidelines.
--A local exhaust system should be installed and operated to provide 
adequate ventilation to reduce airborne exposure to Powdered Aerosol E 
constituents.
--An eye wash fountain and quick drench facility should be close to the 
production area.
--Training for safe handling procedures should be provided to all 
employees that would be likely to handle the containers of the agent or 
extinguishing units filled with the agent.
--Workers responsible for cleanup should allow particulates to settle 
before reentering area and wear appropriate personal protective 
equipment.
--All spills should be cleaned up immediately in accordance with good 
industrial hygiene practices.

    EPA expects that procedures identified in the SDS for Powdered 
Aerosol E and good manufacturing practices will be adhered to, and that 
the appropriate safety and personal protective equipment (PPE) 
consistent with OSHA guidelines will be used during installation, 
servicing, post-discharge clean-up and disposal of total flooding 
systems using Powdered Aerosol E. The manufacturer should provide 
guidance upon installation of the system regarding the appropriate time 
after which workers may re-enter the area for disposal to allow the 
maximum settling of all particulates.
    Comparison to other substitutes in this end-use: Powdered Aerosol E 
has an ODP of zero, comparable to other listed substitutes in this end-
use, with ODPs ranging from zero to 0.048.
    For total flooding agents, Powdered Aerosol E's GWP of 0 (and 1 to 
120 for certain post-activation products) is lower than that of other 
acceptable substitutes, such as HFC-227ea, other HFCs, and some HCFC 
fire suppressants, with GWPs which range from about 1,550 to 14,800. 
Other acceptable substitutes in this end-use have comparable GWPs 
ranging from zero to one, such as water, inert gases, and a number of 
other powdered aerosol fire suppressants.
    Toxicity risks can be minimized by use consistent with the NFPA 
2010 standard, recommendations in the SDS, and other safety precautions 
common in the fire suppression industry. The potential toxicity risks 
due to inhalation exposure are common to many total flooding agents, 
including those already listed as acceptable under SNAP for this same 
end-use. Powdered Aerosol E's post-activation products are 
nonflammable, as are all other available total flooding agents.
    EPA finds Powdered Aerosol E acceptable in the end-use listed above 
because it does not pose greater overall environmental and human health 
risk than other available substitutes in the same end-use.

D. Cleaning Solvents

1. HFO-1336mzz(Z)
    EPA's decision: EPA finds HFO-1336mzz(Z)) acceptable as a 
substitute for use in:

 Electronics cleaning
 Metals cleaning
 Precision cleaning

    HFO-1336mzz(Z) is also known as (Z)-1,1,1,4,4,4-hexafluoro-2-butene 
and cis-1,1,1,4,4,4-hexafluoro-2-butene (CAS Reg. No. 692-49-9).
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Documentation for 
Notice 34 Listing of HFO-1336mzz(Z) in Cleaning Solvents and Aerosol 
Solvents. SNAP Submission Received June 19, 2017.'' EPA performed an 
assessment to examine the health and environmental risks of this 
substitute. This assessment is available in Docket EPA-HQ-OAR-2003-0118 
under the following name:
 ``Risk Screen on Substitutes for Use in Cleaning Solvents 
Substitute: HFO-1336mzz(Z)''
    EPA previously listed HFO-1336mzz(Z) as acceptable for use in 
several refrigeration and air conditioning and foam-blowing end-uses 
(October 21, 2014, 79 FR 62863; July 16, 2015, 80 FR 42053; May 23, 
2016, 81 FR 32241).
    Environmental information: HFO-1336mzz(Z) has an ODP of zero. It 
has a 100-year GWP of about nine.\10\ HFO-1336mzz(Z) is a VOC, and it 
is not exempted from the definition of VOC under CAA regulation (see 40 
CFR 51.100(s)) addressing the development of SIPs to attain and 
maintain the NAAQS. EPA has issued a proposed rule that, if finalized 
as proposed, would exclude HFO-1336mzz(Z) from the definition of VOC 
under CAA regulations (see 40 CFR 51.100(s)) addressing the development 
of SIPs to attain and maintain the NAAQS (May 1, 2018; 83 FR 19026).
---------------------------------------------------------------------------

    \10\ Baasandorj, M., Ravishankara, A.R., Burkholder, J.B., 
Atmospheric Chemistry of (Z)-CF3CH[Otilde]CHCF3: OH Radical Reaction 
Rate Coefficient and Global Warming Potential, Journal of Physical 
Chemistry A, 2011, 115, 10,539-10,549, 2011.
---------------------------------------------------------------------------

    Flammability information: HFO-1336mzz(Z) is not flammable.
    Toxicity and exposure data: Potential health effects of exposure to 
this substitute include skin or eye irritation or frostbite. At 
sufficiently high concentrations, the substitute may cause irregular 
heartbeat. The substitute could cause asphyxiation if air is displaced 
by vapors in a confined space. EPA issued a Significant New Use Rule 
under the Toxic Substances Control Act on June 5, 2015, to require 
persons to submit a Significant New Use Notice to EPA at least 90 days 
before they manufacture or process HFO-1336mzz(Z) for uses other than 
those described in the Premanufacture Notice (80 FR 32003).
    EPA anticipates that HFO-1336mzz(Z) will be used consistent with 
the recommendations specified in the SDS. The WEEL committee of the 
Occupational Alliance for Risk Science (OARS) recommends a WEEL for the 
workplace of 500 ppm on an 8-hour TWA. EPA anticipates that users will 
be able to meet the WEEL and address potential health risks by 
following requirements and recommendations in the SDS and other safety 
precautions common to the cleaning solvents industry.
    Comparison to other substitutes in this end-use: HFO-1336mzz(Z) has 
an ODP of zero, comparable to other listed substitutes in this end-use, 
with ODPs ranging from zero to 0.033.
    For cleaning solvents, HFO-1336mzz(Z)'s GWP of about nine is lower 
than that of other acceptable substitutes, such as HFE-7200, HFE-7100, 
HFC-365mfc and HFC-4310mee with GWPs ranging from 59 to 1,640. HFO-
1336mzz(Z)'s GWP is higher than or comparable to the GWPs of other 
acceptable substitutes for cleaning solvents, including acetone, 
methoxytridecafluoroheptene isomers (MPHE), and trans-1-chloro-3,3,3-
trifluoroprop-1-ene with GWPs ranging from less than 1 to 7.
    Flammability and toxicity risks are comparable to or lower than 
flammability and toxicity risks of other available substitutes in the 
same end-use. Toxicity risks can be minimized by use consistent with 
the OARS WEEL, recommendations in the manufacturer's SDS, and other 
safety precautions common in the cleaning solvents industry; moreover, 
those risks are common to many cleaning solvents,

[[Page 50033]]

including many of those already listed as acceptable under SNAP for 
this end-use.
    EPA finds HFO-1336mzz(Z) acceptable in the end-uses listed above 
because it does not pose greater overall environmental and human health 
risk than other available substitutes in the same end-uses.

E. Aerosols

1. HFO-1336mzz(Z)
    EPA's decision: EPA finds HFO-1336mzz(Z) acceptable as a substitute 
for use in:
 Aerosol Solvents
    HFO-1336mzz(Z) is also known as (Z)-1,1,1,4,4,4-hexafluoro-2-butene 
and cis-1,1,1,4,4,4-hexafluoro-2-butene (CAS Reg. No. 692-49-9).
    You may find the redacted submission in Docket EPA-HQ-OAR-2003-0118 
at www.regulations.gov under the name, ``Supporting Documentation for 
Notice 34 Listing of HFO-1336mzz(Z) in Cleaning Solvents and Aerosol 
Solvents. SNAP Submission Received June 19, 2017.'' EPA performed an 
assessment to examine the health and environmental risks of this 
substitute. This assessment is available in Docket EPA-HQ-OAR-2003-0118 
under the following name:
 ``Risk Screen on Substitutes for Use in Aerosol Solvents 
Substitute: HFO-1336mzz(Z)''
    EPA previously listed HFO-1336mzz(Z) as acceptable for use in 
several refrigeration and air conditioning and foam-blowing end-uses 
(October 21, 2014, 79 FR 62863; July 16, 2015, 80 FR 42053; May 23, 
2016, 81 FR 32241).
    Environmental information: The environmental information for this 
substitute is set forth in the ``Environmental information'' section in 
listing I.D.1.
    Flammability information: HFO-1336mzz(Z) is not flammable.
    Toxicity and exposure data: The toxicity information for this 
substitute is set forth in the ``Toxicity and exposure data'' section 
in listing I.D.1, above.
    EPA anticipates that HFO-1336mzz(Z) will be used consistent with 
the recommendations specified in the SDS. The WEEL committee of the 
Occupational Alliance for Risk Science (OARS) recommends a WEEL for the 
workplace of 500 ppm on an 8-hour TWA. EPA anticipates that users will 
be able to meet the WEEL and address potential health risks by 
following requirements and recommendations in the SDS and other safety 
precautions common to the aerosols industry.
    Comparison to other substitutes in this end-use: HFO-1336mzz(Z) has 
an ODP of zero, comparable to other listed substitutes in this end-use, 
with ODPs ranging from zero to 0.033.
    For aerosol solvents, HFO-1336mzz(Z)'s GWP of about nine is lower 
than that of other acceptable substitutes, such as HFE-7200, HFE-7000, 
HFC-365mfc and HFC-4310mee with GWPs ranging from 59 to 1,640. HFO-
1336mzz(Z)'s GWP is higher than or comparable to the GWPs of other 
acceptable substitutes for aerosol solvents, including acetone, MPHE, 
and trans-1-chloro-3,3,3-trifluoroprop-1-ene with GWPs ranging from 
less than 1 to 7.
    Flammability and toxicity risks are comparable to or lower than 
flammability and toxicity risks of other available substitutes in the 
same end-use. Toxicity risks can be minimized by use consistent with 
the OARS WEEL, recommendations in the manufacturer's SDS, and other 
safety precautions common in the aerosols industry; moreover, those 
risks are common to many aerosol solvents, including many of those 
already listed as acceptable under SNAP for this end-use.
    EPA finds HFO-1336mzz(Z) acceptable in the end-use listed above 
because it does not pose greater overall environmental and human health 
risk than other available substitutes in the same end-use.

List of Subjects in 40 CFR Part 82

    Environmental protection, Administrative practice and procedure, 
Air pollution control, Reporting and recordkeeping requirements.

    Dated: September 19, 2018.
Sarah Dunham,
Director, Office of Atmospheric Programs.

Appendix A: Summary of Decisions for New Acceptable Substitutes



----------------------------------------------------------------------------------------------------------------
             End-use                    Substitute             Decision             Further Information \1\
----------------------------------------------------------------------------------------------------------------
                                       Refrigeration and Air Conditioning
----------------------------------------------------------------------------------------------------------------
Ice skating rinks (retrofit        R-448A..............  Acceptable.........  R-448A has a 100-yr global warming
 equipment only).                                                              potential (GWP) of approximately
                                                                               1,390. This substitute is a blend
                                                                               of HFC-32, which is also known as
                                                                               difluoromethane (CAS Reg. No. 75-
                                                                               10-5); HFC-125, which is also
                                                                               known as 1,1,1,2,2-
                                                                               pentafluoroethane (CAS Reg. No.
                                                                               354-33-6); HFC-134a, which is
                                                                               also known as 1,1,1,2-
                                                                               tetrafluoroethane (CAS Reg. No.
                                                                               811-97-2); HFO-1234yf, which is
                                                                               also known as 2,3,3,3-tetrafluoro-
                                                                               prop-l-ene (CAS Reg. No. 754-12-
                                                                               1); and HFO-1234ze(E), which is
                                                                               also known as trans-1,3,3,3-
                                                                               tetrafluoroprop-l-ene (CAS Reg.
                                                                               No. 29118-24-9).
                                                                              The blend is nonflammable.
                                                                              The American Industrial Hygiene
                                                                               Association (AIHA) has
                                                                               established Workplace
                                                                               Environmental Exposure Limits
                                                                               (WEELs) of 1,000 ppm on an eight-
                                                                               hour time-weighted average (8-hr
                                                                               TWA) basis for HFC-32, HFC-125,
                                                                               and HFC-134a; 500 ppm for HFO-
                                                                               1234yf; and 800 ppm for HFO-
                                                                               1234ze(E). The manufacturer
                                                                               recommends an acceptable exposure
                                                                               limit (AEL) for the workplace for
                                                                               R-448A of 890 ppm (8-hr TWA).
Ice skating rinks (retrofit        R-449A..............  Acceptable.........  R-449A has a 100-year GWP of
 equipment only).                                                              approximately 1,400. This
                                                                               substitute is a blend of HFC-32,
                                                                               which is also known as
                                                                               difluoromethane (CAS Reg. No. 75-
                                                                               10-5); HFC-125, which is also
                                                                               known as 1,1,1,2,2-
                                                                               pentafluoroethane (CAS Reg. No.
                                                                               354-33-6); HFC-134a, which is
                                                                               also known as 1,1,1,2-
                                                                               tetrafluoroethane (CAS Reg. No.
                                                                               811-97-2); and HFO-1234yf, which
                                                                               is also known as 2,3,3,3-
                                                                               tetrafluoroprop-l-ene (CAS Reg.
                                                                               No. 754-12-1).
                                                                              The blend is nonflammable.
                                                                              The AIHA has established WEELs of
                                                                               1,000 ppm (8-hr TWA) for HFC-32,
                                                                               HFC-125, and HFC-134a; and 500
                                                                               ppm for HFO-1234yf. The
                                                                               manufacturer recommends an AEL
                                                                               for the workplace for R-449A of
                                                                               830 ppm (8-hr TWA).

[[Page 50034]]

 
Ice skating rinks (retrofit        R-449B..............  Acceptable.........  R-449B has a 100-year GWP of
 equipment only).                                                              approximately 1,410. This
                                                                               substitute is a blend of HFC-32,
                                                                               which is also known as
                                                                               difluoromethane (CAS Reg. No. 75-
                                                                               10-5); HFC-125, which is also
                                                                               known as 1,1,1,2,2-
                                                                               pentafluoroethane (CAS Reg. No.
                                                                               354-33-6); HFC-134a, which is
                                                                               also known as 1,1,1,2-
                                                                               tetrafluoroethane (CAS Reg. No.
                                                                               811-97-2); and HFO-1234yf, which
                                                                               is also known as 2,3,3,3-
                                                                               tetrafluoroprop-l-ene (CAS Reg.
                                                                               No. 754-12-1).
                                                                              The blend is nonflammable.
                                                                              The AIHA has established WEELs of
                                                                               1,000 ppm (8-hr TWA) for HFC-32,
                                                                               HFC-125, and HFC-134a; and 500
                                                                               ppm for HFO-1234yf. The
                                                                               manufacturer recommends an AEL
                                                                               for the workplace for R-449B of
                                                                               865 ppm (8-hr TWA).
Ice skating rinks (new and         R-450A..............  Acceptable.........  R-450A has a 100-year GWP of
 retrofit equipment).                                                          approximately 600. This
                                                                               substitute is a blend of HFC-
                                                                               134a, which is also known as
                                                                               1,1,1,2-tetrafluoroethane (CAS
                                                                               Reg. No. 811-97-2); and HFO-
                                                                               1234ze(E), which is also known as
                                                                               trans-1,3,3,3, -tetrafluoropro-1-
                                                                               ene (CAS Reg. No. 29118-24-9).
                                                                              This blend is nonflammable.
                                                                              The AIHA has established WEELs of
                                                                               1,000 ppm and 800 ppm (8-hr TWA)
                                                                               for HFC-134a and HFO-1234yf,
                                                                               respectively. The manufacturer
                                                                               recommends an AEL for the
                                                                               workplace for R-450A of 880 ppm
                                                                               (8-hr TWA).
Ice skating rinks (new and         R-513A..............  Acceptable.........  R-513A has a 100-year GWP of
 retrofit equipment).                                                          approximately 630. This
                                                                               substitute is a blend of HFC-
                                                                               134a, which is also known as
                                                                               1,1,1,2-tetrafluoroethane (CAS
                                                                               Reg. No. 811-97-2); and HFO-
                                                                               1234yf, which is also known as
                                                                               2,3,3,3-tetrafluoroprop-l-ene
                                                                               (CAS Reg. No. 754-12-1).
                                                                              This blend is nonflammable.
                                                                              The AIHA has established WEELs of
                                                                               1,000 ppm and 500 ppm (8-hr TWA)
                                                                               for HFC-134a and HFO-1234yf,
                                                                               respectively. The manufacturer
                                                                               recommends an AEL for the
                                                                               workplace for R-513A of 653 ppm
                                                                               (8-hr TWA).
----------------------------------------------------------------------------------------------------------------
                                                  Foam Blowing
----------------------------------------------------------------------------------------------------------------
Rigid polyurethane and             Acetone/isopentane    Acceptable.........  Acetone/isopentane blend has no
 polyisocyanurate laminated         blend.                                     ozone depletion potential (ODP)
 boardstock.                                                                   and a 100-year GWP of
                                                                               approximately <10. Acetone is
                                                                               excluded from the definition of
                                                                               volatile organic compounds (VOC)
                                                                               under CAA regulations (see 40 CFR
                                                                               51.100(s)) addressing the
                                                                               development of state
                                                                               implementation plans (SIPs) to
                                                                               attain and maintain the National
                                                                               Ambient Air Quality Standards
                                                                               (NAAQS), while isopentane is
                                                                               defined as VOC.
                                                                              This foam-blowing agent is
                                                                               flammable.
                                                                              For acetone, the Occupational
                                                                               Safety and Health Administration
                                                                               (OSHA) has established a
                                                                               permissible exposure limit of
                                                                               1000 ppm and the American
                                                                               Conference of Governmental
                                                                               Industrial Hygienists (ACGIH) has
                                                                               established a threshold limit
                                                                               value (TLV) of 750 ppm, both on
                                                                               an 8-hr TWA. For isopentane,
                                                                               ACGIH has established a TLV of
                                                                               600 ppm on an 8-hr TWA.
----------------------------------------------------------------------------------------------------------------
                                                Fire Suppression
----------------------------------------------------------------------------------------------------------------
Total flooding...................  Powdered Aerosol E..  Acceptable.........  Use of this agent should be in
                                                                               accordance with the safety
                                                                               guidelines in the latest edition
                                                                               of the National Fire Protection
                                                                               Association 2010 standard for
                                                                               Aerosol Extinguishing Systems.
                                                                              For establishments manufacturing
                                                                               the agent or filling, installing,
                                                                               or servicing containers or
                                                                               systems to be used in total
                                                                               flooding applications, EPA
                                                                               recommends the following:
                                                                              --The appropriate safety and
                                                                               personal protective equipment
                                                                               (PPE) (e.g., protective gloves,
                                                                               tightly sealed goggles,
                                                                               protective work clothing, and
                                                                               particulate-removing respirators
                                                                               with National Institute for
                                                                               Occupational Safety and Health
                                                                               type N95 or better filters)
                                                                               consistent with Occupational
                                                                               Safety and Health Administration
                                                                               (OSHA) guidelines should be used
                                                                               during manufacture, installation,
                                                                               servicing, and disposal of total
                                                                               flooding systems using the agent;
                                                                              --adequate ventilation should be
                                                                               in place to reduce airborne
                                                                               exposure to constituents of
                                                                               agent;
                                                                              --an eye wash fountain and quick
                                                                               drench facility should be close
                                                                               to the production area;
                                                                              --training for safe handling
                                                                               procedures should be provided to
                                                                               all employees that would be
                                                                               likely to handle containers of
                                                                               the agent or extinguishing units
                                                                               filled with the agent;
                                                                              --workers responsible for clean-up
                                                                               should allow for maximum settling
                                                                               of all particulates before
                                                                               reentering area and wear
                                                                               appropriate personal protective
                                                                               equipment; and
                                                                              --all spills should be cleaned up
                                                                               immediately in accordance with
                                                                               good industrial hygiene
                                                                               practices.

[[Page 50035]]

 
                                                                              As required by the manufacturer,
                                                                               units installed in normally
                                                                               occupied spaces will be equipped
                                                                               with features such as a system-
                                                                               isolate switch and cross-zone
                                                                               detection system to reduce risk
                                                                               of accidental activation of an
                                                                               agent generator while persons are
                                                                               present in the protected space.
                                                                               Also required by the manufacturer
                                                                               is warning of pending discharge
                                                                               and delay in release to ensure
                                                                               egress prior to activation of the
                                                                               agent to reduce the risk of
                                                                               exposure.
                                                                              See additional comments 1, 2, 3,
                                                                               4, 5.
----------------------------------------------------------------------------------------------------------------
1. The EPA recommends that users consult Section VIII of the OSHA Technical Manual for information on selecting
  the appropriate types of personal protective equipment for all listed fire suppression agents. The EPA has no
  intention of duplicating or displacing OSHA coverage related to the use of personal protective equipment
  (e.g., respiratory protection), fire protection, hazard communication, worker training or any other
  occupational safety and health standard with respect to halon substitutes.
2. Use of all listed fire suppression agents should conform to relevant OSHA requirements, including 29 CFR part
  1910, subpart L, sections 1910.160 and 1910.162.
3. Per OSHA requirements, protective gear (SCBA) should be available in the event personnel should reenter the
  area.
4. Discharge testing should be strictly limited to that which is essential to meet safety or performance
  requirements.
5. The agent should be recovered from the fire protection system in conjunction with testing or servicing, and
  recycled for later use or destroyed.


----------------------------------------------------------------------------------------------------------------
             End-use                    Substitute             Decision             Further Information \1\
----------------------------------------------------------------------------------------------------------------
                                                Cleaning Solvents
----------------------------------------------------------------------------------------------------------------
Electronics cleaning, metals       HFO-1336mzz(Z)......  Acceptable.........  HFO-1336mzz(Z) has no ozone
 cleaning, precision cleaning.                                                 depletion potential (ODP) and a
                                                                               100-year GWP of approximately
                                                                               nine. EPA has proposed to exclude
                                                                               it from the definition of
                                                                               volatile organic compounds under
                                                                               CAA regulations (see 40 CFR
                                                                               51.100(s)) addressing the
                                                                               development of state
                                                                               implementation plans (SIPs) to
                                                                               attain and maintain the National
                                                                               Ambient Air Quality Standards
                                                                               (NAAQS).
                                                                              This compound is nonflammable.
                                                                              The Occupational Alliance for Risk
                                                                               Science (OARS) has established a
                                                                               Workplace Environmental Exposure
                                                                               Limit (WEEL) of 500 ppm (8-hr
                                                                               TWA) for HFO-1336mzz(Z).
                                                                              This substitute is subject to a
                                                                               Toxic Substance Control Act
                                                                               (TSCA) section 5(a)(2)
                                                                               Significant New Use Rule (SNUR)
                                                                               (40 CFR 721.10830).
----------------------------------------------------------------------------------------------------------------
                                                    Aerosols
----------------------------------------------------------------------------------------------------------------
Aerosol solvents.................  HFO-1336mzz(Z)......  Acceptable.........  HFO-1336mzz(Z) has no ozone
                                                                               depletion potential (ODP) and a
                                                                               100-year GWP of approximately
                                                                               nine. EPA has proposed to exclude
                                                                               it from the definition of
                                                                               volatile organic compounds under
                                                                               CAA regulations (see 40 CFR
                                                                               51.100(s)) addressing the
                                                                               development of state
                                                                               implementation plans (SIPs) to
                                                                               attain and maintain the National
                                                                               Ambient Air Quality Standards
                                                                               (NAAQS).
                                                                              This compound is nonflammable.
                                                                              The OARS has established a
                                                                               Workplace Environmental Exposure
                                                                               Limit (WEEL) of 500 ppm (8-hr
                                                                               TWA) for HFO-1336mzz(Z).
                                                                              This substitute is subject to a
                                                                               Toxic Substance Control Act
                                                                               (TSCA) section 5(a)(2)
                                                                               Significant New Use Rule (SNUR)
                                                                               (40 CFR 721.10830).
----------------------------------------------------------------------------------------------------------------
\1\ Observe recommendations in the manufacturer's SDS and guidance for all listed substitutes.

[FR Doc. 2018-21463 Filed 10-3-18; 8:45 am]
 BILLING CODE 6560-50-P



                                             50026                 Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations

                                                                                                       EPA-APPROVED IOWA NONREGULATORY PROVISIONS
                                                                                                         Applicable
                                                           Name of                                     geographic or                     State submittal
                                                         nonregulatory                                                                                                   EPA Approval date                                 Explanation
                                                                                                       nonattainment                          date
                                                         SIP provision                                     area


                                                      *                  *                   *                                                    *                          *                                *                  *
                                             (50) Lead Redesignation SIP   Portions of Pottawattamie                                            9/18/2017          10/4/2018, [Insert Federal                     [EPA–R07–OAR–2018–0532;
                                               and Maintenance Plan.         County.                                                                                 Register citation].                            FRL–9984–64–Region 7].



                                             PART 81—DESIGNATION OF AREAS                                             Authority: 42 U.S.C. 7401, et seq.                                § 81.316       Iowa.
                                             FOR AIR QUALITY PLANNING                                                                                                                   *        *        *        *       *
                                                                                                                  ■  4. In § 81.316, the table entitled
                                             PURPOSES
                                                                                                                  ‘‘Iowa-2008 Lead NAAQS’’ is amended
                                             ■ 3. The authority citation for part 81                              by revising the entry ‘‘Pottawattamie
                                             continues to read as follows:                                        County, IA:’’ to read as follows:

                                                                                                                             IOWA-2008 LEAD NAAQS
                                                                                                                                                                                                                   Designation for the 2008
                                                                                                                                                                                                                          NAAQS a
                                                                                                                Designated area
                                                                                                                                                                                                                    Date 1                Type

                                             Pottawattamie County, IA:
                                                 Pottawattamie County (part) ..............................................................................................................................            10/4/2018   Attainment.
                                                     Area bounded by Avenue G on the north, N 16th/S 16th street on the east, 23rd Avenue on the south,
                                                       and N 35th/S 35th street on the west.

                                                          *                            *                              *                            *                            *                             *                       *
                                                 a Includes
                                                          Indian Country located in each county or area, except as otherwise specified.
                                                 1 December 31, 2011 unless otherwise noted.




                                             [FR Doc. 2018–21433 Filed 10–3–18; 8:45 am]                          ADDRESSES:    EPA established a docket                                or courier deliveries should be sent to
                                             BILLING CODE 6560–50–P                                               for this action under Docket ID No.                                   the office location at 1201 Constitution
                                                                                                                  EPA–HQ–OAR–2003–0118                                                  Avenue NW, Washington, DC 20004.
                                                                                                                  (continuation of Air Docket A–91–42).                                    For more information on the Agency’s
                                             ENVIRONMENTAL PROTECTION                                             All electronic documents in the docket
                                                                                                                                                                                        process for administering the SNAP
                                             AGENCY                                                               are listed in the index at
                                                                                                                                                                                        program or criteria for the evaluation of
                                                                                                                  www.regulations.gov. Although listed in
                                             40 CFR Part 82                                                       the index, some information is not                                    substitutes, refer to the initial SNAP
                                                                                                                  publicly available, i.e., Confidential                                rulemaking published in the Federal
                                             [EPA–HQ–OAR–2003–0118; FRL–9984–77–                                  Business Information (CBI) or other                                   Register on March 18, 1994 (59 FR
                                             OAR]                                                                                                                                       13044). Notices and rulemakings under
                                                                                                                  information whose disclosure is
                                                                                                                  restricted by statute. Publicly available                             the SNAP program, as well as other EPA
                                             RIN 2060–AG12
                                                                                                                  docket materials are available either                                 publications on protection of
                                             Protection of Stratospheric Ozone:                                   electronically at www.regulations.gov or                              stratospheric ozone, are available at
                                             Determination 34 for Significant New                                 in hard copy at the EPA Air Docket                                    EPA’s Ozone Layer Protection website at
                                             Alternatives Policy Program                                          (Nos. A–91–42 and EPA–HQ–OAR–                                         www.epa.gov/ozone-layer-protection
                                                                                                                  2003–0118), EPA Docket Center (EPA/                                   including the SNAP portion at
                                             AGENCY: Environmental Protection                                     DC), William J. Clinton West, Room                                    www.epa.gov/snap/.
                                             Agency (EPA).                                                        3334, 1301 Constitution Avenue NW,
                                                                                                                  Washington, DC 20460. The Public                                      SUPPLEMENTARY INFORMATION:
                                             ACTION: Determination of acceptability.
                                                                                                                  Reading Room is open from 8:30 a.m. to                                Table of Contents
                                             SUMMARY:   This determination of                                     4:30 p.m., Monday through Friday,
                                             acceptability expands the list of                                    excluding legal holidays. The telephone                               I. Listing of New Acceptable Substitutes
                                             acceptable substitutes pursuant to the                               number for the Public Reading Room is                                    A. Refrigeration and Air Conditioning
                                             U.S. Environmental Protection Agency’s                               (202) 566–1744, and the telephone                                        B. Foam Blowing
                                             (EPA) Significant New Alternatives                                   number for the Air Docket is (202) 566–                                  C. Fire Suppression and Explosion
                                             Policy (SNAP) program. This action lists                             1742.                                                                      Protection
                                             as acceptable additional substitutes for
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                                                                                                                  FOR FURTHER INFORMATION CONTACT:                                         D. Cleaning Solvents
                                             use in the refrigeration and air                                     Gerald Wozniak by telephone at (202)                                     E. Aerosols
                                             conditioning, foam blowing, fire                                     343–9624, by email at wozniak.gerald@                                 Appendix A: Summary of Decisions for New
                                             suppression, cleaning solvents, and                                  epa.gov, or by mail at U.S.                                                Acceptable Substitutes
                                             aerosols sectors.                                                    Environmental Protection Agency, Mail
                                             DATES: This determination is applicable                              Code 6205T, 1200 Pennsylvania Avenue
                                             on October 4, 2018.                                                  NW, Washington, DC 20460. Overnight


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                                                               Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations                                              50027

                                             I. Listing of New Acceptable                            substitutes, refer to the initial SNAP                hydrofluoroolefin (HFO)-1234yf, which
                                             Substitutes 1                                           rulemaking published March 18, 1994                   is also known as 2,3,3,3-tetrafluoroprop-
                                                This action is limited to listing as                 (59 FR 13044), codified at 40 CFR part                1-ene (CAS Reg. No 754–12–1); and
                                             acceptable additional substitutes for use               82, subpart G. SNAP decisions and the                 seven percent HFO–1234ze(E), which is
                                             in the refrigeration and air conditioning,              appropriate Federal Register citations                also known as trans-1,3,3,3-
                                             foam blowing, fire suppression, cleaning                are found at: www.epa.gov/snap/snap-                  tetrafluoroprop-1-ene (CAS Reg. No.
                                             solvents, and aerosols sectors. This                    regulations. Substitutes listed as                    29118–24–9).
                                             action presents EPA’s most recent                       unacceptable; acceptable, subject to                     You may find the redacted
                                             decision to list as acceptable several                  narrowed use limits; or acceptable,                   submission in Docket EPA–HQ–OAR–
                                             substitutes throughout different SNAP                   subject to use conditions are also listed             2003–0118 at www.regulations.gov
                                             end-uses. New substitutes are:                          in the appendices to 40 CFR part 82,                  under the name, ‘‘Supporting
                                                • R–448A in ice skating rinks (retrofit              subpart G.                                            Documentation for Notice 30 Listing of
                                             equipment only);                                          The sections below discuss each                     R–448A (N–40) in Certain Refrigeration
                                                • R–449A in ice skating rinks (retrofit              substitute listing in detail. Appendix A              and Air Conditioning End-Uses
                                             equipment only);                                        contains tables summarizing this                      Submission Received May 29, 2014.’’
                                                • R–449B in ice skating rinks (retrofit              action’s listing decisions. The                       EPA performed assessments to examine
                                             equipment only);                                        statements in the ‘‘Further Information’’             the health and environmental risks of
                                                • R–450A in ice skating rinks (new                   column in the tables provide additional               this substitute. These assessments are
                                             and retrofit equipment);                                information but these are not legally                 available in Docket EPA–HQ–OAR–
                                                • R–513A in ice skating rinks (new                   binding under section 612 of the Clean                2003–0118 under the following name:
                                             and retrofit equipment);                                Air Act (CAA). In addition, the ‘‘Further
                                                                                                     Information’’ column may not include a                • ‘‘Risk Screen on Substitutes in Ice
                                                • Acetone/isopentane blend in rigid
                                                                                                     comprehensive list of other legal                     Skating Rinks Substitute: R–448A
                                             polyurethane and polyisocyanurate
                                                                                                     obligations you may need to meet when                 (Solstice® N–40)’’
                                             laminated boardstock;
                                                • Powdered Aerosol E in total                        using the substitute. Although you are
                                                                                                                                                             EPA previously listed R–448A as an
                                             flooding fire suppression (normally                     not required to follow recommendations
                                                                                                                                                           acceptable refrigerant in a number of
                                             occupied areas); and                                    in the ‘‘Further Information’’ column of
                                                                                                                                                           other refrigeration and air conditioning
                                                • HFO–1336mzz(Z) in electronics                      the table to use a substitute consistent
                                                                                                                                                           end-uses (e.g., July 16, 2015, 80 FR
                                             cleaning, metals cleaning, and precision                with section 612 of the CAA, some of
                                                                                                                                                           42053; October 11, 2016, 81 FR 70029;
                                             cleaning and aerosol solvents.                          these statements may refer to obligations
                                                                                                                                                           July 21, 2017, 82 FR 33809).
                                                EPA’s review of certain substitutes                  that are enforceable or binding under
                                                                                                     federal or state programs other than the                Environmental information: R–448A
                                             listed in this document is pending for                                                                        has an ozone depletion potential (ODP)
                                             other end-uses. Listing in the end-uses                 SNAP program. In many instances, the
                                                                                                     information simply refers to standard                 of zero. Its components, HFC–32, HFC–
                                             and applications in this document does                                                                        125, HFC–134a, HFO–1234yf, and HFO–
                                             not prejudge EPA’s listing decision for                 operating practices in existing industry
                                                                                                     standards and/or building codes. When                 1234ze(E) have GWPs of 675; 3,500;
                                             these substitutes for other end-uses. For                                                                     1,430; one to four; 2 3 and one to six; 4
                                             many of the substitutes being added                     using these substitutes, EPA strongly
                                                                                                     encourages you to apply the information               respectively. If these values are
                                             through this document to the acceptable                                                                       weighted by mass percentage, then R–
                                             lists for specific end-uses, there are                  in this column. Many of these
                                                                                                     recommendations, if adopted, would                    448A has a GWP of about 1,390. The
                                             other listed substitutes for the end-use                                                                      components of R–448A are excluded
                                             whose overall risk is comparable except                 not require significant changes to
                                                                                                     existing operating practices.                         from the definition of volatile organic
                                             that they have a lower risk in one SNAP                                                                       compounds (VOC) under CAA
                                             criterion, for example toxicity or global                 You can find submissions to EPA for
                                                                                                     the substitutes listed in this document,              regulations (see 40 CFR 51.100(s))
                                             warming potential (GWP). However, for                                                                         addressing the development of state
                                             the end-uses addressed in this action,                  as well as other materials supporting the
                                                                                                     decisions in this action, in Docket EPA–              implementation plans (SIPs) to attain
                                             those alternatives have not yet proven                                                                        and maintain the National Ambient Air
                                             feasible in those specific end-uses.                    HQ–OAR–2003–0118 at
                                                                                                     www.regulations.gov.                                  Quality Standards (NAAQS). Knowingly
                                                For additional information on SNAP,
                                                                                                                                                           venting or releasing this refrigerant
                                             visit the SNAP portion of EPA’s Ozone                   A. Refrigeration and Air Conditioning                 blend is limited by the venting
                                             Layer Protection website at:
                                                                                                     1. R–448A                                             prohibition under section 608(c)(2) of
                                             www.epa.gov/snap. Copies of the full
                                             lists of acceptable substitutes for ozone                 EPA’s decision: EPA finds R–448A                      2 Hodnebrog ;., Etminan, M., Fuglestvedt, J.S.,
                                             depleting substances (ODS) in all                       acceptable as a substitute for use in:                Marston, G., Myhre, G., Nielsen, C.J., Shine, K.P.,
                                             industrial sectors are available at                                                                           Wallington, T.J.: Global Warming Potentials and
                                             www.epa.gov/snap/substitutes-sector.                    • Ice Skating Rinks (Retrofit Equipment               Radiative Efficiencies of Halocarbons and Related
                                             For more information on the Agency’s                    Only)                                                 Compounds: A Comprehensive Review, Reviews of
                                                                                                                                                           Geophysics, 51, 300–378, doi:10.1002/rog.20013,
                                             process for administering the SNAP                        R–448A, marketed under the trade                    2013.
                                             program or criteria for evaluation of                   name Solstice® N–40, is a weighted                      3 Nielsen, O.J., Javadi, M.S., Sulbaek Andersen,
                                                                                                     blend of 26 percent hydrofluorocarbon                 M.P., Hurley, M.D., Wallington, T.J., Singh, R.
                                               1 On April 27, 2018 (83 FR 18431) EPA provided        (HFC)-32, which is also known as                      Atmospheric chemistry of CF3CF=CH2: Kinetics and
                                             information on the Agency’s plan to address the         difluoromethane (Chemical Abstracts                   mechanisms of gas-phase reactions with Cl atoms,
                                             decision of the Court of Appeals for the District of                                                          OH radicals, and O3. Chemical Physics Letters 439,
                                                                                                     Service Registry Number [CAS Reg. No.]
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                                             Columbia Circuit in the case of Mexichem Fluor,                                                               18–22, 2007.
                                             Inc. v. EPA. That decision vacated the 2015 Rule        75–10–5); 26 percent HFC–125, which is                  4 Hodnebrog et al., 2013 and Atmospheric

                                             (80 FR 42870) ‘‘to the extent it requires               also known as 1,1,1,2,2-                              chemistry of trans-CF3CH=CHF: products and
                                             manufacturers to replace HFCs with a substitute         pentafluoroethane (CAS Reg. No. 354–                  mechanisms of hydroxyl radical and chlorine atom
                                             substance’’ and remanded the rule to EPA for                                                                  initiated oxidation’’, M.S. Javadi, R. S<ndergaard,
                                             further proceedings. EPA plans to issue a proposed
                                                                                                     33–6); 21 percent HFC–134a, which is                  O.J. Nielsen, M.D., Hurley, and T.J. Wellington,
                                             rule to address the court’s vacatur and remand in       also known as 1,1,1,2-tetrafluoroethane               Atmospheric Chemistry and Physics Discussions 8,
                                             early 2019.                                             (CAS Reg. No. 811–97–2); 20 percent                   1069–1088, 2008.



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                                             50028            Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations

                                             the CAA, codified at 40 CFR                             pose greater overall environmental and                worst-case fractionation for
                                             82.154(a)(1).                                           human health risk than other available                flammability, is not flammable.
                                                Flammability information: R–448A, as                 substitutes in the same end-use.                         Toxicity and exposure data: Potential
                                             formulated and even considering the
                                                                                                     2. R–449A                                             health effects of exposure to this
                                             worst-case fractionation for
                                                                                                                                                           substitute include drowsiness or
                                             flammability, is not flammable.                           EPA’s decision: EPA finds R–449A
                                                Toxicity and exposure data: Potential                                                                      dizziness. The substitute may also
                                                                                                     acceptable as a substitute for use in:                irritate the skin or eyes or cause
                                             health effects of exposure to this
                                             substitute include drowsiness or                        • Ice Skating Rinks (Retrofit Equipment               frostbite. At sufficiently high
                                             dizziness. The substitute may also                      Only)                                                 concentrations, the substitute may cause
                                             irritate the skin or eyes or cause                                                                            irregular heartbeat. The substitute could
                                                                                                       R–449A, marketed under the trade
                                             frostbite. At sufficiently high                                                                               cause asphyxiation if air is displaced by
                                                                                                     name Opteon® XP 40, is a weighted
                                             concentrations, the substitute may cause                                                                      vapors in a confined space. These
                                                                                                     blend of 24.3 percent HFC–32, which is
                                             irregular heartbeat. The substitute could                                                                     potential health effects are common to
                                                                                                     also known as difluoromethane (CAS
                                             cause asphyxiation if air is displaced by               Reg. No. 75–10–5); 24.7 percent HFC–                  many refrigerants.
                                             vapors in a confined space. These                       125, which is also known as 1,1,1,2,2-                   The AIHA has established WEELs of
                                             potential health effects are common to                  pentafluoroethane (CAS Reg. No. 354–                  1,000 ppm as an 8-hr TWA for HFC–32,
                                             many refrigerants.                                      33–6); 25.7 percent HFC–134a, which is                HFC–125, and HFC–134a and 500 ppm
                                                The American Industrial Hygiene                      also known as 1,1,1,2-tetrafluoroethane               for HFO–1234yf, the components of R–
                                             Association (AIHA) has established                      (CAS Reg. No. 811–97–2); and 25.3                     449A. The manufacturer of R–449A
                                             workplace environmental exposure                        percent HFO–1234yf, which is also                     recommends an AEL of 830 ppm on an
                                             limits (WEELs) of 1,000 ppm as an                       known as 2,3,3,3-tetrafluoroprop-1-ene                8-hour TWA for the blend. EPA
                                             eight-hour time-weighted (TWA) for                      (CAS Reg. No. 754–12–1).                              anticipates that users will be able to
                                             HFC–32, HFC–125, and HFC–134a; 500
                                                                                                       You may find the redacted                           meet each of the AIHA WEELs and the
                                             ppm for HFO–1234yf; and 800 ppm for
                                                                                                     submission in Docket EPA–HQ–OAR–                      manufacturer’s AEL and address
                                             HFO–1234ze(E), the components of R–
                                                                                                     2003–0118 at www.regulations.gov                      potential health risks by following
                                             448A. The manufacturer of R–448A
                                             recommends an acceptable exposure                       under the name, ‘‘Supporting                          requirements and recommendations in
                                             limit (AEL) of 890 ppm on an 8-hour                     Documentation for Notice 30 Listing of                the manufacturer’s SDS, in ASHRAE 15,
                                             TWA for the blend. EPA anticipates that                 R–449A (XP40) in Certain Refrigeration                and other safety precautions common to
                                             users will be able to meet the AIHA                     and Air Conditioning End-Uses. SNAP                   the refrigeration and air conditioning
                                             WEELs and manufacturer’s AEL and                        Submission Received August 6, 2014.’’                 industry.
                                             address potential health risks by                       EPA performed assessments to examine                     Comparison to other substitutes in
                                             following requirements and                              the health and environmental risks of                 this end-use: R–449A has an ODP of
                                             recommendations in the manufacturer’s                   this substitute. These assessments are                zero, comparable to or lower than the
                                             safety data sheet (SDS), in the American                available in Docket EPA–HQ–OAR–
                                                                                                                                                           other listed substitutes in this end-use,
                                             Society for Heating, Refrigerating, and                 2003–0118 under the following name:
                                                                                                                                                           with ODPs ranging from zero to 0.098.
                                             Air-Conditioning Engineers (ASHRAE)                     • ‘‘Risk Screen on Substitutes in Ice                    R–449A’s GWP of 1,400 is lower than
                                             Standard 15, and other safety                           Skating Rinks Substitute: R–449A                      or comparable to that of acceptable
                                             precautions common to the refrigeration                 (Opteon® XP40)’’                                      substitutes for ice skating rinks (retrofit),
                                             and air conditioning industry.                                                                                such as HFC–134a, R–407C, and R–
                                                Comparison to other substitutes in                     EPA previously listed R–449A as an
                                                                                                     acceptable refrigerant in a number of                 507A with GWPs ranging from 1,430 to
                                             this end-use: R–448A has an ODP of
                                             zero, comparable to or lower than other                 other refrigeration and air conditioning              3,990. R–449A’s GWP is higher than the
                                             listed substitutes in this end-use, with                end-uses (e.g., July 16, 2015, 80 FR                  GWPs of other acceptable substitutes for
                                             ODPs ranging from zero to 0.098.                        42053; October 11, 2016, 81 FR 70029;                 ice skating rinks (retrofit), including R–
                                                R–448A’s GWP of 1,390 is lower than                  July 21, 2017, 82 FR 33809).                          401A and R–401B with GWPs ranging
                                             or comparable to that of acceptable                       Environmental information: R–449A                   from 1,182 to 1,288.
                                             substitutes for ice skating rinks (retrofit),           has an ODP of zero. Its components,                      Flammability and toxicity risks are
                                             such as HFC–134a, R–407C, and R–                        HFC–32, HFC–125, HFC–134a, and                        comparable to or lower than
                                             507A, with GWPs ranging from 1,430 to                   HFO–1234yf, have GWPs of 675; 3,500;                  flammability and toxicity risks of other
                                             3,990. R–448A’s GWP is higher than the                  1,430; and one to four,5 respectively. If             available substitutes in the same end-
                                             GWPs of other acceptable substitutes for                these values are weighted by mass                     uses. Toxicity risks can be minimized
                                             ice skating rinks (retrofit), including R–              percentage, then R–449A has a GWP of                  by use consistent with the AIHA
                                             401A and R–401B with GWPs ranging                       about 1,400. The components of R–449A                 WEELs, ASHRAE 15 and other industry
                                             from 1,182 to 1,288.                                    are excluded from the definition of VOC               standards, recommendations in the
                                                Flammability and toxicity risks are                  under CAA regulations (see 40 CFR                     manufacturer’s SDS, and other safety
                                             comparable to or lower than                             51.100(s)) addressing the development                 precautions common in the refrigeration
                                             flammability and toxicity risks of other                of SIPs to attain and maintain the                    and air conditioning industry.
                                             available substitutes in the same end-                  NAAQS. Knowingly venting or releasing
                                             use. Toxicity risks can be minimized by                 this refrigerant blend is limited by the                 EPA finds R–449A acceptable in the
                                             use consistent with the AIHA WEELs,                     venting prohibition under section                     end-use listed above because it does not
                                                                                                     608(c)(2) of the CAA, codified at 40 CFR              pose greater overall environmental and
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                                             ASHRAE 15 and other industry
                                             standards, recommendations in the                       82.154(a)(1).                                         human health risk than other available
                                             manufacturer’s SDS, and other safety                      Flammability information: R–449A, as                substitutes in the same end-use.
                                             precautions common in the refrigeration                 formulated and even considering the                   3. R–449B
                                             and air conditioning industry.
                                                EPA finds R–448A acceptable in the                    5 Hodnebrog et al., 2013 and Nielsen et al., 2007.     EPA’s decision: EPA finds R–449B
                                             end-use listed above because it does not                Op. cit.                                              acceptable as a substitute for use in:


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                                                              Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations                                                50029

                                             • Ice Skating Rinks (Retrofit Equipment                 cause asphyxiation if air is displaced by             under the name, ‘‘Supporting Materials
                                             Only)                                                   vapors in a confined space. These                     for Notice 30 Listing of R–450A in
                                               R–449B, marketed under the trade                      potential health effects are common to                Vending Machines.’’ EPA performed an
                                             name Forane® 449B, is a weighted blend                  many refrigerants.                                    assessment to examine the health and
                                             of 25.2 percent HFC–32, which is also                      The AIHA has established WEELs of                  environmental risks of this substitute.
                                             known as difluoromethane (CAS Reg.                      1,000 ppm as an 8-hr TWA for HFC–32,                  This assessment is available in Docket
                                             No. 75–10–5); 24.3 percent HFC–125,                     HFC–125, and HFC–134a and 500 ppm                     EPA–HQ–OAR–2003–0118 under the
                                             which is also known as 1,1,1,2,2-                       for HFO–1234yf, the components of R–                  following name:
                                                                                                     449B. The manufacturer of R–449B
                                             pentafluoroethane (CAS Reg. No. 354–                                                                          • ‘‘Risk Screen on Substitutes for Use in
                                             33–6); 27.3 percent HFC–134a, which is                  recommends an AEL of 865 ppm on an
                                                                                                                                                           Ice Skating Rinks Substitute: R–450A’’
                                             also known as 1,1,1,2-tetrafluoroethane                 8-hour TWA for the blend. EPA
                                                                                                     anticipates that users will be able to                   EPA previously listed R–450A as
                                             (CAS Reg. No. 811–97–2); and 23.2
                                             percent HFO–1234yf, which is also                       meet each of the AIHA WEELs and the                   acceptable for use as a refrigerant in
                                             known as 2,3,3,3-tetrafluoroprop-1-ene                  manufacturer’s AEL and address                        several refrigeration and air
                                             (CAS Reg. No. 754–12–1).                                potential health risks by following                   conditioning end-uses (October 21,
                                               You may find the redacted                             requirements and recommendations in                   2014, 79 FR 62863; July 16, 2015, 80 FR
                                             submission in Docket EPA–HQ–OAR–                        the manufacturer’s SDS, in ASHRAE 15,                 42053).
                                             2003–0118 at www.regulations.gov                        and other safety precautions common to                   Environmental information: R–450A
                                             under the name, ‘‘Supporting                            the refrigeration and air conditioning                has an ODP of zero. Its components,
                                             Documentation for Notice 32 Listing of                  industry.                                             HFC–134a and HFO–1234ze(E), have
                                             R–449B in Refrigeration and Air                            Comparison to other substitutes in                 GWPs of 1,430 and one to six,7
                                             Conditioning. SNAP Submission                           this end-use: R–449B has an ODP of                    respectively. If these values are
                                             Received October 2, 2015.’’ EPA                         zero, comparable to or lower than the                 weighted by mass percentage, then R–
                                             performed assessments to examine the                    other listed substitutes in this end-use,             450A has a GWP of about 600. The
                                             health and environmental risks of this                  with ODPs ranging from zero to 0.098.                 components of R–450A are both
                                             substitute. These assessments are                          R–449B’s GWP of 1,410 is lower than                excluded from the definition of VOC
                                             available in Docket EPA–HQ–OAR–                         or comparable to that of acceptable                   under CAA regulations (see 40 CFR
                                             2003–0118 under the following name:                     substitutes for ice skating rinks (retrofit),         51.100(s)) addressing the development
                                                                                                     such as HFC–134a, R–407C, and R–                      of SIPs to attain and maintain the
                                             • ‘‘Risk Screen on Substitutes in Ice                   507A with GWPs ranging from 1,430 to                  NAAQS. Knowingly venting or releasing
                                             Skating Rinks Substitute: R–449B                        3,990. R–449B’s GWP is higher than the                this refrigerant blend is limited by the
                                             (Forane® 449B)’’                                        GWPs of other acceptable substitutes for              venting prohibition under section
                                                EPA previously listed R–449B as an                   ice skating rinks (retrofit), including R–            608(c)(2) of the CAA, codified at 40 CFR
                                             acceptable refrigerant in a number of                   401A and R–401B with GWPs ranging                     82.154(a)(1).
                                             other refrigeration and air conditioning                from 1,182 to 1,288.                                     Flammability information: R–450A, as
                                             end-uses (e.g., October 11, 2016, 81 FR                    Flammability and toxicity risks are                formulated and even considering the
                                             70029; July 21, 2017, 82 FR 33809).                     comparable to or lower than                           worst-case fractionation for
                                                Environmental information: R–449B                    flammability and toxicity risks of other              flammability, is not flammable.
                                             has an ODP of zero. Its components,                     available substitutes in the same end-                   Toxicity and exposure data: Potential
                                             HFC–32, HFC–125, HFC–134a, and                          use. Toxicity risks can be minimized by               health effects of exposure to this
                                             HFO–1234yf, have GWPs of 675; 3,500;                    use consistent with the AIHA WEELs,                   substitute include drowsiness or
                                             1,430; and one to four,6 respectively. If               ASHRAE 15 and other industry                          dizziness. The substitute may also
                                             these values are weighted by mass                       standards, recommendations in the                     irritate the skin or eyes or cause
                                             percentage, then R–449B has a GWP of                    manufacturer’s SDS, and other safety                  frostbite. At sufficiently high
                                             about 1,410. The components of R–449B                   precautions common in the refrigeration               concentrations, the substitute may cause
                                             are excluded from the definition of VOC                 and air conditioning industry.                        irregular heartbeat. The substitute could
                                             under CAA regulations (see 40 CFR                          EPA finds R–449B acceptable in the                 cause asphyxiation if air is displaced by
                                             51.100(s)) addressing the development                   end-use listed above because it does not              vapors in a confined space. These
                                             of SIPs to attain and maintain the                      pose greater overall environmental and                potential health effects are common to
                                             NAAQS. Knowingly venting or releasing                   human health risk than other available                many refrigerants.
                                             this refrigerant blend is limited by the                substitutes in the same end-use.                         The AIHA has established WEELs of
                                             venting prohibition under section                                                                             1,000 ppm and 800 ppm as an 8-hour
                                                                                                     4. R–450A                                             TWA for HFC–134a and HFO–
                                             608(c)(2) of the CAA, codified at 40 CFR
                                             82.154(a)(1).                                              EPA’s decision: EPA finds R–450A                   1234ze(E), respectively, the components
                                                Flammability information: R–449B, as                 acceptable as a substitute for use in:                of R–450A. The manufacturer of R–
                                             formulated and even considering the                                                                           450A recommends an AEL of 880 ppm
                                                                                                     • Ice Skating Rinks (New and Retrofit
                                             worst-case fractionation for                                                                                  on an 8-hour TWA for the blend. EPA
                                                                                                     Equipment)
                                             flammability, is not flammable.                                                                               anticipates that users will be able to
                                                Toxicity and exposure data: Potential                  R–450A, marketed under the trade                    meet each of the manufacturer’s AEL
                                             health effects of exposure to this                      name Solstice® N–13, is a weighted                    and AIHA WEELs and address potential
                                             substitute include drowsiness or                        blend of 42 percent HFC–134a, which is                health risks by following requirements
                                             dizziness. The substitute may also                      also known as 1,1,1,2 tetrafluoroethane               and recommendations in the
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                                             irritate the skin or eyes or cause                      (CAS Reg. No. 811–97–2), and 58                       manufacturer’s SDS, in ASHRAE 15,
                                             frostbite. At sufficiently high                         percent HFO–1234ze(E), which is also                  and other safety precautions common to
                                             concentrations, the substitute may cause                known as trans-1,3,3,3-tetrafluoropro-l-              the refrigeration and air conditioning
                                             irregular heartbeat. The substitute could               ene (CAS Reg. No. 29118–24–9).                        industry.
                                                                                                       You may find the redacted
                                              6 Hodnebrog et al., 2013 and Nielsen et al., 2007.     submission in Docket EPA–HQ–OAR–                       7 Hodnebrog et al., 2013 and Nielsen et al., 2007.

                                             Op. cit.                                                2003–0118 at www.regulations.gov                      Op. cit.



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                                             50030            Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations

                                                Comparison to other substitutes in                      Environmental information: R–513A                          Flammability and toxicity risks are
                                             this end-use: R–450A has an ODP of                      has an ODP of zero. Its components,                        comparable to or lower than
                                             zero, comparable to other listed                        HFC–134a and HFO–1234yf, have GWPs                         flammability and toxicity risks of other
                                             substitutes in this end-use, with ODPs                  of 1,430 and one to four,8 respectively.                   available substitutes in the same end-
                                             ranging from zero to 0.098.                             If these values are weighted by mass                       use. Toxicity risks can be minimized by
                                                R–450A’s GWP of 600 is lower than                    percentage, then R–513A has a GWP of                       use consistent with the AIHA WEELs,
                                             that of other acceptable substitutes (for               about 630. The components of R–513A                        ASHRAE 15, and other industry
                                             new and retrofit use for ice skating                    are both excluded from the definition of                   standards, recommendations in the
                                             rinks) such as HFC–134a, R–407C, and                    VOC under CAA regulations (see 40                          manufacturer’s SDS, and other safety
                                             R–507A with GWPs ranging from 1,430                     CFR 51.100(s)) addressing the                              precautions common in the refrigeration
                                             to 3,990. R–450A’s GWP is higher than                   development of SIPs to attain and                          and air conditioning industry.
                                             the GWPs of other acceptable substitutes                maintain the NAAQS. Knowingly                                 EPA finds R–513A acceptable in the
                                             for new ice skating rinks, including                    venting or releasing this refrigerant                      end-use listed above because it does not
                                             ammonia absorption, ammonia vapor                       blend is limited by the venting                            pose greater overall environmental and
                                             compression and carbon dioxide with                     prohibition under section 608(c)(2) of                     human health risk than other available
                                             GWPs ranging from zero to 1.                            the CAA, codified at 40 CFR                                substitutes in the same end-use.
                                                Flammability and toxicity risks are                  82.154(a)(1).
                                             comparable to or lower than                                                                                        B. Foam Blowing
                                                                                                        Flammability information: R–513A, as
                                             flammability and toxicity risks of other                formulated and even considering the                        1. Acetone/Isopentane Blend
                                             available substitutes in the same end-                  worst-case fractionation for                                  EPA’s decision: EPA finds Acetone/
                                             use. Toxicity risks can be minimized by                 flammability, is not flammable.                            Isopentane blend acceptable as a
                                             use consistent with the AIHA WEELs,                        Toxicity and exposure data: Potential                   substitute for use in:
                                             ASHRAE 15, and other industry                           health effects of exposure to this
                                             standards, recommendations in the                       substitute include drowsiness or                           • Rigid Polyurethane and
                                             manufacturer’s SDS, and other safety                    dizziness. The substitute may also                         Polyisocyanurate Laminated Boardstock
                                             precautions common in the refrigeration                 irritate the skin or eyes or cause                            Acetone/Isopentane, is a weighted
                                             and air conditioning industry.                          frostbite. At sufficiently high                            blend of 10–30 percent acetone (CAS
                                                EPA finds R–450A acceptable in the                   concentrations, the substitute may cause                   Reg. No. 67–64–1) and 70–90 percent
                                             end-use listed above because it does not                irregular heartbeat. The substitute could                  isopentane (CAS Reg. No. 78–78–4).
                                             pose greater overall environmental and                  cause asphyxiation if air is displaced by                     You may find the redacted
                                             human health risk than other available                  vapors in a confined space. These                          submission in Docket EPA–HQ–OAR–
                                             substitutes in the same end-use.                        potential health effects are common to                     2003–0118 at www.regulations.gov
                                             5. R–513A                                               many refrigerants.                                         under the name, ‘‘Supporting
                                                                                                        The AIHA has established WEELs of                       Documentation for Notice 34 Listing of
                                                EPA’s decision: EPA finds R–513A                                                                                Acetone/Isopentane blend in rigid
                                             acceptable as a substitute for use in:                  1,000 ppm and 500 ppm as an 8-hour
                                                                                                     TWA for HFC–134a and HFO–1234yf,                           polyurethane and polyisocyanurate
                                             • Ice Skating Rinks (New and Retrofit                   respectively, the components of R–                         laminated boardstock. SNAP
                                             Equipment)                                              513A. The manufacturer of R–513A                           Submission Received August 8, 2017.’’
                                                                                                     recommends an AEL of 653 ppm on an                         EPA performed an assessment to
                                                R–513A, marketed under the trade
                                                                                                     8-hour TWA for the blend. EPA                              examine the health and environmental
                                             name Opteon® XP 10, is a weighted
                                                                                                     anticipates that users will be able to                     risks of this substitute. This assessment
                                             blend of 44 percent HFC–134a, which is
                                                                                                     meet each of the manufacturer’s AEL                        is available in Docket EPA–HQ–OAR–
                                             also known as 1,1,1,2 tetrafluoroethane
                                                                                                     and AIHA WEELs and address potential                       2003–0118 under the following name:
                                             (CAS Reg. No. 811–97–2), and 56
                                             percent HFO–1234yf, which is also                       health risks by following requirements                     • ‘‘Risk Screen on Substitutes for Use in
                                             known as 2,3,3,3-tetrafluoroprop-1-ene                  and recommendations in the                                 Rigid Polyurethane and
                                             (CAS Reg. No. 754–12–1).                                manufacturer’s SDS, in ASHRAE 15,                          Polyisocyanurate Laminated Boardstock
                                                You may find the redacted                            and other safety precautions common to                     Substitute: Acetone/Isopentane Blend’’
                                             submission in Docket EPA–HQ–OAR–                        the refrigeration and air conditioning
                                                                                                     industry.                                                    EPA previously listed acetone as
                                             2003–0118 at www.regulations.gov                                                                                   acceptable for use as a foam-blowing
                                             under the name, ‘‘Supporting                               Comparison to other substitutes in
                                                                                                                                                                agent in flexible polyurethane and in
                                             Documentation for Notice 30 Listing of                  this end-use: R–513A has an ODP of
                                                                                                                                                                integral skin polyurethane (March 18,
                                             R–513A (XP10) in Certain Refrigeration                  zero, comparable to other listed
                                                                                                                                                                1994, 59 FR 13044; February 24, 1998,
                                             and Air Conditioning End-Uses. SNAP                     substitutes in this end-use, with ODPs
                                                                                                                                                                63 FR 9151). EPA previously listed C3–
                                             Submission Received July 24, 2014.’’                    ranging from zero to 0.098.
                                                                                                                                                                C6 light saturated hydrocarbons, which
                                             EPA performed an assessment to                             R–513A’s GWP of 630 is lower than
                                                                                                                                                                include isopentane, as acceptable for
                                             examine the health and environmental                    that of other acceptable substitutes for
                                                                                                                                                                use as a foam-blowing agent in a
                                             risks of this substitute. This assessment               new and retrofit use for ice skating
                                                                                                                                                                number of foam-blowing end-uses.
                                             is available in Docket EPA–HQ–OAR–                      rinks, such as HFC–134a, R–407C, and
                                                                                                                                                                (August 26, 1994, 59 FR 44240; April
                                             2003–0118 under the following name:                     R–507A with GWPs ranging from 1,430
                                                                                                                                                                11, 2000, 65 FR 19327).
                                                                                                     to 3,990. R–513A’s GWP is higher than
                                             • ‘‘Risk Screen on Substitutes for Use in               the GWPs of other acceptable substitutes
                                                                                                                                                                  Environmental information: Acetone/
                                             Ice Skating Rinks Substitute: R–513A’’                                                                             isopentane blend has an ODP of zero. Its
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                                                                                                     for new ice skating rinks, including                       components, acetone and isopentane,
                                               EPA previously listed R–513A as                       ammonia absorption, ammonia vapor                          have GWPs of 0.5 and <10,
                                             acceptable for use as a refrigerant in                  compression and carbon dioxide with                        respectively.9 Acetone is excluded from
                                             several refrigeration and air                           GWPs ranging from zero to 1.
                                             conditioning end-uses (July 16, 2015, 80                                                                             9 GWP for acetone comes from IPCC, 2007. GWP
                                             FR 42053; May 23, 2016, 81 FR 32241;                      8 Hodnebrog     et al., 2013 and Nielsen et al., 2007.   for isopentane is estimated based on GWP of butane
                                             July 21, 2017, 82 FR 33809).                            Op. cit.                                                   from IPCC, 2007 and the relative atmospheric



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                                                              Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations                                       50031

                                             the definition of VOC under CAA                         recommendations in the manufacturer’s                 • ‘‘Risk Screen on Substitutes for Total
                                             regulations (see 40 CFR 51.100(s))                      SDS, and other safety precautions                     Flooding Systems in Occupied Spaces
                                             addressing the development of SIPs to                   common in the foam-blowing industry.                  Substitute: Powdered Aerosol E
                                             attain and maintain the NAAQS, while                      EPA finds acetone/isopentane blend                  (FirePro)’’
                                             isopentane is defined as VOC under                      acceptable in the end-use listed above                   Environmental information: The
                                             those regulations.                                      because it does not pose greater overall              active ingredients of Powdered Aerosol
                                                Flammability information: Acetone/                   environmental and human health risk                   E are solids both before and after use;
                                             isopentane blend is flammable.                          than other available substitutes in the
                                                Toxicity and exposure data: Potential                                                                      thus, their ODP and GWP are both zero.
                                                                                                     same end-use.                                         The gaseous post-activation products for
                                             health effects of exposure to this
                                             substitute include drowsiness or                        C. Fire Suppression and Explosion                     Powdered Aerosol E also have zero ODP
                                             dizziness. Higher concentrations may                    Protection                                            and GWPs of 120 or less. The solid
                                             cause central nervous system depression                                                                       active ingredients and particulate post-
                                                                                                     1. Powdered Aerosol E (FireProTM)                     activation products do not participate in
                                             and loss of consciousness. The
                                             substitute may also irritate the skin or                                                                      atmospheric photochemical reactions
                                                                                                      EPA’s decision: EPA finds Powdered
                                             eyes. The substitute could cause                                                                              and are not VOCs. The gaseous post-
                                                                                                     Aerosol E acceptable as a substitute for:
                                             asphyxiation if air is displaced by                                                                           activation products are either not
                                             vapors in a confined space. These                       • Total Flooding Uses                                 organic or excluded from the definition
                                             potential health effects are common to                                                                        of VOC under CAA regulations (see 40
                                                                                                        Powdered Aerosol E is generated in                 CFR 51.100(s)) addressing the
                                             many foam-blowing agents.                               an automated manufacturing process
                                                For acetone, the Occupational Safety                                                                       development of SIPs to attain and
                                                                                                     during which the chemicals, in powder                 maintain the NAAQS.
                                             and Health Administration (OSHA) has                    form, are mixed and then supplied to
                                             established a permissible exposure limit                                                                         Flammability information: Powdered
                                                                                                     end users as a solid contained within a               Aerosol E’s post-activation products are
                                             (PEL) of 1000 ppm and the American                      fire extinguisher. In the presence of
                                             Conference of Governmental Industrial                                                                         nonflammable.
                                                                                                     heat, the solid converts to an aerosol                   Toxicity and exposure data: Exposure
                                             Hygienists (ACGIH) has established a                    consisting mainly of potassium salts.
                                             threshold limit value (TLV) of 750 ppm,                                                                       to Powdered Aerosol E after activation
                                                                                                     EPA previously listed Powdered                        may cause temporary, mild irritation of
                                             both on an 8-hr TWA. For isopentane,
                                                                                                     Aerosol E as acceptable subject to use                the mucous membrane. If eye or skin
                                             ACGIH has established a TLV of 600
                                                                                                     conditions in areas that are not normally             contact occurs, end users should flush
                                             ppm on an 8-hr TWA. EPA anticipates
                                                                                                     occupied (71 FR 56359; September 27,                  eyes with water or wash skin with soap
                                             that users will be able to meet the
                                                                                                     2006). Based on a review of additional                and water. If inhaled, end users should
                                             ACGIH’s TLVs for both components and
                                                                                                     information from the submitter to                     be removed and exposed to fresh air.
                                             address potential health risks by
                                                                                                     support the safe use of Powdered                      Exposure to the post-discharge products
                                             following requirements and
                                                                                                     Aerosol E in normally occupied spaces,                is expected to be below the relevant
                                             recommendations in the manufacturer’s
                                                                                                     EPA now determines that Powdered                      workplace exposure limits for those
                                             SDS and other safety precautions
                                                                                                     Aerosol E is also acceptable for use in               compounds. Because it is housed in a
                                             common to the foam-blowing industry.
                                                Comparison to other substitutes in                   total flooding systems for normally                   hermetically sealed container, exposure
                                             this end-use: Acetone/isopentane blend                  occupied spaces, and EPA is adding                    should not occur unless the system is
                                             has an ODP of zero, comparable to other                 Powdered Aerosol E to the list of                     activated.
                                             listed substitutes in this end-use, with                acceptable substitutes for total flooding                The post-activation components of the
                                             ODPs ranging from zero to 0.012.                        uses, which would include both                        proposed substitute are common
                                                For rigid polyurethane and                           unoccupied and occupied spaces. In a                  compounds that are not expected to
                                             polyisocyanurate laminated boardstock,                  subsequent rulemaking EPA will                        exceed immediately dangerous to life or
                                             acetone/isopentane blend’s GWP of <10                   remove the previous listing as                        health (IDLH) levels from the National
                                             is comparable to the GWPs of other                      acceptable subject to use conditions. In              Institute for Occupational Safety and
                                             acceptable substitutes for rigid                        the ‘‘Further Information’’ column of the             Health (NIOSH) that apply to
                                             polyurethane and polyisocyanurate                       tables summarizing today’s listing                    occupational and end use exposure.
                                             laminated boardstock, including                         decisions and found at the end of this                   Information on additional safety
                                             EcomateTM, CO2, HFO–1336mzz(Z) and                      document, we also state that use of this              recommendations: The discharge of the
                                             C3–C6 light saturated hydrocarbons                      agent should continue to be in                        aerosol results in a reduction of
                                             with GWPs ranging from less than 1 to                   accordance with the safety guidelines in              visibility in the protected space due to
                                             approximately 12.                                       the latest edition of the National Fire               the uniform distribution of the
                                                Flammability and toxicity risks are                  Protection Association (NFPA) 2010                    particulate generated. Use according to
                                             comparable to or lower than                             Standard for Aerosol Extinguishing                    the NFPA 2010 Standard will reduce
                                             flammability and toxicity risks of other                Systems.                                              any safety risks due to reduced
                                             available substitutes in the same end-                     You may find the redacted                          visibility. In addition, EPA recommends
                                             use. Toxicity risks can be minimized by                 submission in Docket EPA–HQ–OAR–                      that cross-zone detection systems and
                                             use consistent with the ACGIH TLVs,                     2003–0118 at www.regulations.gov                      abort switches located near an exit from
                                                                                                     under the name, ‘‘Supporting                          the protected space be employed;
                                             lifetimes of butane and isopentane from:                Documentation for Notice 34 Listing of                improved detection systems within the
                                             Safeguarding the Ozone Layer and the Global             Powdered Aerosol E (FirePro) in Fire                  protected space and manual abort
                                             Climate System. IPCC/TEAP, 2005—Bert Metz,
                                                                                                     Suppression. SNAP Submission                          switches outside of the space could help
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                                             Lambert Kuijpers, Susan Solomon, Stephen O.
                                             Anderson, Ogunlade Davidson, Jose Pons, David de        Received November 17, 2016.’’ EPA                     avoid inadvertent discharge.
                                             Jager, Tahl Kestin, Martin Manning, and Leo Meyer       performed an assessment to examine the                   In the ‘‘Further Information’’ column
                                             (Eds.). Cambridge University Press, UK. pp 478.         health and environmental risks of this                of the tables summarizing today’s listing
                                             Available from Cambridge University Press, The
                                             Edinburgh Building Shaftesbury Road, Cambridge
                                                                                                     substitute. This assessment is available              decisions, EPA recommends the
                                             CB2 2RU ENGLAND Available online at https://            in Docket EPA–HQ–OAR–2003–0118                        following for establishments
                                             www.ipcc.ch/report/sroc.                                under the following name:                             manufacturing Powdered Aerosol E and


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                                             50032            Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations

                                             filling containers to be used in total                  and other safety precautions common in                rule that, if finalized as proposed,
                                             flooding applications:                                  the fire suppression industry. The                    would exclude HFO–1336mzz(Z) from
                                             —Workers should use appropriate safety                  potential toxicity risks due to inhalation            the definition of VOC under CAA
                                                and protective equipment (e.g.,                      exposure are common to many total                     regulations (see 40 CFR 51.100(s))
                                                protective gloves, tightly sealed                    flooding agents, including those already              addressing the development of SIPs to
                                                goggles, protective work clothing, and               listed as acceptable under SNAP for this              attain and maintain the NAAQS (May 1,
                                                particulate-removing respirators using               same end-use. Powdered Aerosol E’s                    2018; 83 FR 19026).
                                                NIOSH type N95 or better filters)                    post-activation products are                             Flammability information: HFO–
                                                consistent with OSHA guidelines.                     nonflammable, as are all other available              1336mzz(Z) is not flammable.
                                             —A local exhaust system should be                       total flooding agents.                                   Toxicity and exposure data: Potential
                                                installed and operated to provide                       EPA finds Powdered Aerosol E                       health effects of exposure to this
                                                adequate ventilation to reduce                       acceptable in the end-use listed above                substitute include skin or eye irritation
                                                airborne exposure to Powdered                        because it does not pose greater overall              or frostbite. At sufficiently high
                                                Aerosol E constituents.                              environmental and human health risk                   concentrations, the substitute may cause
                                             —An eye wash fountain and quick                         than other available substitutes in the               irregular heartbeat. The substitute could
                                                drench facility should be close to the               same end-use.                                         cause asphyxiation if air is displaced by
                                                production area.                                                                                           vapors in a confined space. EPA issued
                                                                                                     D. Cleaning Solvents                                  a Significant New Use Rule under the
                                             —Training for safe handling procedures
                                                should be provided to all employees                  1. HFO–1336mzz(Z)                                     Toxic Substances Control Act on June 5,
                                                that would be likely to handle the                                                                         2015, to require persons to submit a
                                                                                                        EPA’s decision: EPA finds HFO–                     Significant New Use Notice to EPA at
                                                containers of the agent or                           1336mzz(Z)) acceptable as a substitute                least 90 days before they manufacture or
                                                extinguishing units filled with the                  for use in:                                           process HFO–1336mzz(Z) for uses other
                                                agent.                                               • Electronics cleaning                                than those described in the
                                             —Workers responsible for cleanup                        • Metals cleaning                                     Premanufacture Notice (80 FR 32003).
                                                should allow particulates to settle                  • Precision cleaning                                     EPA anticipates that HFO–
                                                before reentering area and wear                         HFO–1336mzz(Z) is also known as                    1336mzz(Z) will be used consistent with
                                                appropriate personal protective                      (Z)-1,1,1,4,4,4-hexafluoro-2-butene and               the recommendations specified in the
                                                equipment.                                           cis-1,1,1,4,4,4-hexafluoro-2-butene (CAS              SDS. The WEEL committee of the
                                             —All spills should be cleaned up                        Reg. No. 692–49–9).                                   Occupational Alliance for Risk Science
                                                immediately in accordance with good                     You may find the redacted                          (OARS) recommends a WEEL for the
                                                industrial hygiene practices.                        submission in Docket EPA–HQ–OAR–                      workplace of 500 ppm on an 8-hour
                                                EPA expects that procedures                          2003–0118 at www.regulations.gov                      TWA. EPA anticipates that users will be
                                             identified in the SDS for Powdered                      under the name, ‘‘Supporting                          able to meet the WEEL and address
                                             Aerosol E and good manufacturing                        Documentation for Notice 34 Listing of                potential health risks by following
                                             practices will be adhered to, and that                  HFO–1336mzz(Z) in Cleaning Solvents                   requirements and recommendations in
                                             the appropriate safety and personal                     and Aerosol Solvents. SNAP                            the SDS and other safety precautions
                                             protective equipment (PPE) consistent                   Submission Received June 19, 2017.’’                  common to the cleaning solvents
                                             with OSHA guidelines will be used                       EPA performed an assessment to                        industry.
                                             during installation, servicing, post-                   examine the health and environmental                     Comparison to other substitutes in
                                             discharge clean-up and disposal of total                risks of this substitute. This assessment             this end-use: HFO–1336mzz(Z) has an
                                             flooding systems using Powdered                         is available in Docket EPA–HQ–OAR–                    ODP of zero, comparable to other listed
                                             Aerosol E. The manufacturer should                      2003–0118 under the following name:                   substitutes in this end-use, with ODPs
                                             provide guidance upon installation of                                                                         ranging from zero to 0.033.
                                             the system regarding the appropriate                    • ‘‘Risk Screen on Substitutes for Use in                For cleaning solvents, HFO–
                                             time after which workers may re-enter                   Cleaning Solvents Substitute: HFO–                    1336mzz(Z)’s GWP of about nine is
                                             the area for disposal to allow the                      1336mzz(Z)’’                                          lower than that of other acceptable
                                             maximum settling of all particulates.                     EPA previously listed HFO–                          substitutes, such as HFE–7200, HFE–
                                                Comparison to other substitutes in                   1336mzz(Z) as acceptable for use in                   7100, HFC–365mfc and HFC–4310mee
                                             this end-use: Powdered Aerosol E has an                 several refrigeration and air                         with GWPs ranging from 59 to 1,640.
                                             ODP of zero, comparable to other listed                 conditioning and foam-blowing end-                    HFO–1336mzz(Z)’s GWP is higher than
                                             substitutes in this end-use, with ODPs                  uses (October 21, 2014, 79 FR 62863;                  or comparable to the GWPs of other
                                             ranging from zero to 0.048.                             July 16, 2015, 80 FR 42053; May 23,                   acceptable substitutes for cleaning
                                                For total flooding agents, Powdered                  2016, 81 FR 32241).                                   solvents, including acetone,
                                             Aerosol E’s GWP of 0 (and 1 to 120 for                    Environmental information: HFO–                     methoxytridecafluoroheptene isomers
                                             certain post-activation products) is                    1336mzz(Z) has an ODP of zero. It has                 (MPHE), and trans-1-chloro-3,3,3-
                                             lower than that of other acceptable                     a 100-year GWP of about nine.10 HFO–                  trifluoroprop-1-ene with GWPs ranging
                                             substitutes, such as HFC–227ea, other                   1336mzz(Z) is a VOC, and it is not                    from less than 1 to 7.
                                             HFCs, and some HCFC fire                                exempted from the definition of VOC                      Flammability and toxicity risks are
                                             suppressants, with GWPs which range                     under CAA regulation (see 40 CFR                      comparable to or lower than
                                             from about 1,550 to 14,800. Other                       51.100(s)) addressing the development                 flammability and toxicity risks of other
                                             acceptable substitutes in this end-use                  of SIPs to attain and maintain the                    available substitutes in the same end-
                                             have comparable GWPs ranging from                                                                             use. Toxicity risks can be minimized by
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                                                                                                     NAAQS. EPA has issued a proposed
                                             zero to one, such as water, inert gases,                                                                      use consistent with the OARS WEEL,
                                             and a number of other powdered aerosol                    10 Baasandorj, M., Ravishankara, A.R.,              recommendations in the manufacturer’s
                                             fire suppressants.                                      Burkholder, J.B., Atmospheric Chemistry of (Z)-       SDS, and other safety precautions
                                                                                                     CF3CHÕCHCF3: OH Radical Reaction Rate
                                                Toxicity risks can be minimized by                   Coefficient and Global Warming Potential, Journal
                                                                                                                                                           common in the cleaning solvents
                                             use consistent with the NFPA 2010                       of Physical Chemistry A, 2011, 115, 10,539–10,549,    industry; moreover, those risks are
                                             standard, recommendations in the SDS,                   2011.                                                 common to many cleaning solvents,


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                                                              Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations                                           50033

                                             including many of those already listed                  several refrigeration and air                         HFO–1336mzz(Z)’s GWP is higher than
                                             as acceptable under SNAP for this end-                  conditioning and foam-blowing end-                    or comparable to the GWPs of other
                                             use.                                                    uses (October 21, 2014, 79 FR 62863;                  acceptable substitutes for aerosol
                                               EPA finds HFO–1336mzz(Z)                              July 16, 2015, 80 FR 42053; May 23,                   solvents, including acetone, MPHE, and
                                             acceptable in the end-uses listed above                 2016, 81 FR 32241).                                   trans-1-chloro-3,3,3-trifluoroprop-1-ene
                                             because it does not pose greater overall                   Environmental information: The                     with GWPs ranging from less than
                                             environmental and human health risk                     environmental information for this                    1 to 7.
                                             than other available substitutes in the                 substitute is set forth in the                           Flammability and toxicity risks are
                                             same end-uses.                                          ‘‘Environmental information’’ section in              comparable to or lower than
                                                                                                     listing I.D.1.                                        flammability and toxicity risks of other
                                             E. Aerosols
                                                                                                        Flammability information: HFO–                     available substitutes in the same end-
                                             1. HFO–1336mzz(Z)                                       1336mzz(Z) is not flammable.                          use. Toxicity risks can be minimized by
                                                EPA’s decision: EPA finds HFO–                          Toxicity and exposure data: The                    use consistent with the OARS WEEL,
                                             1336mzz(Z) acceptable as a substitute                   toxicity information for this substitute is           recommendations in the manufacturer’s
                                             for use in:                                             set forth in the ‘‘Toxicity and exposure              SDS, and other safety precautions
                                                                                                     data’’ section in listing I.D.1, above.               common in the aerosols industry;
                                             • Aerosol Solvents                                         EPA anticipates that HFO–                          moreover, those risks are common to
                                                HFO–1336mzz(Z) is also known as                      1336mzz(Z) will be used consistent with               many aerosol solvents, including many
                                             (Z)-1,1,1,4,4,4-hexafluoro-2-butene and                 the recommendations specified in the                  of those already listed as acceptable
                                             cis-1,1,1,4,4,4-hexafluoro-2-butene (CAS                SDS. The WEEL committee of the                        under SNAP for this end-use.
                                             Reg. No. 692–49–9).                                     Occupational Alliance for Risk Science
                                                                                                                                                              EPA finds HFO–1336mzz(Z)
                                                You may find the redacted                            (OARS) recommends a WEEL for the
                                                                                                                                                           acceptable in the end-use listed above
                                             submission in Docket EPA–HQ–OAR–                        workplace of 500 ppm on an 8-hour
                                                                                                                                                           because it does not pose greater overall
                                             2003–0118 at www.regulations.gov                        TWA. EPA anticipates that users will be
                                                                                                                                                           environmental and human health risk
                                             under the name, ‘‘Supporting                            able to meet the WEEL and address
                                                                                                                                                           than other available substitutes in the
                                             Documentation for Notice 34 Listing of                  potential health risks by following
                                                                                                                                                           same end-use.
                                             HFO–1336mzz(Z) in Cleaning Solvents                     requirements and recommendations in
                                             and Aerosol Solvents. SNAP                              the SDS and other safety precautions                  List of Subjects in 40 CFR Part 82
                                             Submission Received June 19, 2017.’’                    common to the aerosols industry.
                                                                                                        Comparison to other substitutes in                   Environmental protection,
                                             EPA performed an assessment to                                                                                Administrative practice and procedure,
                                             examine the health and environmental                    this end-use: HFO–1336mzz(Z) has an
                                                                                                     ODP of zero, comparable to other listed               Air pollution control, Reporting and
                                             risks of this substitute. This assessment                                                                     recordkeeping requirements.
                                             is available in Docket EPA–HQ–OAR–                      substitutes in this end-use, with ODPs
                                             2003–0118 under the following name:                     ranging from zero to 0.033.                             Dated: September 19, 2018.
                                                                                                        For aerosol solvents, HFO–                         Sarah Dunham,
                                             • ‘‘Risk Screen on Substitutes for Use in               1336mzz(Z)’s GWP of about nine is                     Director, Office of Atmospheric Programs.
                                             Aerosol Solvents Substitute: HFO–                       lower than that of other acceptable
                                             1336mzz(Z)’’                                            substitutes, such as HFE–7200, HFE–                   Appendix A: Summary of Decisions for
                                               EPA previously listed HFO–                            7000, HFC–365mfc and HFC–4310mee                      New Acceptable Substitutes
                                             1336mzz(Z) as acceptable for use in                     with GWPs ranging from 59 to 1,640.

                                                       End-use                     Substitute          Decision                                         Further Information 1

                                                                                                           Refrigeration and Air Conditioning

                                             Ice skating rinks (retrofit      R–448A ...........   Acceptable ......    R–448A has a 100-yr global warming potential (GWP) of approximately 1,390.
                                               equipment only).                                                           This substitute is a blend of HFC–32, which is also known as
                                                                                                                          difluoromethane (CAS Reg. No. 75–10–5); HFC–125, which is also known as
                                                                                                                          1,1,1,2,2-pentafluoroethane (CAS Reg. No. 354–33–6); HFC–134a, which is
                                                                                                                          also known as 1,1,1,2-tetrafluoroethane (CAS Reg. No. 811–97–2); HFO–
                                                                                                                          1234yf, which is also known as 2,3,3,3-tetrafluoro-prop-l-ene (CAS Reg. No.
                                                                                                                          754–12–1); and HFO–1234ze(E), which is also known as trans-1,3,3,3-
                                                                                                                          tetrafluoroprop-l-ene (CAS Reg. No. 29118–24–9).
                                                                                                                        The blend is nonflammable.
                                                                                                                        The American Industrial Hygiene Association (AIHA) has established Work-
                                                                                                                          place Environmental Exposure Limits (WEELs) of 1,000 ppm on an eight-
                                                                                                                          hour time-weighted average (8-hr TWA) basis for HFC–32, HFC–125, and
                                                                                                                          HFC–134a; 500 ppm for HFO–1234yf; and 800 ppm for HFO–1234ze(E).
                                                                                                                          The manufacturer recommends an acceptable exposure limit (AEL) for the
                                                                                                                          workplace for R–448A of 890 ppm (8-hr TWA).
                                             Ice skating rinks (retrofit      R–449A ...........   Acceptable ......    R–449A has a 100-year GWP of approximately 1,400. This substitute is a
                                               equipment only).                                                           blend of HFC–32, which is also known as difluoromethane (CAS Reg. No.
                                                                                                                          75–10–5); HFC–125, which is also known as 1,1,1,2,2-pentafluoroethane
                                                                                                                          (CAS Reg. No. 354–33–6); HFC–134a, which is also known as 1,1,1,2-
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                                                                                                                          tetrafluoroethane (CAS Reg. No. 811–97–2); and HFO–1234yf, which is also
                                                                                                                          known as 2,3,3,3-tetrafluoroprop-l-ene (CAS Reg. No. 754–12–1).
                                                                                                                        The blend is nonflammable.
                                                                                                                        The AIHA has established WEELs of 1,000 ppm (8-hr TWA) for HFC–32,
                                                                                                                          HFC–125, and HFC–134a; and 500 ppm for HFO–1234yf. The manufacturer
                                                                                                                          recommends an AEL for the workplace for R–449A of 830 ppm (8-hr TWA).




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                                             50034               Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations

                                                         End-use                      Substitute           Decision                                          Further Information 1

                                             Ice skating rinks (retrofit           R–449B ...........   Acceptable ......     R–449B has a 100-year GWP of approximately 1,410. This substitute is a
                                               equipment only).                                                                 blend of HFC–32, which is also known as difluoromethane (CAS Reg. No.
                                                                                                                                75–10–5); HFC–125, which is also known as 1,1,1,2,2-pentafluoroethane
                                                                                                                                (CAS Reg. No. 354–33–6); HFC–134a, which is also known as 1,1,1,2-
                                                                                                                                tetrafluoroethane (CAS Reg. No. 811–97–2); and HFO–1234yf, which is also
                                                                                                                                known as 2,3,3,3-tetrafluoroprop-l-ene (CAS Reg. No. 754–12–1).
                                                                                                                              The blend is nonflammable.
                                                                                                                              The AIHA has established WEELs of 1,000 ppm (8-hr TWA) for HFC–32,
                                                                                                                                HFC–125, and HFC–134a; and 500 ppm for HFO–1234yf. The manufacturer
                                                                                                                                recommends an AEL for the workplace for R–449B of 865 ppm (8-hr TWA).
                                             Ice skating rinks (new and            R–450A ...........   Acceptable ......     R–450A has a 100-year GWP of approximately 600. This substitute is a blend
                                               retrofit equipment).                                                             of HFC–134a, which is also known as 1,1,1,2-tetrafluoroethane (CAS Reg.
                                                                                                                                No. 811–97–2); and HFO–1234ze(E), which is also known as trans-1,3,3,3,
                                                                                                                                -tetrafluoropro-1-ene (CAS Reg. No. 29118–24–9).
                                                                                                                              This blend is nonflammable.
                                                                                                                              The AIHA has established WEELs of 1,000 ppm and 800 ppm (8-hr TWA) for
                                                                                                                                HFC–134a and HFO–1234yf, respectively. The manufacturer recommends
                                                                                                                                an AEL for the workplace for R–450A of 880 ppm (8-hr TWA).
                                             Ice skating rinks (new and            R–513A ...........   Acceptable ......     R–513A has a 100-year GWP of approximately 630. This substitute is a blend
                                               retrofit equipment).                                                             of HFC–134a, which is also known as 1,1,1,2-tetrafluoroethane (CAS Reg.
                                                                                                                                No. 811–97–2); and HFO–1234yf, which is also known as 2,3,3,3-
                                                                                                                                tetrafluoroprop-l-ene (CAS Reg. No. 754–12–1).
                                                                                                                              This blend is nonflammable.
                                                                                                                              The AIHA has established WEELs of 1,000 ppm and 500 ppm (8-hr TWA) for
                                                                                                                                HFC–134a and HFO–1234yf, respectively. The manufacturer recommends
                                                                                                                                an AEL for the workplace for R–513A of 653 ppm (8-hr TWA).

                                                                                                                             Foam Blowing

                                             Rigid polyurethane and                Acetone/             Acceptable ......     Acetone/isopentane blend has no ozone depletion potential (ODP) and a 100-
                                               polyisocyanurate lami-                isopentane                                 year GWP of approximately <10. Acetone is excluded from the definition of
                                               nated boardstock.                     blend.                                     volatile organic compounds (VOC) under CAA regulations (see 40 CFR
                                                                                                                                51.100(s)) addressing the development of state implementation plans (SIPs)
                                                                                                                                to attain and maintain the National Ambient Air Quality Standards (NAAQS),
                                                                                                                                while isopentane is defined as VOC.
                                                                                                                              This foam-blowing agent is flammable.
                                                                                                                              For acetone, the Occupational Safety and Health Administration (OSHA) has
                                                                                                                                established a permissible exposure limit of 1000 ppm and the American Con-
                                                                                                                                ference of Governmental Industrial Hygienists (ACGIH) has established a
                                                                                                                                threshold limit value (TLV) of 750 ppm, both on an 8-hr TWA. For
                                                                                                                                isopentane, ACGIH has established a TLV of 600 ppm on an 8-hr TWA.

                                                                                                                            Fire Suppression

                                             Total flooding ....................   Powdered Aer-        Acceptable ......     Use of this agent should be in accordance with the safety guidelines in the lat-
                                                                                     osol E.                                    est edition of the National Fire Protection Association 2010 standard for Aer-
                                                                                                                                osol Extinguishing Systems.
                                                                                                                              For establishments manufacturing the agent or filling, installing, or servicing
                                                                                                                                containers or systems to be used in total flooding applications, EPA rec-
                                                                                                                                ommends the following:
                                                                                                                              —The appropriate safety and personal protective equipment (PPE) (e.g., pro-
                                                                                                                                tective gloves, tightly sealed goggles, protective work clothing, and particu-
                                                                                                                                late-removing respirators with National Institute for Occupational Safety and
                                                                                                                                Health type N95 or better filters) consistent with Occupational Safety and
                                                                                                                                Health Administration (OSHA) guidelines should be used during manufac-
                                                                                                                                ture, installation, servicing, and disposal of total flooding systems using the
                                                                                                                                agent;
                                                                                                                              —adequate ventilation should be in place to reduce airborne exposure to con-
                                                                                                                                stituents of agent;
                                                                                                                              —an eye wash fountain and quick drench facility should be close to the pro-
                                                                                                                                duction area;
                                                                                                                              —training for safe handling procedures should be provided to all employees
                                                                                                                                that would be likely to handle containers of the agent or extinguishing units
                                                                                                                                filled with the agent;
                                                                                                                              —workers responsible for clean-up should allow for maximum settling of all
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                                                                                                                                particulates before reentering area and wear appropriate personal protective
                                                                                                                                equipment; and
                                                                                                                              —all spills should be cleaned up immediately in accordance with good indus-
                                                                                                                                trial hygiene practices.




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                                                               Federal Register / Vol. 83, No. 193 / Thursday, October 4, 2018 / Rules and Regulations                                         50035

                                                        End-use                     Substitute          Decision                                          Further Information 1

                                                                                                                          As required by the manufacturer, units installed in normally occupied spaces
                                                                                                                            will be equipped with features such as a system-isolate switch and cross-
                                                                                                                            zone detection system to reduce risk of accidental activation of an agent
                                                                                                                            generator while persons are present in the protected space. Also required by
                                                                                                                            the manufacturer is warning of pending discharge and delay in release to en-
                                                                                                                            sure egress prior to activation of the agent to reduce the risk of exposure.
                                                                                                                          See additional comments 1, 2, 3, 4, 5.
                                               1. The EPA recommends that users consult Section VIII of the OSHA Technical Manual for information on selecting the appropriate types of
                                             personal protective equipment for all listed fire suppression agents. The EPA has no intention of duplicating or displacing OSHA coverage related
                                             to the use of personal protective equipment (e.g., respiratory protection), fire protection, hazard communication, worker training or any other oc-
                                             cupational safety and health standard with respect to halon substitutes.
                                               2. Use of all listed fire suppression agents should conform to relevant OSHA requirements, including 29 CFR part 1910, subpart L, sections
                                             1910.160 and 1910.162.
                                               3. Per OSHA requirements, protective gear (SCBA) should be available in the event personnel should reenter the area.
                                               4. Discharge testing should be strictly limited to that which is essential to meet safety or performance requirements.
                                               5. The agent should be recovered from the fire protection system in conjunction with testing or servicing, and recycled for later use or
                                             destroyed.

                                                        End-use                     Substitute          Decision                                          Further Information 1

                                                                                                                        Cleaning Solvents

                                             Electronics cleaning, met-         HFO–                Acceptable ......     HFO–1336mzz(Z) has no ozone depletion potential (ODP) and a 100-year
                                               als cleaning, precision           1336mzz(Z).                                GWP of approximately nine. EPA has proposed to exclude it from the defini-
                                               cleaning.                                                                    tion of volatile organic compounds under CAA regulations (see 40 CFR
                                                                                                                            51.100(s)) addressing the development of state implementation plans (SIPs)
                                                                                                                            to attain and maintain the National Ambient Air Quality Standards (NAAQS).
                                                                                                                          This compound is nonflammable.
                                                                                                                          The Occupational Alliance for Risk Science (OARS) has established a Work-
                                                                                                                            place Environmental Exposure Limit (WEEL) of 500 ppm (8-hr TWA) for
                                                                                                                            HFO–1336mzz(Z).
                                                                                                                          This substitute is subject to a Toxic Substance Control Act (TSCA) section
                                                                                                                            5(a)(2) Significant New Use Rule (SNUR) (40 CFR 721.10830).

                                                                                                                            Aerosols

                                             Aerosol solvents ...............   HFO–                Acceptable ......     HFO–1336mzz(Z) has no ozone depletion potential (ODP) and a 100-year
                                                                                 1336mzz(Z).                                GWP of approximately nine. EPA has proposed to exclude it from the defini-
                                                                                                                            tion of volatile organic compounds under CAA regulations (see 40 CFR
                                                                                                                            51.100(s)) addressing the development of state implementation plans (SIPs)
                                                                                                                            to attain and maintain the National Ambient Air Quality Standards (NAAQS).
                                                                                                                          This compound is nonflammable.
                                                                                                                          The OARS has established a Workplace Environmental Exposure Limit
                                                                                                                            (WEEL) of 500 ppm (8-hr TWA) for HFO–1336mzz(Z).
                                                                                                                          This substitute is subject to a Toxic Substance Control Act (TSCA) section
                                                                                                                            5(a)(2) Significant New Use Rule (SNUR) (40 CFR 721.10830).
                                                1 Observe   recommendations in the manufacturer’s SDS and guidance for all listed substitutes.


                                             [FR Doc. 2018–21463 Filed 10–3–18; 8:45 am]              Allotments to reallot channel 17 from                  stations and receive over-the-air service
                                             BILLING CODE 6560–50–P                                   Block Island, Rhode Island, to Newport,                from WPXQ.
                                                                                                      Rhode Island. The Commission also                      DATES: Effective October 4, 2018.
                                                                                                      grants ION’s request to change WPXQ’s
                                                                                                                                                             FOR FURTHER INFORMATION CONTACT:
                                             FEDERAL COMMUNICATIONS                                   community of license to Newport,
                                                                                                                                                             Darren Fernandez, Media Bureau, at
                                             COMMISSION                                               Rhode Island, amending the DTV Table                   Darren.Fernandez@fcc.gov; or Joyce
                                                                                                      of Allotments to reflect this change                   Bernstein, Media Bureau, at
                                             47 CFR Part 73                                           while modifying WPXQ’s license to                      Joyce.Bernstein@fcc.gov.
                                             [MB Docket No. 18–153; RM–11801; DA 18–                  reflect that its community of license is
                                                                                                                                                             SUPPLEMENTARY INFORMATION: This is a
                                             962]                                                     Newport, Rhode Island. The new
                                                                                                                                                             summary of the Report and Order in MB
                                                                                                      allotment will be mutually exclusive
                                                                                                                                                             Docket No. 18–153; RM–11801; DA 18–
                                             Television Broadcasting Services;                        with WPXQ’s existing allotment and the
                                                                                                                                                             962, adopted September 18, 2018, and
                                             Block Island and Newport, Rhode                          reallotment will result in a preferential
                                                                                                                                                             released September 18, 2018. The full
                                             Island                                                   arrangement of allotments pursuant to                  text of this document is available for
                                                                                                      the Commission’s second allotment                      public inspection and copying during
daltland on DSKBBV9HB2PROD with RULES




                                             AGENCY:  Federal Communications
                                             Commission.                                              priority by providing Newport its first                normal business hours in the FCC’s
                                                                                                      local television service. The reallotment              Reference Information Center at Portals
                                             ACTION: Final rule.
                                                                                                      will cause no public harm because                      II, CY–A257, 445 12th Street SW,
                                             SUMMARY:  At the request of ION                          Block Island will continue to be served                Washington, DC 20554, or online at
                                             Television License, LLC (ION), the                       by five full power commercial and one                  http://apps.fcc.gov/ecfs/. To request
                                             Commission amends the DTV Table of                       full power non-commercial television                   materials in accessible formats (braille,


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Document Created: 2018-10-04 02:02:25
Document Modified: 2018-10-04 02:02:25
CategoryRegulatory Information
CollectionFederal Register
sudoc ClassAE 2.7:
GS 4.107:
AE 2.106:
PublisherOffice of the Federal Register, National Archives and Records Administration
SectionRules and Regulations
ActionDetermination of acceptability.
DatesThis determination is applicable on October 4, 2018.
ContactGerald Wozniak by telephone at (202) 343-9624, by email at [email protected], or by mail at U.S. Environmental Protection Agency, Mail Code 6205T, 1200 Pennsylvania Avenue NW, Washington, DC 20460. Overnight or courier deliveries should be sent to the office location at 1201 Constitution Avenue NW, Washington, DC 20004.
FR Citation83 FR 50026 
RIN Number2060-AG12
CFR AssociatedEnvironmental Protection; Administrative Practice and Procedure; Air Pollution Control and Reporting and Recordkeeping Requirements

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