83_FR_61356 83 FR 61127 - Air Quality: Revision to the Regulatory Definition of Volatile Organic Compounds-Exclusion of cis-1,1,1,4,4,4-hexafluorobut-2-ene (HFO-1336mzz-Z)

83 FR 61127 - Air Quality: Revision to the Regulatory Definition of Volatile Organic Compounds-Exclusion of cis-1,1,1,4,4,4-hexafluorobut-2-ene (HFO-1336mzz-Z)

ENVIRONMENTAL PROTECTION AGENCY

Federal Register Volume 83, Issue 229 (November 28, 2018)

Page Range61127-61134
FR Document2018-25891

On May 1, 2018, the U.S. Environmental Protection Agency (EPA) published a proposed rule seeking comments in response to a petition requesting the revision of the EPA's regulatory definition of volatile organic compounds (VOC) to exempt cis-1,1,1,4,4,4-hexafluorobut-2-ene (also known as HFO-1336mzz-Z; CAS number 692-49-9). The EPA is now taking final action to revise the regulatory definition of VOC under the Clean Air Act (CAA). This final action adds HFO-1336mzz-Z to the list of compounds excluded from the regulatory definition of VOC on the basis that this compound makes a negligible contribution to tropospheric ozone (O3) formation.

Federal Register, Volume 83 Issue 229 (Wednesday, November 28, 2018)
[Federal Register Volume 83, Number 229 (Wednesday, November 28, 2018)]
[Rules and Regulations]
[Pages 61127-61134]
From the Federal Register Online  [www.thefederalregister.org]
[FR Doc No: 2018-25891]


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ENVIRONMENTAL PROTECTION AGENCY

40 CFR Part 51

[EPA-HQ-OAR-2017-0175; FRL-9987-02-OAR]
RIN 2060-AT52


Air Quality: Revision to the Regulatory Definition of Volatile 
Organic Compounds--Exclusion of cis-1,1,1,4,4,4-hexafluorobut-2-ene 
(HFO-1336mzz-Z)

AGENCY: Environmental Protection Agency (EPA).

ACTION: Final rule.

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SUMMARY: On May 1, 2018, the U.S. Environmental Protection Agency (EPA) 
published a proposed rule seeking comments in response to a petition 
requesting the revision of the EPA's regulatory definition of volatile 
organic compounds (VOC) to exempt cis-1,1,1,4,4,4-hexafluorobut-2-ene 
(also known as HFO-1336mzz-Z; CAS number 692-49-9). The EPA is now 
taking final action to revise the regulatory definition of VOC under 
the Clean Air Act (CAA). This final action adds HFO-1336mzz-Z to the 
list of compounds excluded from the regulatory definition of VOC on the 
basis that this compound makes a negligible contribution to 
tropospheric ozone (O3) formation.

DATES: This final rule is effective on January 28, 2019.

ADDRESSES: The EPA has established a docket for this action under 
Docket ID No. EPA-HQ-OAR-2017-0175. All documents in the docket are 
listed on the https://www.regulations.gov website. Although listed in 
the index, some information is not publicly available, e.g., 
Confidential Business Information or other information whose disclosure 
is restricted by statute. Certain other material, such as copyrighted 
materials, is not placed on the internet and will be publicly available 
only in hard copy form. Publicly available docket materials are 
available electronically through https://www.regulations.gov.

FOR FURTHER INFORMATION CONTACT: Dr. Souad Benromdhane, Office of Air 
Quality Planning and Standards, Health and Environmental Impacts 
Division, Mail Code C539-07, Environmental Protection Agency, Research 
Triangle Park, NC 27711; telephone: (919) 541-4359; fax number: (919) 
541-5315; email address: [email protected].

SUPPLEMENTARY INFORMATION:

Table of Contents

I. Does this action apply to me?
II. Background
    A. The EPA's VOC Exemption Policy
    B. Petition To List HFO-1336mzz-Z as an Exempt Compound
III. The EPA's Assessment of the Petition
    A. Contribution to Tropospheric Ozone Formation
    B. Potential Impacts on Other Environmental Endpoints
    1. Contribution to Stratospheric Ozone Depletion
    2. The Significant New Alternatives Policy (SNAP) Program 
Acceptability Findings
    3. Toxicity
    4. Contribution to Climate Change
    C. Response to Comments and Conclusion
IV. Final Action
V. Statutory and Executive Order Reviews
    A. Executive Order 12866: Regulatory Planning and Review and 
Executive Order 13563: Improving Regulation and Regulatory Review
    B. Executive Order 13771: Reducing Regulations and Controlling 
Regulatory Costs
    C. Paperwork Reduction Act (PRA)
    D. Regulatory Flexibility Act (RFA)
    E. Unfunded Mandates Reform Act (UMRA)
    F. Executive Order 13132: Federalism
    G. Executive Order 13175: Consultation and Coordination With 
Indian Tribal Governments
    H. Executive Order 13045: Protection of Children From 
Environmental Health and Safety Risks
    I. Executive Order 13211: Actions Concerning Regulations That 
Significantly Affect Energy Supply, Distribution or Use
    J. National Technology Transfer and Advancement Act (NTTAA)
    K. Executive Order 12898: Federal Actions To Address 
Environmental Justice in Minority Populations and Low-Income 
Populations
    L. Congressional Review Act (CRA)
    M. Judicial Review

I. Does this action apply to me?

    Entities potentially affected by this final rule include, but are 
not necessarily limited to, the following: State and local air 
pollution control agencies that adopt and implement regulations to 
control air emissions of VOC; and industries manufacturing and/or using 
HFO-1336mzz-Z for use in polyurethane rigid insulating foams, 
refrigeration, and air conditioning. Potential entities that may be 
affected by this action include:

[[Page 61128]]



   Table 1--Potentially Affected Entities by North American Industrial
                   Classification System (NAICS) Code
------------------------------------------------------------------------
                                                      Description of
            Category               NAICS code       regulated entities
------------------------------------------------------------------------
Industry.......................          326140  Polystyrene Foam
                                                  Product Manufacturing.
Industry.......................          326150  Urethane and Other Foam
                                                  Product (except
                                                  Polystyrene)
                                                  Manufacturing.
Industry.......................          333415  Air-Conditioning and
                                                  Warm Air Heating
                                                  Equipment and
                                                  Commercial and
                                                  Industrial
                                                  Refrigeration
                                                  Equipment
                                                  Manufacturing.
Industry.......................            3363  Motor Vehicle Parts
                                                  Manufacturing.
Industry.......................          336611  Ship Building and
                                                  Repairing.
Industry.......................          336612  Boat Building.
Industry.......................          339999  All other Miscellaneous
                                                  Manufacturing.
------------------------------------------------------------------------

    This table is not intended to be exhaustive, but rather provides a 
guide for readers regarding entities that might be affected by this 
deregulatory action. This table lists the types of entities that the 
EPA is now aware of that could potentially be affected to some extent 
by this action. Other types of entities not listed in the table could 
also be affected to some extent. To determine whether your entity is 
directly or indirectly affected by this action, you should consult your 
state or local air pollution control and/or air quality management 
agencies.

II. Background

A. The EPA's VOC Exemption Policy

    Tropospheric O3, commonly known as smog, is formed when VOC and 
nitrogen oxides (NOX) react in the atmosphere in the presence of 
sunlight. Because of the harmful health effects of O3, the EPA and 
state governments limit the amount of VOC that can be released into the 
atmosphere. VOC form O3 through atmospheric photochemical reactions, 
and different VOC have different levels of reactivity. That is, 
different VOC do not react to form O3 at the same speed or do not form 
O3 to the same extent. Some VOC react slowly or form less O3; 
therefore, changes in their emissions have limited effects on local or 
regional O3 pollution episodes. It has been the EPA's policy since 
1971, that certain organic compounds with a negligible level of 
reactivity should be excluded from the regulatory definition of VOC in 
order to focus VOC control efforts on compounds that significantly 
affect O3 concentrations. The EPA also believes that exempting such 
compounds creates an incentive for industry to use negligibly reactive 
compounds in place of more highly reactive compounds that are regulated 
as VOC. The EPA lists compounds that it has determined to be negligibly 
reactive in its regulations as being excluded from the regulatory 
definition of VOC (40 CFR 51.100(s)).
    The CAA requires the regulation of VOC for various purposes. 
Section 302(s) of the CAA specifies that the EPA has the authority to 
define the meaning of ``VOC'' and, hence, what compounds shall be 
treated as VOC for regulatory purposes. The policy of excluding 
negligibly reactive compounds from the regulatory definition of VOC was 
first laid out in the ``Recommended Policy on Control of Volatile 
Organic Compounds'' (42 FR 35314, July 8, 1977) (from here forward 
referred to as the 1977 Recommended Policy) and was supplemented 
subsequently with the ``Interim Guidance on Control of Volatile Organic 
Compounds in Ozone State Implementation Plans'' (70 FR 54046, September 
13, 2005) (from here forward referred to as the 2005 Interim Guidance). 
The EPA uses the reactivity of ethane as the threshold for determining 
whether a compound has negligible reactivity. Compounds that are less 
reactive than, or equally reactive to, ethane under certain assumed 
conditions may be deemed negligibly reactive and, therefore, suitable 
for exemption from the regulatory definition of VOC. Compounds that are 
more reactive than ethane continue to be considered VOC for regulatory 
purposes and, therefore, are subject to control requirements. The 
selection of ethane as the threshold compound was based on a series of 
smog chamber experiments that underlay the 1977 Recommended Policy.
    The EPA has used three different metrics to compare the reactivity 
of a specific compound to that of ethane: (i) The rate constant for 
reaction with the hydroxyl radical (OH) (known as kOH); (ii) 
the maximum incremental reactivity (MIR) on a reactivity per unit mass 
basis; and (iii) the MIR expressed on a reactivity per mole basis. 
Differences between these three metrics are discussed below.
    The kOH is the rate constant of the reaction of the 
compound with the OH radical in the air. This reaction is often, but 
not always, the first and rate-limiting step in a series of chemical 
reactions by which a compound breaks down in the air and contributes to 
O3 formation. If this step is slow, the compound will likely 
not form O3 at a very fast rate. The kOH values 
have long been used by the EPA as metrics of photochemical reactivity 
and O3-forming activity, and they were the basis for most of 
the EPA's early exemptions of negligibly reactive compounds from the 
regulatory definition of VOC. The kOH metric is inherently a 
molar-based comparison, i.e., it measures the rate at which molecules 
react.
    The MIR, both by mole and by mass, is a more updated metric of 
photochemical reactivity derived from a computer-based photochemical 
model, and it has been used as a metric of reactivity since 1995. This 
metric considers the complete O3-forming activity of a 
compound over multiple hours and through multiple reaction pathways, 
not merely the first reaction step with OH. Further explanation of the 
MIR metric can be found in Carter (1994).
    The EPA has considered the choice between MIRs with a molar or mass 
basis for the comparison to ethane in past rulemakings and guidance. In 
the 2005 Interim Guidance, the EPA stated:

    [A] comparison to ethane on a mass basis strikes the right 
balance between a threshold that is low enough to capture compounds 
that significantly affect ozone concentrations and a threshold that 
is high enough to exempt some compounds that may usefully substitute 
for more highly reactive compounds.
    When reviewing compounds that have been suggested for VOC-exempt 
status, EPA will continue to compare them to ethane using 
kOH expressed on a molar basis and MIR values expressed 
on a mass basis.

    The 2005 Interim Guidance notes that the EPA will consider a 
compound to be negligibly reactive if it is equally as or less reactive 
than ethane based on either kOH expressed on a molar basis 
or MIR values expressed on a mass basis.
    The molar comparison of MIR is more consistent with the original 
smog chamber experiments, which compared equal molar concentrations of 
individual VOCs, supporting the selection of ethane as the threshold, 
while the mass-based comparison of MIR is consistent with how MIR 
values and other reactivity metrics are applied

[[Page 61129]]

in reactivity-based emission limits. It is, however, important to note 
that the mass-based comparison is slightly less restrictive than the 
molar-based comparison in that a few more compounds would qualify as 
negligibly reactive.
    Given the two goals of the exemption policy articulated in the 2005 
Interim Guidance, the EPA believes that ethane continues to be an 
appropriate threshold for defining negligible reactivity. And, to 
encourage the use of environmentally beneficial substitutions, the EPA 
believes that a comparison to ethane on a mass basis strikes the right 
balance between a threshold that is low enough to capture compounds 
that significantly affect O3 concentrations and a threshold 
that is high enough to exempt some compounds that may usefully 
substitute for more highly reactive compounds.
    The 2005 Interim Guidance also noted that concerns have sometimes 
been raised about the potential impact of a VOC exemption on 
environmental endpoints other than O3 concentrations, 
including fine particle formation, air toxics exposures, stratospheric 
O3 depletion, and climate change. The EPA has recognized, 
however, that there are existing regulatory or non-regulatory programs 
that are specifically designed to address these issues, and the EPA 
continues to believe in general that the impacts of VOC exemptions on 
environmental endpoints other than O3 formation can be 
adequately addressed by these programs. The VOC exemption policy is 
intended to facilitate attainment of the O3 National Ambient 
Air Quality Standards (NAAQS) and VOC exemption decisions will continue 
to be based primarily on consideration of a compound's contribution to 
O3 formation. However, if the EPA determines that a 
particular VOC exemption is likely to result in a significant increase 
in the use of a compound and that the increased use would pose a 
significant risk to human health or the environment that would not be 
addressed adequately by existing programs or policies, then the EPA may 
exercise its judgment accordingly in deciding whether to grant an 
exemption.

B. Petition To List HFO-1336mzz-Z as an Exempt Compound

    DuPont Chemicals & Fluoroproducts (DuPont) submitted a petition to 
the EPA on February 14, 2014, requesting that cis-1,1,1,4,4,4-
hexafluorobut-2-ene (HFO-1336mzz-Z; CAS number 692-49-9) be exempted 
from the regulatory definition of VOC. The petition was based on the 
argument that HFO-1336mzz-Z has low reactivity relative to ethane. The 
petitioner indicated that HFO-1336mzz-Z may be used in a variety of 
applications as a replacement for foam expansion or blowing agents with 
higher global warming potential (GWP) (>700 GWP) for use in 
polyurethane rigid insulating foams, among others. It is also a new 
developmental refrigerant as a potential working fluid for Organic 
Rankine Cycles (ORC).\1\
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    \1\ Konstantinos Kontomaris, 2014, HFO-1336mzz-Z High 
Temperature Chemical Stability and Use as a Working Fluid in Organic 
Rankine Cycles. International Refrigeration and Air Conditioning 
Conference. Purdue University: https://www.chemours.com/Refrigerants/en_US/products/Opteon/Stationary_Refrigeration/assets/downloads/2014_Purdue-Paper-Opteon-MZ.pdf.
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    To support its petition, DuPont referenced several documents, 
including one peer-reviewed journal article on HFO-1336mzz-Z reaction 
rates (Baasandorj, M. et al., 2011). DuPont also provided a 
supplemental technical report on the MIR of HFO-1336mzz-Z (Carter, 
2011a). Per this report, the MIR of HFO-1336mzz-Z is 0.04 gram (g) 
O3/g HFO-1336mzz-Z on the mass-based MIR scale. This 
reactivity rate is 86 percent lower than that of ethane (0.28 g 
O3/g ethane). The reactivity rate kOH for the 
gas-phase reaction of OH radicals with HFO-1336mzz-Z (kOH) 
has been measured to be 4.91 x 10-13 centimeter (cm)\3\/
molecule-seconds at ~296 degrees Kelvin (K) (Pitts et al., 1983, 
Baasandorj et al., 2011). This kOH rate is twice as high as 
that of ethane (kOH of ethane = 2.4 x 10-13 
cm\3\/molecule-sec at ~298 K) and, therefore, suggests that HFO-
1336mzz-Z is twice as reactive as ethane. In most cases, chemicals with 
high kOH values also have high MIR values, but for HFO-
1336mzz-Z, the products that are formed in subsequent reactions are 
expected to be poly fluorinated compounds, which do not contribute to 
O3 formation (Baasandorj et al., 2011). Based on the current 
scientific understanding of tetrafluoroalkene reactions in the 
atmosphere, it is unlikely that the actual O3 impact on a 
mass basis would equal or exceed that of ethane in the scenarios used 
to calculate VOC reactivity (Baasandorj et al., 2011; Carter, 2011a).
    To address the potential for stratospheric O3 impacts, 
the petitioner contended that, because the atmospheric lifetime of HFO-
1336mzz-Z due to loss by OH reaction was estimated to be ~20 days and 
it does not contain chlorine or bromine, it is not expected to 
contribute to the depletion of the stratospheric O3 layer.

III. The EPA's Assessment of the Petition

    On May 1, 2018, the EPA published a proposed rulemaking (83 FR 
19026) seeking comments in response to the petition to revise the EPA's 
regulatory definition of VOC for exemption of HFO-1336mzz-Z. The EPA is 
taking final action to respond to the petition by exempting HFO-
1336mzz-Z from the regulatory definition of VOC. This action is based 
on consideration of the compound's low contribution to tropospheric 
O3 and the low likelihood of risk to human health or the 
environment, including stratospheric O3 depletion, toxicity, 
and climate change. Additional information on these topics is provided 
in the following sections.

A. Contribution to Tropospheric Ozone Formation

    As noted in studies cited by the petitioner, HFO-1336mzz-Z has a 
MIR value of 0.04 g O3/g VOC for ``averaged conditions,'' 
versus 0.28 g O3/g VOC for ethane (Carter, 2011). Therefore, 
the EPA considers HFO-1336mzz-Z to be negligibly reactive and eligible 
for VOC-exempt status in accordance with the Agency's long-standing 
policy that compounds should so qualify where either reactivity metric 
(kOH expressed on a molar basis or MIR expressed on a mass 
basis) indicates that the compound is less reactive than ethane. While 
the overall atmospheric reactivity of HFO-1336mzz-Z was not studied in 
an experimental smog chamber, the chemical mechanism derived from other 
chamber studies (Carter, 2011) was used to model the complete formation 
of O3 for an entire single day under realistic atmospheric 
conditions (Carter, 2011a). Therefore, the EPA believes that the MIR 
value calculated in the Carter study submitted by the petitioner is 
reliable.
    Table 2 presents three reactivity metrics for HFO-1336mzz-Z as they 
compare to ethane.

[[Page 61130]]



                                Table 2--Reactivities of Ethane and HFO-1336mzz-Z
----------------------------------------------------------------------------------------------------------------
                                                                                      Maximum
                                                                                    incremental       Maximum
                                                                    kOH (cm\3\/     reactivity      incremental
                            Compound                               molecule-sec)   (MIR) (g O3/     reactivity
                                                                                     mole VOC)     (MIR) (g O3/g
                                                                                                       VOC)
----------------------------------------------------------------------------------------------------------------
Ethane..........................................................     2.4 x 10-13             8.4            0.28
HFO-1336mzz-Z...................................................    4.91 x 10-13             6.6            0.04
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Notes:
\1.\ kOH value at 298 K for ethane is from Atkinson et al., 2006 (page 3626).
\2.\ kOH value at 296 K for HFO-1336mzz-Z is from Baasandorj, 2011.
\3.\ Mass-based MIR value (g O3/g VOC) of ethane is from Carter, 2011.
\4.\ Mass-based MIR value (g O3/g VOC) of HFO-1336mzz-Z is from a supplemental report by Carter, 2011a.
\5.\ Molar-based MIR (g O3/mole VOC) values were calculated from the mass-based MIR (g O3/g VOC) values using
  the number of moles per gram of the relevant organic compound.

    The reaction rate of HFO-1336mzz-Z with the OH radical 
(kOH) has been measured to be 4.91 x 10-13 cm\3\/
molecule-sec (Baasandorj et al., 2011); other reactions with 
O3 and the nitrate radical were negligibly small. The 
corresponding reaction rate of ethane with OH is 2.4 x 
10-13cm\3\/molecule-sec (Atkinson et al., 2006). The data in 
Table 2 show that HFO-1336mzz-Z has a higher kOH value than 
ethane, meaning that it initially reacts twice as fast in the 
atmosphere as ethane. However, the resulting unsaturated fluorinated 
compounds in the atmosphere are short lived and react more slowly to 
form O3 (Baasandorj et al., 2011). The mass based MIR is 
0.04 g O3/g VOC and much lower than that of ethane.
    A molecule of HFO-1336mzz-Z is less reactive than a molecule of 
ethane in terms of complete O3-forming activity as shown by 
the molar-based MIR (g O3/mole VOC) values. One gram of HFO-
1336mzz-Z has a lower capacity than one gram of ethane to form 
O3 in terms of a mass-based MIR. Thus, following the 2005 
Interim Guidance in striking a balance between reactivity on a molar 
basis as well as a gram basis, the EPA finds HFO-1336mzz-Z to be 
eligible for exemption from the regulatory definition of VOC based on 
both the molar- and mass-based MIR.

B. Potential Impacts on Other Environmental Endpoints

    The EPA's decision to exempt HFO-1336mzz-Z from the regulatory 
definition of VOC is based on our findings above. However, as noted in 
the 2005 Interim Guidance, the EPA reserves the right to exercise its 
judgment in certain cases where an exemption is likely to result in a 
significant increase in the use of a compound and a subsequent 
significantly increased risk to human health or the environment. In 
this case, the EPA does not find that exemption of HFO-1336mzz-Z would 
result in an increase of risk to human health or the environment, with 
regard to stratospheric O3 depletion, toxicity and climate 
change. Additional information on these topics is provided in the 
following sections.
1. Contribution to Stratospheric Ozone Depletion
    HFO-1336mzz-Z is unlikely to contribute to the depletion of the 
stratospheric O3 layer. The O3 depletion 
potential (ODP) of HFO-1336mzz-Z is expected to be negligible based on 
several lines of evidence: The absence of chlorine or bromine in the 
compound and the atmospheric reactions described in Carter (2008). 
Because HFO-1336mzz-Z has a kOH value that is twice as high 
as that of ethane (see section III.A ``Contribution to Tropospheric 
Ozone Formation''), it will decay before it has a chance to reach the 
stratosphere and, thus, will not participate in O3 
destruction.
2. The Significant New Alternatives Policy (SNAP) Program Acceptability 
Findings
    The SNAP program is the EPA's program to evaluate and regulate 
substitutes for end-uses historically using O3-depleting 
chemicals. Under section 612(c) of the CAA, the EPA is required to 
identify and publish lists of acceptable and unacceptable substitutes 
for class I or class II O3-depleting substances. Per the 
SNAP program findings, the ODP of HFO-1336mzz-Z is zero. The SNAP 
program has listed HFO-1336mzz-Z as an acceptable substitute for a 
number of foam blowing end-uses provided in 79 FR 62863, October 21, 
2014 (USEPA, 2014), and as an acceptable substitute in the 
refrigeration and air conditioning sector in heat transfer, as well as 
in chillers and industrial process air conditioning provided in 81 FR 
32241, May 23, 2016 (USEPA, 2016).
3. Toxicity
    Based on screening assessments of the health and environmental 
risks of HFO-1336mzz-Z, the SNAP program anticipated that users will be 
able to use the compound without significantly greater health risks 
than presented by use of other available substitutes for the same uses 
(USEPA, 2014, 2016).
    The EPA anticipates that HFO-1336mzz-Z will be used consistent with 
the recommendations specified in the material safety data sheet (SDS) 
(DuPont, 2011). According to the SDS, potential health effects from 
inhalation of HFO-1336mzz-Z include skin or eye irritation or 
frostbite. Exposure to high concentrations of HFO-1336mzz-Z from misuse 
or intentional inhalation abuse may cause irregular heartbeat. In 
addition, HFO-1336mzz-Z could cause asphyxiation if air is displaced by 
vapors in a confined space. The Workplace Environmental Exposure Limit 
(WEEL) committee of the Occupational Alliance for Risk Science (OARS) 
reviewed available animal toxicity data and recommends a WEEL for the 
workplace of 500 parts per million (ppm) (3350 mg/m\3\) time-weighted 
average (TWA) for an 8-hour workday as provided in the OARS (OARS, 
2014).\2\ This WEEL was derived based on reduced male body weight in 
the 13-week rat inhalation toxicity study (Dupont, 2011). The WEEL is 
also protective against skeletal fluorosis, which may occur at higher 
exposures because of metabolism. The EPA anticipates that users will be 
able to meet the WEEL and address potential health risks by following 
requirements and recommendations in the SDS and other safety 
precautions common to the refrigeration and air conditioning industry.
---------------------------------------------------------------------------

    \2\ Occupational Alliance for Risk Science (OARS-WEELs)--HFO-
1336mzz-Z, 2014: https://www.tera.org/OARS/HFO-1336mzz-Z%20WEEL%20FINAL.pdf.

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[[Page 61131]]

    HFO-1336mzz-Z is not regulated as a hazardous air pollutant (HAP) 
under title I of the CAA. Also, it is not listed as a toxic chemical 
under section 313 of the Emergency Planning and Community Right-to-Know 
Act (EPCRA).
    The Toxic Substances Control Act (TSCA) gives the EPA authority to 
assess and prevent potential unreasonable risks to human health and the 
environment before a new chemical substance is introduced into 
commerce. Section 5 of TSCA requires manufacturers and importers to 
notify the EPA before manufacturing or importing a new chemical 
substance by submitting a Premanufacture Notice (PMN) prior to the 
manufacture (including import) of the chemical. Under the TSCA New 
Chemicals Program, the EPA then assesses whether an unreasonable risk 
may, or will, be presented by the expected manufacturing, processing, 
distribution in commerce, use, and disposal of the new substance. The 
EPA has determined, however, that domestic manufacturing, use in non-
industrial products, or use other than as described in the PMN may 
cause serious chronic health effects. To mitigate risks identified 
during the PMN review of HFO-1336mzz-Z, the EPA issued a Significant 
New Use Rule (SNUR) under TSCA on June 5, 2015, to require persons to 
submit a Significant New Use Notice (SNUN) to the EPA at least 90 days 
before they manufacture or process HFO-1336mzz-Z for uses other than 
those described in the PMN (80 FR 32003, 32005, June 5, 2015). The 
required notification will provide the EPA with the opportunity to 
evaluate the intended use and, if necessary, to prohibit or limit that 
activity before it occurs. The EPA, therefore, believes that existing 
programs address the risk of toxicity associated with the use of HFO-
1336mzz-Z.
4. Contribution to Climate Change
    The Intergovernmental Panel on Climate Change (IPCC) Fifth 
Assessment Report (IPCC AR5) estimated the lifetime of HFO-1336mzz-Z to 
be approximately 22 days (Baasandorj et al., 2011), and the gas-phase 
degradation of HFO-1336-mzz-Z is not expected to lead to a significant 
formation of atmospherically long-lived species. The radiative 
efficiency of HFO-1336-mzz-Z was calculated to be 0.38 watts per square 
meter at the earth's surface per part per billion concentration of the 
material (W m-2 ppb-1) based on Baasandorj et 
al., 2011. The report estimated the resulting 100-year GWP to be 9, 
meaning that, over a 100-year period, one ton of HFO-1336mzz-Z traps 9 
times as much warming energy as one ton of carbon dioxide 
(CO2) (IPCC, 2013). HFO-1336mzz-Z's GWP of 9 is lower than 
those of some of the substitutes in a variety of foam blowing end-uses 
and in centrifugal and positive displacement chillers, heat transfer, 
and industrial process air conditioning. HFO-1336mzz-Z was developed to 
replace other chemicals used for similar end-uses with GWP ranging from 
725 to 5,750 such as CFC-11, CFC-113, HCFC-141b and HCFC-22. The 
petitioner claims that HFO-1336mzz-Z is a better alternative to other 
substitutes in foam expansion or blowing agents for use in polyurethane 
rigid insulating foams. Thermal test data and energy efficiency trials 
indicate that HFO-1336mzz-Z will provide superior insulating value and, 
thus, reduces climate change impacts both directly by its relatively 
low GWP and indirectly by decreasing energy consumption throughout the 
lifecycle of insulated foams in appliances, buildings, refrigerated 
storage and transportation.

C. Response to Comments and Conclusion

    The EPA received five comments on the May 1, 2018, notice of 
proposed rulemaking. One commenter supported the proposed action to 
exempt HFO-1336mzz-Z from the EPA's definition of VOC in 40 CFR 
51.100(s), one opposed the proposed action, and three raised issues 
that were outside the scope of this rulemaking including a discussion 
about air and water quality in Asia and Mexico, and climate change. 
These three anonymous comments failed to identify any specific issue 
that is germane to our proposal to exempt HFO-1336mzz-Z. Substantial 
comments and the EPA's responses are provided below.
    Comment: One commenter (ID: EPA-HQ-OAR-2017-0175-0010) expressed 
concern that ``the EPA should not exempt HFO-1336mzz-Z . . . [and that] 
. . . surely there is a reason it was . . . [regulated as a VOC] in the 
first place.'' The commenter expressed skepticism that ``other 
regulatory groups outside of the EPA'' would prevent the compound from 
being used, if there were other environmental impacts than 
O3, once the EPA exempted this compound. This commenter also 
expressed concern that the petitioner's data ``could potentially be 
biased'' and they ``. . . would like to read a proposal that gets its 
information from a more unbiased source and considers how it will deal 
with possible drawbacks of deregulating HFO-1336mzz-Z.''
    Response: The commenter appears to state that HFO-1336mzz-Z should 
not be exempted from the definition of VOC simply because it is 
currently included in the definition of VOC. This is a circular 
argument, and, if followed, the EPA would never be able to exempt any 
substances from the definition of VOC, even where, as here, scientific 
data supported such an exemption. The commenter does not provide any 
scientific evidence that rebuts the petitioner's data supporting the 
demonstration that HFO-1336mzz-Z is eligible for this exemption.
    The reason HFO-1336mzz-Z is currently regulated as a VOC is because 
it meets the EPA's definition of VOC in 40 CFR 51.100(s) as ``any 
compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic 
acid . . . which participates in atmospheric photochemical reactions.'' 
[emphasis added] The petitioner submitted data to the EPA that show 
HFO-1336mzz-Z negligibly participates in atmospheric photochemical 
reactions, presenting a better environmental alternative for similar 
industrial applications, and therefore should be excluded from the 
definition of VOC. As explained above, our approval would allow states 
to encourage VOC substitutions with negligibly reactive compounds that 
would reduce O3 formation.
    The EPA would like to clarify the statement in the proposal which 
referred to ``existing regulatory or non-regulatory programs that are 
specifically designed to address'' other environmental issues besides 
tropospheric O3 formation, such as fine particle formation, 
air toxics exposures, stratospheric O3 depletion, and 
climate change. When referring to existing regulatory or non-regulatory 
programs, the EPA was not referring to ``other regulatory groups 
outside of the EPA,'' as the commenter suggested. Rather, Congress has 
granted the EPA with other authorities under the CAA that allow the 
Agency to address these issues specifically (e.g., NAAQS program for 
fine particle pollution; section 112 for air toxics). As stated in the 
2005 Interim Guidance, where an exemption is likely to result in a 
significant increase in the use of a compound and a subsequent 
significantly increased risk to human health or the environment, the 
EPA reserves the right to exercise its judgment and choose not to grant 
a petition for an exemption from the definition of VOC, even where the 
substance meets the reactivity metrics. However, as explained in 
section III.B. of this final rule, the EPA does not believe an 
exemption of HFO-1336mzz-

[[Page 61132]]

Z will lead to significant environmental impacts.
    To the extent the commenter is raising concerns that the EPA's 
action will result in non-EPA organizations treating HFO-1336mzz-Z 
differently, we note that this action does not prohibit state and local 
air pollution regulatory agencies from regulating HFO-1336mzz-Z. Some 
local agencies continue restrictions on the use of certain compounds 
that have been excluded from the definition of VOC by the EPA.
    With respect to the comment that the petitioner's data could 
potentially be biased, the EPA uses credible, peer-reviewed information 
in its review of VOC exemption petitions. In this regard, and as 
discussed in our proposed rule and in this action, we note that the 
journal article submitted by DuPont on HFO-1336mzz-Z reaction rates was 
performed by the National Oceanic and Atmospheric Administration and 
published in The Journal of Physical Chemistry, a peer-reviewed 
journal. The other primary document relied on to support the exemption 
petition was authored by the researcher who developed the MIR scale 
(Carter, 2011a). Staff in the EPA's Office of Research and Development 
reviewed these documents as part of the petition assessment process and 
find that they are consistent with current understanding of atmospheric 
chemistry. We are not aware of information that would indicate they are 
biased.
    Therefore, for reasons discussed above, the EPA is finalizing this 
rule with no changes. The EPA finds that HFO-1336mzz-Z is negligibly 
reactive with respect to its contribution to tropospheric O3 
formation and, thus, may be exempted from the EPA's definition of VOC 
in 40 CFR 51.100(s). HFO-1336mzz-Z has been listed as acceptable for 
use in several industrial and commercial refrigeration and air 
conditioning end-uses, as well as for use as a blowing agent under the 
SNAP program (USEPA, 2014, 2016). The EPA has also determined that 
exemption of HFO-1336mzz-Z from the regulatory definition of VOC will 
not result in an increase of risk to human health and the environment, 
and, to the extent that use of this compound does have impacts on other 
environmental endpoints, those impacts are adequately managed by 
existing programs. For example, HFO-1336mzz-Z has a similar or lower 
stratospheric O3 depletion potential than available 
substitutes in those end-uses, and the toxicity risk from using HFO-
1336mzz-Z is not significantly greater than the risk from using other 
available alternatives for the same uses. The EPA has concluded that 
non-tropospheric O3-related risks associated with potential 
increased use of HFO-1336mzz-Z are adequately managed by SNAP. The EPA 
does not expect significant use of HFO-1336mzz-Z in applications not 
covered by the SNAP program. To the extent that the compound is used in 
other applications not already reviewed under SNAP or under the New 
Chemicals Program under TSCA, the SNUR in place under TSCA requires 
that any significant new use of a chemical be reported to the EPA using 
a SNUN. Any significant new use of HFO-1336mzz-Z would, thus, need to 
be evaluated by the EPA, and the EPA will continually review the 
availability of acceptable substitute chemicals under the SNAP program.

IV. Final Action

    The EPA is responding to the petition by revising its regulatory 
definition of VOC at 40 CFR 51.100(s) to add HFO-1336mzz-Z to the list 
of compounds that are exempt from the regulatory definition of VOC 
because it is less reactive than ethane based on a comparison of mass-
based MIR and molar-based MIR metrics and is, therefore, considered 
negligibly reactive. As a result of this action, if an entity which 
uses or produces this compound and is subject to the EPA regulations 
limiting the use of VOC in a product, limiting the VOC emissions from a 
facility, or otherwise controlling the use of VOC for purposes related 
to attaining the O3 NAAQS, this compound will not be counted 
as a VOC in determining whether these regulatory obligations have been 
met. This action would affect whether this compound is considered a VOC 
for state regulatory purposes to reduce O3 formation, if a 
state relies on the EPA's regulatory definition of VOC. States are not 
obligated to exclude from control as a VOC those compounds that the EPA 
has found to be negligibly reactive. However, no state may take credit 
for controlling this compound in its O3 control strategy. 
Consequently, reductions in emissions for this compound will not be 
considered or counted in determining whether states have met the rate 
of progress requirements for VOC in State Implementation Plans or in 
demonstrating attainment of the O3 NAAQS.

V. Statutory and Executive Order Reviews

    Additional information about these statutes and Executive Orders 
can be found at https://www2.epa.gov/laws-regulations/laws-and-executive-orders.

A. Executive Order 12866: Regulatory Planning and Review and Executive 
Order 13563: Improving Regulation and Regulatory Review

    This action is not a significant regulatory action and was, 
therefore, not submitted to the Office of Management and Budget (OMB) 
for review.

B. Executive Order 13771: Reducing Regulations and Controlling 
Regulatory Costs

    This action is considered an Executive Order 13771 deregulatory 
action. This final rule provides meaningful burden reduction by 
exempting HFO-1336mzz-Z from the VOC regulatory definition and 
relieving manufacturers, distributers, and users from recordkeeping or 
reporting requirements. This action is voluntary in nature and has non-
quantifiable cost savings given the unpredictability in who or how much 
of it will be used.

C. Paperwork Reduction Act (PRA)

    This action does not impose an information collection burden under 
the PRA. It does not contain any recordkeeping or reporting 
requirements.

D. Regulatory Flexibility Act (RFA)

    I certify that this action will not have a significant economic 
impact on a substantial number of small entities under the RFA. This 
action will not impose any requirements on small entities. This action 
removes HFO-1336mzz-Z from the regulatory definition of VOC and, 
thereby, relieves manufacturers, distributers, and users of the 
compound from tropospheric O3 requirements to control 
emissions of the compound.

E. Unfunded Mandates Reform Act (UMRA)

    This action does not contain any unfunded mandate as described in 
UMRA, 2 U.S.C. 1531-1538, and does not significantly or uniquely affect 
small governments. This action imposes no enforceable duty on any 
state, local or tribal governments, or the private sector.

F. Executive Order 13132: Federalism

    This action does not have federalism implications. It will not have 
substantial direct effects on the states, on the relationship between 
the national government and the states, or on the distribution of power 
and responsibilities among the various levels of government.

[[Page 61133]]

G. Executive Order 13175: Consultation and Coordination With Indian 
Tribal Governments

    This action does not have tribal implications, as specified in 
Executive Order 13175. This final rule removes HFO-1336mzz-Z from the 
regulatory definition of VOC and, thereby, relieves manufacturers, 
distributers and users from tropospheric O3 requirements to 
control emissions of the compound. Thus, Executive Order 13175 does not 
apply to this action.

H. Executive Order 13045: Protection of Children From Environmental 
Health and Safety Risks

    This action is not subject to Executive Order 13045, because it is 
not economically significant as defined in Executive Order 12866, and 
because the EPA does not believe the environmental health or safety 
risks addressed by this action present a disproportionate risk to 
children. Since HFO-1336mzz-Z is utilized in specific industrial 
applications where children are not present and dissipates quickly 
(e.g., lifetime of 22 days) with short-lived end products, there is no 
exposure or disproportionate risk to children. This action removes HFO-
1336mzz-Z from the regulatory definition of VOC and, thereby, relieves 
manufacturers, distributers and users from tropospheric O3 
requirements to control emissions of the compound.

I. Executive Order 13211: Actions Concerning Regulations That 
Significantly Affect Energy Supply, Distribution or Use

    This action is not subject to Executive Order 13211, because it is 
not a significant regulatory action under Executive Order 12866.

J. National Technology Transfer and Advancement Act (NTTAA)

    This rulemaking does not involve technical standards.

K. Executive Order 12898: Federal Actions To Address Environmental 
Justice in Minority Populations and Low-Income Populations

    The EPA believes that this action does not have disproportionately 
high and adverse human health or environmental effects on minority 
populations, low-income populations and/or indigenous peoples, as 
specified in Executive Order 12898 (59 FR 7629 February 16, 1994). This 
action removes HFO-1336mzz-Z from the regulatory definition of VOC and, 
thereby, relieves manufacturers, distributers, and users of the 
compound from tropospheric O3 requirements to control 
emissions of the compound.

L. Congressional Review Act (CRA)

    This action is subject to the CRA, and the EPA will submit a rule 
report to each House of the Congress and to the Comptroller General of 
the United States. This action is not a ``major rule'' as defined by 5 
U.S.C. 804(2).

M. Judicial Review

    Under section 307(b)(1) of the CAA, petitions for judicial review 
of this action must be filed in the United States Court of Appeals for 
the District of Columbia Circuit Court within 60 days from the date the 
final action is published in the Federal Register. Filing a petition 
for review by the Administrator of this final action does not affect 
the finality of this action for the purposes of judicial review nor 
does it extend the time within which a petition for judicial review 
must be filed, and shall not postpone the effectiveness of such action. 
Thus, any petitions for review of this action related to the exemption 
of HFO-1336mzz-Z from the regulatory definition of VOC must be filed in 
the Court of Appeals for the District of Columbia Circuit within 60 
days from the date the final action is published in the Federal 
Register.

References

Atkinson, R., Baulch, D.L., Cox, R.A., Crowley, J.N., Hampson, Jr., 
R.F., Hynes, R.G., Jenkin, M.E., Kerr, J.A., Rossi, M.J., and Troe, 
J. (2006) Evaluated kinetic and photochemical data for atmospheric 
chemistry: Volume II--gas phase reactions of organic species. Atmos. 
Chem. Phys. 6: 3625-4055.
Baasandorj, M., Ravishankara, A.R., Burkholder, J.B. (2011) 
Atmospheric chemistry of (Z)-CF3CH[boxH]CHCF3: OH radical reaction 
rate coefficient and global warming potential. J Phys Chem A. 2011 
Sep 29; 115(38):10539-49. doi: 10.1021/jp206195g.
Carter, W.P.L. (1994) Development of ozone reactivity scales for 
volatile organic compounds. J. Air Waste Manage, 44: 881-899.
Carter, W.P.L. (2008) Reactivity Estimates for Selected Consumer 
Product Compounds, Final Report to California Air Resources Board 
Contract No. 06-408, February 19, 2008. http://www.arb.ca.gov/research/reactivity/consumer_products.pdf.
Carter, W.P.L. (2011) SAPRC Atmospheric Chemical Mechanisms and VOC 
Reactivity Scales, at http://www.engr.ucr.edu/~carter/SAPRC/. Last 
updated in Sept. 14, 2013. Tables of Maximum Incremental Reactivity 
(MIR) Values available at http://www.arb.ca.gov/regact/2009/mir2009/mir2009.htm. May 11, 2011.
Carter, W.P.L. (2011a) Estimation of the ground-level atmospheric 
ozone formation potentials of Cis 1,1,1,4,4,4-HexaFluoro-2-Butene, 
August 8, 2011.
DuPont Haskell. FEA-1100: 90-day inhalation toxicity study in rats; 
Unpublished Report DuPont-17453-785-1; Haskell Laboratory of 
Industrial Toxicology: Newark, DE, 2011.
IPCC, 2007: Climate Change 2007: The Physical Science Basis. 
Contribution of Working Group I to the Fourth Assessment Report of 
the Intergovernmental Panel on Climate Change [Solomon, S., D. Qin, 
M. Manning, Z. Chen, M. Marquis, K.B. Averyt, M. Tignor and H.L. 
Miller (eds.)]. Cambridge University Press, Cambridge, United 
Kingdom and New York, NY, USA, 996 pp.
IPCC, 2013: Climate Change 2013: The Physical Science Basis. 
Contribution of Working Group I to the Fifth Assessment Report of 
the Intergovernmental Panel on Climate Change [Stocker, T.F., D. 
Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, 
Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, 
Cambridge, United Kingdom and New York, NY, USA, 1535 pp.
Pitts, J.N. Jr., Winer, A.M., Aschmann, S.M., Carter, W.P.L., and 
Atkinson, K. (1983), Experimental Protocol for Determining Hydroxyl 
Radical Reaction Rate Constants Environmental Science Research 
Laboratory, ORD, USEPA. EPA600/3-82-038.
USEPA, 2014. Significant New Alternatives Policy Program; Foam 
Blowing Sector; Risk Screen on Substitutes in Rigid Polyurethane 
Appliance Foam; Rigid Polyurethane and Polyisocyanurate Laminated 
Boardstock; Rigid Polyurethane Commercial Refrigeration and Sandwich 
Panels; Rigid Polyurethane Slabstock and Other; Flexible 
Polyurethane; Integral Skin Polyurethane; and Phenolic Insulation 
Board and Bunstock. Substitute: HFO-1336mzz(Z) (Formacel[supreg] 
1100); October 10, 2014. Available online at: https://www.thefederalregister.org/fdsys/pkg/FR-2014-10-21/pdf/2014-24989.pdf.
USEPA, 2016. Significant New Alternatives Policy Program; 
Refrigeration and Air Conditioning Sector; Risk Screen on 
Substitutes for Use in Chillers and Industrial Process Air 
Conditioning Substitute: HFO-1336mzz(Z) (Opteon[supreg] MZ); May 23, 
2016. Available online at: https://www.thefederalregister.org/fdsys/pkg/FR2016-05-23/pdf/2016-12117.pdf.

List of Subjects in 40 CFR Part 51

    Environmental protection, Administrative practice and procedure, 
Air pollution control, Ozone, Reporting and recordkeeping requirements, 
Volatile organic compounds.

    Dated: November 16, 2018.
Andrew R. Wheeler,
Acting Administrator.

    For reasons stated in the preamble, part 51 of chapter I of title 
40 of the Code of Federal Regulations is amended as follows:

[[Page 61134]]

PART 51--REQUIREMENTS FOR PREPARATION, ADOPTION, AND SUBMITTAL OF 
IMPLEMENTATION PLANS

0
1. The authority citation for part 51 continues to read as follows:

    Authority:  23 U.S.C. 101; 42 U.S.C. 7401-7671q.

Subpart F--Procedural Requirements

0
2. Section 51.100 is amended by revising paragraph (s)(1) introductory 
text to read as follows:


Sec.  51.100   Definitions.

* * * * *
    (s) * * *
    (1) This includes any such organic compound other than the 
following, which have been determined to have negligible photochemical 
reactivity: Methane; ethane; methylene chloride (dichloromethane); 
1,1,1-trichloroethane (methyl chloroform); 1,1,2-trichloro-1,2,2-
trifluoroethane (CFC-113); trichlorofluoromethane (CFC-11); 
dichlorodifluoromethane (CFC-12); chlorodifluoromethane (HCFC-22); 
trifluoromethane (HFC-23); 1,2-dichloro 1,1,2,2-tetrafluoroethane (CFC-
114); chloropentafluoroethane (CFC-115); 1,1,1-trifluoro 2,2-
dichloroethane (HCFC-123); 1,1,1,2-tetrafluoroethane (HFC-134a); 1,1-
dichloro 1-fluoroethane (HCFC-141b); 1-chloro 1,1-difluoroethane (HCFC-
142b); 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124); pentafluoroethane 
(HFC-125); 1,1,2,2-tetrafluoroethane (HFC-134); 1,1,1-trifluoroethane 
(HFC-143a); 1,1-difluoroethane (HFC-152a); parachlorobenzotrifluoride 
(PCBTF); cyclic, branched, or linear completely methylated siloxanes; 
acetone; perchloroethylene (tetrachloroethylene); 3,3-dichloro-
1,1,1,2,2-pentafluoropropane (HCFC-225ca); 1,3-dichloro-1,1,2,2,3-
pentafluoropropane (HCFC-225cb); 1,1,1,2,3,4,4,5,5,5-decafluoropentane 
(HFC 43-10mee); difluoromethane (HFC-32); ethylfluoride (HFC-161); 
1,1,1,3,3,3-hexafluoropropane (HFC-236fa); 1,1,2,2,3-pentafluoropropane 
(HFC-245ca); 1,1,2,3,3-pentafluoropropane (HFC-245ea); 1,1,1,2,3-
pentafluoropropane (HFC-245eb); 1,1,1,3,3-pentafluoropropane (HFC-
245fa); 1,1,1,2,3,3-hexafluoropropane (HFC-236ea); 1,1,1,3,3-
pentafluorobutane (HFC-365mfc); chlorofluoromethane (HCFC-31); 1 
chloro-1-fluoroethane (HCFC-151a); 1,2-dichloro-1,1,2-trifluoroethane 
(HCFC-123a); 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-butane 
(C4F9OCH3 or HFE-7100); 2-
(difluoromethoxymethyl)-1,1,1,2,3,3,3-heptafluoropropane 
((CF3)2CFCF2OCH3); 1-
ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane 
(C4F9OC2H5 or HFE-7200); 2-
(ethoxydifluoromethyl)-1,1,1,2,3,3,3-heptafluoropropane 
((CF3)2CFCF2OC2H5
); methyl acetate; 1,1,1,2,2,3,3-heptafluoro-3-methoxy-propane (n-
C3F7OCH3, HFE-7000); 3-ethoxy- 1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-
(trifluoromethyl) hexane (HFE-7500); 1,1,1,2,3,3,3-heptafluoropropane 
(HFC 227ea); methyl formate (HCOOCH3); 1,1,1,2,2,3,4,5,5,5-decafluoro-
3-methoxy-4-trifluoromethyl-pentane (HFE-7300); propylene carbonate; 
dimethyl carbonate; trans-1,3,3,3-tetrafluoropropene; 
HCF2OCF2H (HFE-134); 
HCF2OCF2OCF2H (HFE-236cal2); 
HCF2OCF2CF2OCF2H (HFE-
338pcc13); 
HCF2OCF2OCF2CF2OCF2
H (H-Galden 1040x or H-Galden ZT 130 (or 150 or 180)); trans 1-chloro-
3,3,3-trifluoroprop-1-ene; 2,3,3,3-tetrafluoropropene; 2-amino-2-
methyl-1-propanol; t-butyl acetate; 1,1,2,2- Tetrafluoro -1-(2,2,2-
trifluoroethoxy) ethane; cis-1,1,1,4,4,4-hexafluorobut-2-ene (HFO-
1336mzz-Z); and perfluorocarbon compounds which fall into these 
classes:
* * * * *
[FR Doc. 2018-25891 Filed 11-27-18; 8:45 am]
 BILLING CODE 6560-50-P



                   Federal Register / Vol. 83, No. 229 / Wednesday, November 28, 2018 / Rules and Regulations                                           61127

     year, the Judges shall adjust the royalty                (x) 2019: 59 cents per subscriber per                and Environmental Impacts Division,
     fee payable under Section 119(b)(1)(B)                  month.                                                Mail Code C539–07, Environmental
     ‘‘to reflect any changes occurring in the                                                                     Protection Agency, Research Triangle
                                                             Suzanne M. Barnett,
     cost of living as determined by the most                                                                      Park, NC 27711; telephone: (919) 541–
     recent Consumer Price Index (for all                    Chief Copyright Royalty Judge.                        4359; fax number: (919) 541–5315;
     consumers and for all items) [CPI–U]                    [FR Doc. 2018–25907 Filed 11–27–18; 8:45 am]          email address: benromdhane.souad@
     published by the Secretary of Labor                     BILLING CODE 1410–72–P                                epa.gov.
     before December 1 of the preceding                                                                            SUPPLEMENTARY INFORMATION:
     year.’’ Section 119 also requires that
     ‘‘[n]otification of the adjusted fees shall             ENVIRONMENTAL PROTECTION                              Table of Contents
     be published in the Federal Register at                 AGENCY                                                I. Does this action apply to me?
     least 25 days before January 1.’’ 17                                                                          II. Background
     U.S.C. 119(c)(2).                                       40 CFR Part 51                                           A. The EPA’s VOC Exemption Policy
                                                             [EPA–HQ–OAR–2017–0175; FRL–9987–02–                      B. Petition To List HFO–1336mzz–Z as an
        The change in the cost of living as
                                                             OAR]                                                        Exempt Compound
     determined by the CPI–U during the                                                                            III. The EPA’s Assessment of the Petition
     period from the most recent index                       RIN 2060–AT52                                            A. Contribution to Tropospheric Ozone
     published before December 1, 2017, to                                                                               Formation
     the most recent index published before                  Air Quality: Revision to the Regulatory                  B. Potential Impacts on Other
     December 1, 2018, is 2.5%.2 Application                 Definition of Volatile Organic                              Environmental Endpoints
     of the 2.5% COLA to the current rate for                Compounds—Exclusion of cis-                              1. Contribution to Stratospheric Ozone
     the secondary transmission of broadcast                 1,1,1,4,4,4-hexafluorobut-2-ene (HFO–                       Depletion
     stations by satellite carriers for private              1336mzz–Z)                                               2. The Significant New Alternatives Policy
                                                                                                                         (SNAP) Program Acceptability Findings
     home viewing—28 cents per subscriber
                                                             AGENCY:  Environmental Protection                        3. Toxicity
     per month—results in a rate of 29 cents                                                                          4. Contribution to Climate Change
                                                             Agency (EPA).
     per subscriber per month (rounded to                                                                             C. Response to Comments and Conclusion
     the nearest cent). See 37 CFR                           ACTION: Final rule.
                                                                                                                   IV. Final Action
     386.2(b)(1). Application of the 2.5%                    SUMMARY:   On May 1, 2018, the U.S.                   V. Statutory and Executive Order Reviews
     COLA to the current rate for viewing in                 Environmental Protection Agency (EPA)                    A. Executive Order 12866: Regulatory
     commercial establishments—58 cents                                                                                  Planning and Review and Executive
                                                             published a proposed rule seeking                           Order 13563: Improving Regulation and
     per subscriber per month—results in a                   comments in response to a petition
     rate of 59 cents per subscriber per                                                                                 Regulatory Review
                                                             requesting the revision of the EPA’s                     B. Executive Order 13771: Reducing
     month (rounded to the nearest cent). See                regulatory definition of volatile organic                   Regulations and Controlling Regulatory
     37 CFR 386.2(b)(2).                                     compounds (VOC) to exempt cis-                              Costs
     List of Subjects in 37 CFR Part 386                     1,1,1,4,4,4-hexafluorobut-2-ene (also                    C. Paperwork Reduction Act (PRA)
                                                             known as HFO–1336mzz–Z; CAS                              D. Regulatory Flexibility Act (RFA)
         Copyright, Satellite, Television.                   number 692–49–9). The EPA is now                         E. Unfunded Mandates Reform Act
                                                                                                                         (UMRA)
     Final Regulations                                       taking final action to revise the
                                                                                                                      F. Executive Order 13132: Federalism
                                                             regulatory definition of VOC under the                   G. Executive Order 13175: Consultation
       In consideration of the foregoing, the                Clean Air Act (CAA). This final action                      and Coordination With Indian Tribal
     Judges amend part 386 of title 37 of the                adds HFO–1336mzz–Z to the list of                           Governments
     Code of Federal Regulations as follows:                 compounds excluded from the                              H. Executive Order 13045: Protection of
                                                             regulatory definition of VOC on the                         Children From Environmental Health
     PART 386—ADJUSTMENT OF                                  basis that this compound makes a                            and Safety Risks
     ROYALTY FEES FOR SECONDARY                              negligible contribution to tropospheric                  I. Executive Order 13211: Actions
     TRANSMISSIONS BY SATELLITE                              ozone (O3) formation.                                       Concerning Regulations That
     CARRIERS                                                                                                            Significantly Affect Energy Supply,
                                                             DATES: This final rule is effective on                      Distribution or Use
                                                             January 28, 2019.                                        J. National Technology Transfer and
     ■ 1. The authority citation for part 386                ADDRESSES: The EPA has established a                        Advancement Act (NTTAA)
     continues to read as follows:                           docket for this action under Docket ID                   K. Executive Order 12898: Federal Actions
         Authority: 17 U.S.C. 119(c), 801(b)(1).             No. EPA–HQ–OAR–2017–0175. All                               To Address Environmental Justice in
                                                             documents in the docket are listed on                       Minority Populations and Low-Income
     ■ 2. Section 386.2 is amended by adding                                                                             Populations
                                                             the https://www.regulations.gov
     paragraphs (b)(1)(x) and (b)(2)(x) to read                                                                       L. Congressional Review Act (CRA)
                                                             website. Although listed in the index,                   M. Judicial Review
     as follows:
                                                             some information is not publicly
     § 386.2 Royalty fee for secondary                       available, e.g., Confidential Business                I. Does this action apply to me?
     transmission by satellite carriers.                     Information or other information whose                   Entities potentially affected by this
     *    *    *     *    *                                  disclosure is restricted by statute.                  final rule include, but are not
                                                             Certain other material, such as                       necessarily limited to, the following:
      (b) * * *
                                                             copyrighted materials, is not placed on               State and local air pollution control
      (1) * * *                                              the internet and will be publicly                     agencies that adopt and implement
      (x) 2019: 29 cents per subscriber per                  available only in hard copy form.                     regulations to control air emissions of
     month.                                                  Publicly available docket materials are               VOC; and industries manufacturing
                                                             available electronically through https://             and/or using HFO–1336mzz–Z for use
      (2) * * *
                                                             www.regulations.gov.                                  in polyurethane rigid insulating foams,
       2 On November 14, 2018, the Bureau of Labor           FOR FURTHER INFORMATION CONTACT: Dr.                  refrigeration, and air conditioning.
     Statistics announced that the CPI–U increased 2.5%      Souad Benromdhane, Office of Air                      Potential entities that may be affected by
     over the last 12 months.                                Quality Planning and Standards, Health                this action include:


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     61128             Federal Register / Vol. 83, No. 229 / Wednesday, November 28, 2018 / Rules and Regulations

       TABLE 1—POTENTIALLY AFFECTED ENTITIES BY NORTH AMERICAN INDUSTRIAL CLASSIFICATION SYSTEM (NAICS) CODE
                             Category                                      NAICS code                                      Description of regulated entities

     Industry .....................................................              326140     Polystyrene Foam Product Manufacturing.
     Industry .....................................................              326150     Urethane and Other Foam Product (except Polystyrene) Manufacturing.
     Industry .....................................................              333415     Air-Conditioning and Warm Air Heating Equipment and Commercial and Industrial
                                                                                               Refrigeration Equipment Manufacturing.
     Industry     .....................................................            3363     Motor Vehicle Parts Manufacturing.
     Industry     .....................................................          336611     Ship Building and Repairing.
     Industry     .....................................................          336612     Boat Building.
     Industry     .....................................................          339999     All other Miscellaneous Manufacturing.



        This table is not intended to be                                       has the authority to define the meaning                very fast rate. The kOH values have long
     exhaustive, but rather provides a guide                                   of ‘‘VOC’’ and, hence, what compounds                  been used by the EPA as metrics of
     for readers regarding entities that might                                 shall be treated as VOC for regulatory                 photochemical reactivity and O3-
     be affected by this deregulatory action.                                  purposes. The policy of excluding                      forming activity, and they were the basis
     This table lists the types of entities that                               negligibly reactive compounds from the                 for most of the EPA’s early exemptions
     the EPA is now aware of that could                                        regulatory definition of VOC was first                 of negligibly reactive compounds from
     potentially be affected to some extent by                                 laid out in the ‘‘Recommended Policy                   the regulatory definition of VOC. The
     this action. Other types of entities not                                  on Control of Volatile Organic                         kOH metric is inherently a molar-based
     listed in the table could also be affected                                Compounds’’ (42 FR 35314, July 8,                      comparison, i.e., it measures the rate at
     to some extent. To determine whether                                      1977) (from here forward referred to as                which molecules react.
     your entity is directly or indirectly                                     the 1977 Recommended Policy) and was                      The MIR, both by mole and by mass,
     affected by this action, you should                                       supplemented subsequently with the                     is a more updated metric of
     consult your state or local air pollution                                 ‘‘Interim Guidance on Control of                       photochemical reactivity derived from a
     control and/or air quality management                                     Volatile Organic Compounds in Ozone                    computer-based photochemical model,
     agencies.                                                                 State Implementation Plans’’ (70 FR                    and it has been used as a metric of
                                                                               54046, September 13, 2005) (from here                  reactivity since 1995. This metric
     II. Background
                                                                               forward referred to as the 2005 Interim                considers the complete O3-forming
     A. The EPA’s VOC Exemption Policy                                         Guidance). The EPA uses the reactivity                 activity of a compound over multiple
        Tropospheric O3, commonly known                                        of ethane as the threshold for                         hours and through multiple reaction
     as smog, is formed when VOC and                                           determining whether a compound has                     pathways, not merely the first reaction
     nitrogen oxides (NOX) react in the                                        negligible reactivity. Compounds that                  step with OH. Further explanation of
     atmosphere in the presence of sunlight.                                   are less reactive than, or equally reactive            the MIR metric can be found in Carter
     Because of the harmful health effects of                                  to, ethane under certain assumed                       (1994).
     O3, the EPA and state governments limit                                   conditions may be deemed negligibly                       The EPA has considered the choice
     the amount of VOC that can be released                                    reactive and, therefore, suitable for                  between MIRs with a molar or mass
     into the atmosphere. VOC form O3                                          exemption from the regulatory                          basis for the comparison to ethane in
     through atmospheric photochemical                                         definition of VOC. Compounds that are                  past rulemakings and guidance. In the
     reactions, and different VOC have                                         more reactive than ethane continue to                  2005 Interim Guidance, the EPA stated:
     different levels of reactivity. That is,                                  be considered VOC for regulatory                          [A] comparison to ethane on a mass basis
     different VOC do not react to form O3                                     purposes and, therefore, are subject to                strikes the right balance between a threshold
     at the same speed or do not form O3 to                                    control requirements. The selection of                 that is low enough to capture compounds
     the same extent. Some VOC react slowly                                    ethane as the threshold compound was                   that significantly affect ozone concentrations
                                                                               based on a series of smog chamber                      and a threshold that is high enough to
     or form less O3; therefore, changes in
                                                                                                                                      exempt some compounds that may usefully
     their emissions have limited effects on                                   experiments that underlay the 1977                     substitute for more highly reactive
     local or regional O3 pollution episodes.                                  Recommended Policy.                                    compounds.
     It has been the EPA’s policy since 1971,                                     The EPA has used three different                       When reviewing compounds that have
     that certain organic compounds with a                                     metrics to compare the reactivity of a                 been suggested for VOC-exempt status, EPA
     negligible level of reactivity should be                                  specific compound to that of ethane: (i)               will continue to compare them to ethane
     excluded from the regulatory definition                                   The rate constant for reaction with the                using kOH expressed on a molar basis and
     of VOC in order to focus VOC control                                      hydroxyl radical (OH) (known as kOH);                  MIR values expressed on a mass basis.
     efforts on compounds that significantly                                   (ii) the maximum incremental reactivity                  The 2005 Interim Guidance notes that
     affect O3 concentrations. The EPA also                                    (MIR) on a reactivity per unit mass                    the EPA will consider a compound to be
     believes that exempting such                                              basis; and (iii) the MIR expressed on a                negligibly reactive if it is equally as or
     compounds creates an incentive for                                        reactivity per mole basis. Differences                 less reactive than ethane based on either
     industry to use negligibly reactive                                       between these three metrics are                        kOH expressed on a molar basis or MIR
     compounds in place of more highly                                         discussed below.                                       values expressed on a mass basis.
     reactive compounds that are regulated                                        The kOH is the rate constant of the                   The molar comparison of MIR is more
     as VOC. The EPA lists compounds that                                      reaction of the compound with the OH                   consistent with the original smog
     it has determined to be negligibly                                        radical in the air. This reaction is often,            chamber experiments, which compared
     reactive in its regulations as being                                      but not always, the first and rate-                    equal molar concentrations of
     excluded from the regulatory definition                                   limiting step in a series of chemical                  individual VOCs, supporting the
     of VOC (40 CFR 51.100(s)).                                                reactions by which a compound breaks                   selection of ethane as the threshold,
        The CAA requires the regulation of                                     down in the air and contributes to O3                  while the mass-based comparison of
     VOC for various purposes. Section                                         formation. If this step is slow, the                   MIR is consistent with how MIR values
     302(s) of the CAA specifies that the EPA                                  compound will likely not form O3 at a                  and other reactivity metrics are applied


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                  Federal Register / Vol. 83, No. 229 / Wednesday, November 28, 2018 / Rules and Regulations                                          61129

     in reactivity-based emission limits. It is,             that cis-1,1,1,4,4,4-hexafluorobut-2-ene                 To address the potential for
     however, important to note that the                     (HFO–1336mzz–Z; CAS number 692–                       stratospheric O3 impacts, the petitioner
     mass-based comparison is slightly less                  49–9) be exempted from the regulatory                 contended that, because the
     restrictive than the molar-based                        definition of VOC. The petition was                   atmospheric lifetime of HFO–1336mzz–
     comparison in that a few more                           based on the argument that HFO–                       Z due to loss by OH reaction was
     compounds would qualify as negligibly                   1336mzz–Z has low reactivity relative to              estimated to be ∼20 days and it does not
     reactive.                                               ethane. The petitioner indicated that                 contain chlorine or bromine, it is not
        Given the two goals of the exemption                 HFO–1336mzz–Z may be used in a                        expected to contribute to the depletion
     policy articulated in the 2005 Interim                  variety of applications as a replacement              of the stratospheric O3 layer.
     Guidance, the EPA believes that ethane                  for foam expansion or blowing agents
     continues to be an appropriate threshold                with higher global warming potential                  III. The EPA’s Assessment of the
     for defining negligible reactivity. And,                (GWP) (≤700 GWP) for use in                           Petition
     to encourage the use of environmentally                 polyurethane rigid insulating foams,
                                                             among others. It is also a new                           On May 1, 2018, the EPA published
     beneficial substitutions, the EPA
     believes that a comparison to ethane on                 developmental refrigerant as a potential              a proposed rulemaking (83 FR 19026)
     a mass basis strikes the right balance                  working fluid for Organic Rankine                     seeking comments in response to the
     between a threshold that is low enough                  Cycles (ORC).1                                        petition to revise the EPA’s regulatory
     to capture compounds that significantly                    To support its petition, DuPont                    definition of VOC for exemption of
     affect O3 concentrations and a threshold                referenced several documents, including               HFO–1336mzz–Z. The EPA is taking
     that is high enough to exempt some                      one peer-reviewed journal article on                  final action to respond to the petition by
     compounds that may usefully substitute                  HFO–1336mzz–Z reaction rates                          exempting HFO–1336mzz–Z from the
     for more highly reactive compounds.                     (Baasandorj, M. et al., 2011). DuPont                 regulatory definition of VOC. This
        The 2005 Interim Guidance also noted                 also provided a supplemental technical                action is based on consideration of the
     that concerns have sometimes been                       report on the MIR of HFO–1336mzz–Z                    compound’s low contribution to
     raised about the potential impact of a                  (Carter, 2011a). Per this report, the MIR             tropospheric O3 and the low likelihood
     VOC exemption on environmental                          of HFO–1336mzz–Z is 0.04 gram (g) O3/                 of risk to human health or the
     endpoints other than O3 concentrations,                 g HFO–1336mzz–Z on the mass-based                     environment, including stratospheric O3
     including fine particle formation, air                  MIR scale. This reactivity rate is 86                 depletion, toxicity, and climate change.
     toxics exposures, stratospheric O3                      percent lower than that of ethane (0.28               Additional information on these topics
     depletion, and climate change. The EPA                  g O3/g ethane). The reactivity rate kOH               is provided in the following sections.
     has recognized, however, that there are                 for the gas-phase reaction of OH radicals
                                                             with HFO–1336mzz–Z (kOH) has been                     A. Contribution to Tropospheric Ozone
     existing regulatory or non-regulatory                                                                         Formation
     programs that are specifically designed                 measured to be 4.91 × 10¥13 centimeter
     to address these issues, and the EPA                    (cm)3/molecule-seconds at ∼296 degrees                  As noted in studies cited by the
     continues to believe in general that the                Kelvin (K) (Pitts et al., 1983, Baasandorj            petitioner, HFO–1336mzz–Z has a MIR
     impacts of VOC exemptions on                            et al., 2011). This kOH rate is twice as              value of 0.04 g O3/g VOC for ‘‘averaged
     environmental endpoints other than O3                   high as that of ethane (kOH of ethane =               conditions,’’ versus 0.28 g O3/g VOC for
     formation can be adequately addressed                   2.4 × 10¥13 cm3/molecule-sec at ∼298 K)               ethane (Carter, 2011). Therefore, the
     by these programs. The VOC exemption                    and, therefore, suggests that HFO–                    EPA considers HFO–1336mzz–Z to be
     policy is intended to facilitate                        1336mzz–Z is twice as reactive as
                                                                                                                   negligibly reactive and eligible for VOC-
     attainment of the O3 National Ambient                   ethane. In most cases, chemicals with
                                                                                                                   exempt status in accordance with the
     Air Quality Standards (NAAQS) and                       high kOH values also have high MIR
                                                                                                                   Agency’s long-standing policy that
     VOC exemption decisions will continue                   values, but for HFO–1336mzz–Z, the
                                                                                                                   compounds should so qualify where
     to be based primarily on consideration                  products that are formed in subsequent
                                                             reactions are expected to be poly                     either reactivity metric (kOH expressed
     of a compound’s contribution to O3                                                                            on a molar basis or MIR expressed on
     formation. However, if the EPA                          fluorinated compounds, which do not
                                                             contribute to O3 formation (Baasandorj                a mass basis) indicates that the
     determines that a particular VOC                                                                              compound is less reactive than ethane.
     exemption is likely to result in a                      et al., 2011). Based on the current
                                                             scientific understanding of                           While the overall atmospheric reactivity
     significant increase in the use of a                                                                          of HFO–1336mzz–Z was not studied in
     compound and that the increased use                     tetrafluoroalkene reactions in the
                                                             atmosphere, it is unlikely that the actual            an experimental smog chamber, the
     would pose a significant risk to human                                                                        chemical mechanism derived from other
                                                             O3 impact on a mass basis would equal
     health or the environment that would                                                                          chamber studies (Carter, 2011) was used
                                                             or exceed that of ethane in the scenarios
     not be addressed adequately by existing                                                                       to model the complete formation of O3
                                                             used to calculate VOC reactivity
     programs or policies, then the EPA may                                                                        for an entire single day under realistic
                                                             (Baasandorj et al., 2011; Carter, 2011a).
     exercise its judgment accordingly in                                                                          atmospheric conditions (Carter, 2011a).
     deciding whether to grant an exemption.                   1 Konstantinos Kontomaris, 2014, HFO–1336mzz–       Therefore, the EPA believes that the
     B. Petition To List HFO–1336mzz–Z as                    Z High Temperature Chemical Stability and Use as      MIR value calculated in the Carter study
                                                             a Working Fluid in Organic Rankine Cycles.
     an Exempt Compound                                      International Refrigeration and Air Conditioning
                                                                                                                   submitted by the petitioner is reliable.
       DuPont Chemicals & Fluoroproducts                     Conference. Purdue University: https://                  Table 2 presents three reactivity
                                                             www.chemours.com/Refrigerants/en_US/products/
     (DuPont) submitted a petition to the                    Opteon/Stationary_Refrigeration/assets/downloads/
                                                                                                                   metrics for HFO–1336mzz–Z as they
     EPA on February 14, 2014, requesting                    2014_Purdue-Paper-Opteon-MZ.pdf.                      compare to ethane.




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     61130              Federal Register / Vol. 83, No. 229 / Wednesday, November 28, 2018 / Rules and Regulations

                                                              TABLE 2—REACTIVITIES OF ETHANE AND HFO–1336MZZ–Z
                                                                                                                                                                            Maximum in-      Maximum in-
                                                                                                                                                              kOH           cremental re-    cremental re-
                                                                    Compound                                                                             (cm3/molecule-     activity (MIR)   activity (MIR)
                                                                                                                                                              sec)           (g O3/mole      (g O3/g VOC)
                                                                                                                                                                                VOC)

     Ethane ..........................................................................................................................................     2.4 × 10¥13                 8.4             0.28
     HFO–1336mzz–Z .........................................................................................................................              4.91 × 10¥13                 6.6             0.04
       Notes:
       1. k
           OH value at 298 K for ethane is from Atkinson et al., 2006 (page 3626).
       2. k
           OH value at 296 K for HFO–1336mzz–Z is from Baasandorj, 2011.
       3. Mass-based MIR value (g O /g VOC) of ethane is from Carter, 2011.
                                      3
       4. Mass-based MIR value (g O /g VOC) of HFO–1336mzz–Z is from a supplemental report by Carter, 2011a.
                                      3
       5. Molar-based MIR (g O /mole VOC) values were calculated from the mass-based MIR (g O /g VOC) values using the number of moles per
                                 3                                                            3
     gram of the relevant organic compound.


        The reaction rate of HFO–1336mzz–Z                                       environment, with regard to                                               3. Toxicity
     with the OH radical (kOH) has been                                          stratospheric O3 depletion, toxicity and
     measured to be 4.91 × 10¥13 cm3/                                            climate change. Additional information                                       Based on screening assessments of the
     molecule-sec (Baasandorj et al., 2011);                                                                                                               health and environmental risks of HFO–
                                                                                 on these topics is provided in the
     other reactions with O3 and the nitrate                                                                                                               1336mzz–Z, the SNAP program
                                                                                 following sections.
     radical were negligibly small. The                                                                                                                    anticipated that users will be able to use
     corresponding reaction rate of ethane                                       1. Contribution to Stratospheric Ozone                                    the compound without significantly
     with OH is 2.4 × 10¥13cm3/molecule-sec                                      Depletion                                                                 greater health risks than presented by
     (Atkinson et al., 2006). The data in                                                                                                                  use of other available substitutes for the
     Table 2 show that HFO–1336mzz–Z has                                            HFO–1336mzz–Z is unlikely to                                           same uses (USEPA, 2014, 2016).
     a higher kOH value than ethane, meaning                                     contribute to the depletion of the                                           The EPA anticipates that HFO–
     that it initially reacts twice as fast in the                               stratospheric O3 layer. The O3 depletion                                  1336mzz–Z will be used consistent with
     atmosphere as ethane. However, the                                          potential (ODP) of HFO–1336mzz–Z is                                       the recommendations specified in the
     resulting unsaturated fluorinated                                           expected to be negligible based on                                        material safety data sheet (SDS)
     compounds in the atmosphere are short                                       several lines of evidence: The absence of                                 (DuPont, 2011). According to the SDS,
     lived and react more slowly to form O3                                      chlorine or bromine in the compound                                       potential health effects from inhalation
     (Baasandorj et al., 2011). The mass                                         and the atmospheric reactions described                                   of HFO–1336mzz–Z include skin or eye
     based MIR is 0.04 g O3/g VOC and much                                       in Carter (2008). Because HFO–                                            irritation or frostbite. Exposure to high
     lower than that of ethane.                                                  1336mzz–Z has a kOH value that is twice                                   concentrations of HFO–1336mzz–Z
        A molecule of HFO–1336mzz–Z is                                           as high as that of ethane (see section                                    from misuse or intentional inhalation
     less reactive than a molecule of ethane                                     III.A ‘‘Contribution to Tropospheric                                      abuse may cause irregular heartbeat. In
     in terms of complete O3-forming activity                                    Ozone Formation’’), it will decay before                                  addition, HFO–1336mzz–Z could cause
     as shown by the molar-based MIR (g O3/                                      it has a chance to reach the stratosphere                                 asphyxiation if air is displaced by
     mole VOC) values. One gram of HFO–                                          and, thus, will not participate in O3                                     vapors in a confined space. The
     1336mzz–Z has a lower capacity than                                         destruction.                                                              Workplace Environmental Exposure
     one gram of ethane to form O3 in terms                                                                                                                Limit (WEEL) committee of the
     of a mass-based MIR. Thus, following                                        2. The Significant New Alternatives                                       Occupational Alliance for Risk Science
     the 2005 Interim Guidance in striking a                                     Policy (SNAP) Program Acceptability                                       (OARS) reviewed available animal
     balance between reactivity on a molar                                       Findings                                                                  toxicity data and recommends a WEEL
     basis as well as a gram basis, the EPA                                                                                                                for the workplace of 500 parts per
     finds HFO–1336mzz–Z to be eligible for                                         The SNAP program is the EPA’s                                          million (ppm) (3350 mg/m3) time-
     exemption from the regulatory                                               program to evaluate and regulate                                          weighted average (TWA) for an 8-hour
     definition of VOC based on both the                                         substitutes for end-uses historically                                     workday as provided in the OARS
     molar- and mass-based MIR.                                                  using O3-depleting chemicals. Under                                       (OARS, 2014).2 This WEEL was derived
     B. Potential Impacts on Other                                               section 612(c) of the CAA, the EPA is                                     based on reduced male body weight in
     Environmental Endpoints                                                     required to identify and publish lists of                                 the 13-week rat inhalation toxicity study
                                                                                 acceptable and unacceptable substitutes                                   (Dupont, 2011). The WEEL is also
        The EPA’s decision to exempt HFO–                                        for class I or class II O3-depleting                                      protective against skeletal fluorosis,
     1336mzz–Z from the regulatory                                               substances. Per the SNAP program                                          which may occur at higher exposures
     definition of VOC is based on our
                                                                                 findings, the ODP of HFO–1336mzz–Z                                        because of metabolism. The EPA
     findings above. However, as noted in
                                                                                 is zero. The SNAP program has listed                                      anticipates that users will be able to
     the 2005 Interim Guidance, the EPA
                                                                                 HFO–1336mzz–Z as an acceptable                                            meet the WEEL and address potential
     reserves the right to exercise its
                                                                                 substitute for a number of foam blowing                                   health risks by following requirements
     judgment in certain cases where an
                                                                                 end-uses provided in 79 FR 62863,                                         and recommendations in the SDS and
     exemption is likely to result in a
                                                                                 October 21, 2014 (USEPA, 2014), and as                                    other safety precautions common to the
     significant increase in the use of a
                                                                                 an acceptable substitute in the                                           refrigeration and air conditioning
     compound and a subsequent
                                                                                 refrigeration and air conditioning sector                                 industry.
     significantly increased risk to human
     health or the environment. In this case,                                    in heat transfer, as well as in chillers
                                                                                                                                                            2 Occupational Alliance for Risk Science (OARS–
     the EPA does not find that exemption of                                     and industrial process air conditioning
                                                                                                                                                           WEELs)—HFO–1336mzz–Z, 2014: https://
     HFO–1336mzz–Z would result in an                                            provided in 81 FR 32241, May 23, 2016                                     www.tera.org/OARS/HFO-1336mzz-
     increase of risk to human health or the                                     (USEPA, 2016).                                                            Z%20WEEL%20FINAL.pdf.



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                  Federal Register / Vol. 83, No. 229 / Wednesday, November 28, 2018 / Rules and Regulations                                         61131

        HFO–1336mzz–Z is not regulated as a                  100-year period, one ton of HFO–                         Response: The commenter appears to
     hazardous air pollutant (HAP) under                     1336mzz–Z traps 9 times as much                       state that HFO–1336mzz–Z should not
     title I of the CAA. Also, it is not listed              warming energy as one ton of carbon                   be exempted from the definition of VOC
     as a toxic chemical under section 313 of                dioxide (CO2) (IPCC, 2013). HFO–                      simply because it is currently included
     the Emergency Planning and                              1336mzz–Z’s GWP of 9 is lower than                    in the definition of VOC. This is a
     Community Right-to-Know Act                             those of some of the substitutes in a                 circular argument, and, if followed, the
     (EPCRA).                                                variety of foam blowing end-uses and in               EPA would never be able to exempt any
        The Toxic Substances Control Act                     centrifugal and positive displacement                 substances from the definition of VOC,
     (TSCA) gives the EPA authority to                       chillers, heat transfer, and industrial               even where, as here, scientific data
     assess and prevent potential                            process air conditioning. HFO–                        supported such an exemption. The
     unreasonable risks to human health and                  1336mzz–Z was developed to replace                    commenter does not provide any
     the environment before a new chemical                   other chemicals used for similar end-                 scientific evidence that rebuts the
     substance is introduced into commerce.                  uses with GWP ranging from 725 to                     petitioner’s data supporting the
     Section 5 of TSCA requires                              5,750 such as CFC–11, CFC–113, HCFC–                  demonstration that HFO–1336mzz–Z is
     manufacturers and importers to notify                   141b and HCFC–22. The petitioner                      eligible for this exemption.
     the EPA before manufacturing or                         claims that HFO–1336mzz–Z is a better                    The reason HFO–1336mzz–Z is
     importing a new chemical substance by                   alternative to other substitutes in foam              currently regulated as a VOC is because
     submitting a Premanufacture Notice                      expansion or blowing agents for use in                it meets the EPA’s definition of VOC in
     (PMN) prior to the manufacture                          polyurethane rigid insulating foams.                  40 CFR 51.100(s) as ‘‘any compound of
     (including import) of the chemical.                     Thermal test data and energy efficiency               carbon, excluding carbon monoxide,
     Under the TSCA New Chemicals                            trials indicate that HFO–1336mzz–Z                    carbon dioxide, carbonic acid . . .
     Program, the EPA then assesses whether                  will provide superior insulating value                which participates in atmospheric
     an unreasonable risk may, or will, be                   and, thus, reduces climate change                     photochemical reactions.’’ [emphasis
     presented by the expected                               impacts both directly by its relatively               added] The petitioner submitted data to
     manufacturing, processing, distribution                 low GWP and indirectly by decreasing                  the EPA that show HFO–1336mzz–Z
     in commerce, use, and disposal of the                   energy consumption throughout the                     negligibly participates in atmospheric
     new substance. The EPA has                              lifecycle of insulated foams in                       photochemical reactions, presenting a
     determined, however, that domestic                      appliances, buildings, refrigerated                   better environmental alternative for
     manufacturing, use in non-industrial                    storage and transportation.                           similar industrial applications, and
     products, or use other than as described
                                                             C. Response to Comments and                           therefore should be excluded from the
     in the PMN may cause serious chronic
                                                             Conclusion                                            definition of VOC. As explained above,
     health effects. To mitigate risks
                                                                The EPA received five comments on                  our approval would allow states to
     identified during the PMN review of
                                                             the May 1, 2018, notice of proposed                   encourage VOC substitutions with
     HFO–1336mzz–Z, the EPA issued a
                                                             rulemaking. One commenter supported                   negligibly reactive compounds that
     Significant New Use Rule (SNUR) under
                                                             the proposed action to exempt HFO–                    would reduce O3 formation.
     TSCA on June 5, 2015, to require
     persons to submit a Significant New Use                 1336mzz–Z from the EPA’s definition of                   The EPA would like to clarify the
     Notice (SNUN) to the EPA at least 90                    VOC in 40 CFR 51.100(s), one opposed                  statement in the proposal which
     days before they manufacture or process                 the proposed action, and three raised                 referred to ‘‘existing regulatory or non-
     HFO–1336mzz–Z for uses other than                       issues that were outside the scope of                 regulatory programs that are specifically
     those described in the PMN (80 FR                       this rulemaking including a discussion                designed to address’’ other
     32003, 32005, June 5, 2015). The                        about air and water quality in Asia and               environmental issues besides
     required notification will provide the                  Mexico, and climate change. These                     tropospheric O3 formation, such as fine
     EPA with the opportunity to evaluate                    three anonymous comments failed to                    particle formation, air toxics exposures,
     the intended use and, if necessary, to                  identify any specific issue that is                   stratospheric O3 depletion, and climate
     prohibit or limit that activity before it               germane to our proposal to exempt                     change. When referring to existing
     occurs. The EPA, therefore, believes that               HFO–1336mzz–Z. Substantial                            regulatory or non-regulatory programs,
     existing programs address the risk of                   comments and the EPA’s responses are                  the EPA was not referring to ‘‘other
     toxicity associated with the use of HFO–                provided below.                                       regulatory groups outside of the EPA,’’
     1336mzz–Z.                                                 Comment: One commenter (ID: EPA–                   as the commenter suggested. Rather,
                                                             HQ–OAR–2017–0175–0010) expressed                      Congress has granted the EPA with
     4. Contribution to Climate Change                       concern that ‘‘the EPA should not                     other authorities under the CAA that
        The Intergovernmental Panel on                       exempt HFO–1336mzz–Z . . . [and that]                 allow the Agency to address these issues
     Climate Change (IPCC) Fifth Assessment                  . . . surely there is a reason it was . . .           specifically (e.g., NAAQS program for
     Report (IPCC AR5) estimated the                         [regulated as a VOC] in the first place.’’            fine particle pollution; section 112 for
     lifetime of HFO–1336mzz–Z to be                         The commenter expressed skepticism                    air toxics). As stated in the 2005 Interim
     approximately 22 days (Baasandorj et                    that ‘‘other regulatory groups outside of             Guidance, where an exemption is likely
     al., 2011), and the gas-phase                           the EPA’’ would prevent the compound                  to result in a significant increase in the
     degradation of HFO–1336–mzz–Z is not                    from being used, if there were other                  use of a compound and a subsequent
     expected to lead to a significant                       environmental impacts than O3, once                   significantly increased risk to human
     formation of atmospherically long-lived                 the EPA exempted this compound. This                  health or the environment, the EPA
     species. The radiative efficiency of                    commenter also expressed concern that                 reserves the right to exercise its
     HFO–1336–mzz–Z was calculated to be                     the petitioner’s data ‘‘could potentially             judgment and choose not to grant a
     0.38 watts per square meter at the                      be biased’’ and they ‘‘. . . would like to            petition for an exemption from the
     earth’s surface per part per billion                    read a proposal that gets its information             definition of VOC, even where the
     concentration of the material (W m¥2                    from a more unbiased source and                       substance meets the reactivity metrics.
     ppb¥1) based on Baasandorj et al., 2011.                considers how it will deal with possible              However, as explained in section III.B.
     The report estimated the resulting 100-                 drawbacks of deregulating HFO–                        of this final rule, the EPA does not
     year GWP to be 9, meaning that, over a                  1336mzz–Z.’’                                          believe an exemption of HFO–1336mzz–


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     61132        Federal Register / Vol. 83, No. 229 / Wednesday, November 28, 2018 / Rules and Regulations

     Z will lead to significant environmental                The EPA has concluded that non-                       A. Executive Order 12866: Regulatory
     impacts.                                                tropospheric O3-related risks associated              Planning and Review and Executive
        To the extent the commenter is raising               with potential increased use of HFO–                  Order 13563: Improving Regulation and
     concerns that the EPA’s action will                     1336mzz–Z are adequately managed by                   Regulatory Review
     result in non-EPA organizations treating                SNAP. The EPA does not expect
     HFO–1336mzz–Z differently, we note                      significant use of HFO–1336mzz–Z in                     This action is not a significant
     that this action does not prohibit state                applications not covered by the SNAP                  regulatory action and was, therefore, not
     and local air pollution regulatory                      program. To the extent that the                       submitted to the Office of Management
     agencies from regulating HFO–                           compound is used in other applications                and Budget (OMB) for review.
     1336mzz–Z. Some local agencies                          not already reviewed under SNAP or
     continue restrictions on the use of                                                                           B. Executive Order 13771: Reducing
                                                             under the New Chemicals Program
     certain compounds that have been                        under TSCA, the SNUR in place under                   Regulations and Controlling Regulatory
     excluded from the definition of VOC by                  TSCA requires that any significant new                Costs
     the EPA.                                                use of a chemical be reported to the EPA                 This action is considered an
        With respect to the comment that the                 using a SNUN. Any significant new use                 Executive Order 13771 deregulatory
     petitioner’s data could potentially be                  of HFO–1336mzz–Z would, thus, need                    action. This final rule provides
     biased, the EPA uses credible, peer-                    to be evaluated by the EPA, and the EPA
     reviewed information in its review of                                                                         meaningful burden reduction by
                                                             will continually review the availability              exempting HFO–1336mzz–Z from the
     VOC exemption petitions. In this regard,                of acceptable substitute chemicals under
     and as discussed in our proposed rule                                                                         VOC regulatory definition and relieving
                                                             the SNAP program.
     and in this action, we note that the                                                                          manufacturers, distributers, and users
     journal article submitted by DuPont on                  IV. Final Action                                      from recordkeeping or reporting
     HFO–1336mzz–Z reaction rates was                           The EPA is responding to the petition              requirements. This action is voluntary
     performed by the National Oceanic and                   by revising its regulatory definition of              in nature and has non-quantifiable cost
     Atmospheric Administration and                          VOC at 40 CFR 51.100(s) to add HFO–                   savings given the unpredictability in
     published in The Journal of Physical                    1336mzz–Z to the list of compounds                    who or how much of it will be used.
     Chemistry, a peer-reviewed journal. The                 that are exempt from the regulatory                   C. Paperwork Reduction Act (PRA)
     other primary document relied on to                     definition of VOC because it is less
     support the exemption petition was                      reactive than ethane based on a                         This action does not impose an
     authored by the researcher who                          comparison of mass-based MIR and                      information collection burden under the
     developed the MIR scale (Carter, 2011a).                molar-based MIR metrics and is,                       PRA. It does not contain any
     Staff in the EPA’s Office of Research and               therefore, considered negligibly                      recordkeeping or reporting
     Development reviewed these documents                    reactive. As a result of this action, if an           requirements.
     as part of the petition assessment                      entity which uses or produces this
     process and find that they are consistent               compound and is subject to the EPA                    D. Regulatory Flexibility Act (RFA)
     with current understanding of                           regulations limiting the use of VOC in
     atmospheric chemistry. We are not                       a product, limiting the VOC emissions                    I certify that this action will not have
     aware of information that would                         from a facility, or otherwise controlling             a significant economic impact on a
     indicate they are biased.                               the use of VOC for purposes related to                substantial number of small entities
        Therefore, for reasons discussed                     attaining the O3 NAAQS, this                          under the RFA. This action will not
     above, the EPA is finalizing this rule                  compound will not be counted as a VOC                 impose any requirements on small
     with no changes. The EPA finds that                     in determining whether these regulatory               entities. This action removes HFO–
     HFO–1336mzz–Z is negligibly reactive                    obligations have been met. This action                1336mzz–Z from the regulatory
     with respect to its contribution to                     would affect whether this compound is                 definition of VOC and, thereby, relieves
     tropospheric O3 formation and, thus,                    considered a VOC for state regulatory                 manufacturers, distributers, and users of
     may be exempted from the EPA’s                          purposes to reduce O3 formation, if a                 the compound from tropospheric O3
     definition of VOC in 40 CFR 51.100(s).                  state relies on the EPA’s regulatory                  requirements to control emissions of the
     HFO–1336mzz–Z has been listed as                        definition of VOC. States are not                     compound.
     acceptable for use in several industrial                obligated to exclude from control as a
     and commercial refrigeration and air                                                                          E. Unfunded Mandates Reform Act
                                                             VOC those compounds that the EPA has
     conditioning end-uses, as well as for use                                                                     (UMRA)
                                                             found to be negligibly reactive.
     as a blowing agent under the SNAP                       However, no state may take credit for                    This action does not contain any
     program (USEPA, 2014, 2016). The EPA                    controlling this compound in its O3                   unfunded mandate as described in
     has also determined that exemption of                   control strategy. Consequently,                       UMRA, 2 U.S.C. 1531–1538, and does
     HFO–1336mzz–Z from the regulatory                       reductions in emissions for this                      not significantly or uniquely affect small
     definition of VOC will not result in an                 compound will not be considered or                    governments. This action imposes no
     increase of risk to human health and the                counted in determining whether states                 enforceable duty on any state, local or
     environment, and, to the extent that use                have met the rate of progress                         tribal governments, or the private sector.
     of this compound does have impacts on                   requirements for VOC in State
     other environmental endpoints, those                    Implementation Plans or in                            F. Executive Order 13132: Federalism
     impacts are adequately managed by                       demonstrating attainment of the O3
     existing programs. For example, HFO–                    NAAQS.                                                  This action does not have federalism
     1336mzz–Z has a similar or lower                                                                              implications. It will not have substantial
     stratospheric O3 depletion potential                    V. Statutory and Executive Order                      direct effects on the states, on the
     than available substitutes in those end-                Reviews                                               relationship between the national
     uses, and the toxicity risk from using                    Additional information about these                  government and the states, or on the
     HFO–1336mzz–Z is not significantly                      statutes and Executive Orders can be                  distribution of power and
     greater than the risk from using other                  found at https://www2.epa.gov/laws-                   responsibilities among the various
     available alternatives for the same uses.               regulations/laws-and-executive-orders.                levels of government.


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                  Federal Register / Vol. 83, No. 229 / Wednesday, November 28, 2018 / Rules and Regulations                                             61133

     G. Executive Order 13175: Consultation                  L. Congressional Review Act (CRA)                     DuPont Haskell. FEA–1100: 90-day
     and Coordination With Indian Tribal                                                                                inhalation toxicity study in rats;
                                                                This action is subject to the CRA, and                  Unpublished Report DuPont–17453–
     Governments                                             the EPA will submit a rule report to                       785–1; Haskell Laboratory of Industrial
        This action does not have tribal                     each House of the Congress and to the                      Toxicology: Newark, DE, 2011.
     implications, as specified in Executive                 Comptroller General of the United                     IPCC, 2007: Climate Change 2007: The
     Order 13175. This final rule removes                    States. This action is not a ‘‘major rule’’                Physical Science Basis. Contribution of
     HFO–1336mzz–Z from the regulatory                       as defined by 5 U.S.C. 804(2).                             Working Group I to the Fourth
     definition of VOC and, thereby, relieves                                                                           Assessment Report of the
                                                             M. Judicial Review                                         Intergovernmental Panel on Climate
     manufacturers, distributers and users
     from tropospheric O3 requirements to                       Under section 307(b)(1) of the CAA,                     Change [Solomon, S., D. Qin, M.
                                                             petitions for judicial review of this                      Manning, Z. Chen, M. Marquis, K.B.
     control emissions of the compound.
                                                                                                                        Averyt, M. Tignor and H.L. Miller (eds.)].
     Thus, Executive Order 13175 does not                    action must be filed in the United States
                                                                                                                        Cambridge University Press, Cambridge,
     apply to this action.                                   Court of Appeals for the District of                       United Kingdom and New York, NY,
                                                             Columbia Circuit Court within 60 days                      USA, 996 pp.
     H. Executive Order 13045: Protection of                 from the date the final action is
     Children From Environmental Health                                                                            IPCC, 2013: Climate Change 2013: The
                                                             published in the Federal Register.                         Physical Science Basis. Contribution of
     and Safety Risks                                        Filing a petition for review by the                        Working Group I to the Fifth Assessment
        This action is not subject to Executive              Administrator of this final action does                    Report of the Intergovernmental Panel on
     Order 13045, because it is not                          not affect the finality of this action for                 Climate Change [Stocker, T.F., D. Qin,
     economically significant as defined in                  the purposes of judicial review nor does                   G.-K. Plattner, M. Tignor, S.K. Allen, J.
     Executive Order 12866, and because the                                                                             Boschung, A. Nauels, Y. Xia, V. Bex and
                                                             it extend the time within which a
     EPA does not believe the environmental                                                                             P.M. Midgley (eds.)]. Cambridge
                                                             petition for judicial review must be                       University Press, Cambridge, United
     health or safety risks addressed by this                filed, and shall not postpone the                          Kingdom and New York, NY, USA, 1535
     action present a disproportionate risk to               effectiveness of such action. Thus, any                    pp.
     children. Since HFO–1336mzz–Z is                        petitions for review of this action                   Pitts, J.N. Jr., Winer, A.M., Aschmann, S.M.,
     utilized in specific industrial                         related to the exemption of HFO–                           Carter, W.P.L., and Atkinson, K. (1983),
     applications where children are not                     1336mzz–Z from the regulatory                              Experimental Protocol for Determining
     present and dissipates quickly (e.g.,                   definition of VOC must be filed in the                     Hydroxyl Radical Reaction Rate
     lifetime of 22 days) with short-lived end               Court of Appeals for the District of                       Constants Environmental Science
     products, there is no exposure or                                                                                  Research Laboratory, ORD, USEPA.
                                                             Columbia Circuit within 60 days from
     disproportionate risk to children. This                                                                            EPA600/3–82–038.
                                                             the date the final action is published in             USEPA, 2014. Significant New Alternatives
     action removes HFO–1336mzz–Z from                       the Federal Register.                                      Policy Program; Foam Blowing Sector;
     the regulatory definition of VOC and,                                                                              Risk Screen on Substitutes in Rigid
     thereby, relieves manufacturers,                        References
                                                                                                                        Polyurethane Appliance Foam; Rigid
     distributers and users from tropospheric                                                                           Polyurethane and Polyisocyanurate
                                                             Atkinson, R., Baulch, D.L., Cox, R.A.,
     O3 requirements to control emissions of                                                                            Laminated Boardstock; Rigid
                                                                 Crowley, J.N., Hampson, Jr., R.F., Hynes,
     the compound.                                               R.G., Jenkin, M.E., Kerr, J.A., Rossi, M.J.,           Polyurethane Commercial Refrigeration
                                                                 and Troe, J. (2006) Evaluated kinetic and              and Sandwich Panels; Rigid
     I. Executive Order 13211: Actions                                                                                  Polyurethane Slabstock and Other;
     Concerning Regulations That                                 photochemical data for atmospheric
                                                                 chemistry: Volume II—gas phase                         Flexible Polyurethane; Integral Skin
     Significantly Affect Energy Supply,                         reactions of organic species. Atmos.                   Polyurethane; and Phenolic Insulation
     Distribution or Use                                         Chem. Phys. 6: 3625–4055.                              Board and Bunstock. Substitute: HFO–
        This action is not subject to Executive              Baasandorj, M., Ravishankara, A.R.,                        1336mzz(Z) (Formacel® 1100); October
     Order 13211, because it is not a                            Burkholder, J.B. (2011) Atmospheric                    10, 2014. Available online at: https://
                                                                 chemistry of (Z)–CF3CHÕCHCF3: OH                       www.gpo.gov/fdsys/pkg/FR-2014-10-21/
     significant regulatory action under                                                                                pdf/2014-24989.pdf.
                                                                 radical reaction rate coefficient and
     Executive Order 12866.                                      global warming potential. J Phys Chem             USEPA, 2016. Significant New Alternatives
     J. National Technology Transfer and                         A. 2011 Sep 29; 115(38):10539–49. doi:                 Policy Program; Refrigeration and Air
     Advancement Act (NTTAA)                                     10.1021/jp206195g.                                     Conditioning Sector; Risk Screen on
                                                             Carter, W.P.L. (1994) Development of ozone                 Substitutes for Use in Chillers and
        This rulemaking does not involve                         reactivity scales for volatile organic                 Industrial Process Air Conditioning
     technical standards.                                        compounds. J. Air Waste Manage, 44:                    Substitute: HFO–1336mzz(Z) (Opteon®
                                                                 881–899.                                               MZ); May 23, 2016. Available online at:
     K. Executive Order 12898: Federal                       Carter, W.P.L. (2008) Reactivity Estimates for             https://www.gpo.gov/fdsys/pkg/FR2016-
     Actions To Address Environmental                            Selected Consumer Product Compounds,                   05-23/pdf/2016-12117.pdf.
     Justice in Minority Populations and                         Final Report to California Air Resources
     Low-Income Populations                                      Board Contract No. 06–408, February 19,           List of Subjects in 40 CFR Part 51
                                                                 2008. http://www.arb.ca.gov/research/
        The EPA believes that this action does                   reactivity/consumer_products.pdf.                   Environmental protection,
     not have disproportionately high and                    Carter, W.P.L. (2011) SAPRC Atmospheric               Administrative practice and procedure,
     adverse human health or environmental                       Chemical Mechanisms and VOC                       Air pollution control, Ozone, Reporting
     effects on minority populations, low-                       Reactivity Scales, at http://                     and recordkeeping requirements,
     income populations and/or indigenous                        www.engr.ucr.edu/∼carter/SAPRC/. Last             Volatile organic compounds.
     peoples, as specified in Executive Order                    updated in Sept. 14, 2013. Tables of
                                                                 Maximum Incremental Reactivity (MIR)               Dated: November 16, 2018.
     12898 (59 FR 7629 February 16, 1994).
                                                                 Values available at http://                       Andrew R. Wheeler,
     This action removes HFO–1336mzz–Z
                                                                 www.arb.ca.gov/regact/2009/mir2009/               Acting Administrator.
     from the regulatory definition of VOC                       mir2009.htm. May 11, 2011.
     and, thereby, relieves manufacturers,                   Carter, W.P.L. (2011a) Estimation of the                For reasons stated in the preamble,
     distributers, and users of the compound                     ground-level atmospheric ozone                    part 51 of chapter I of title 40 of the
     from tropospheric O3 requirements to                        formation potentials of Cis 1,1,1,4,4,4-          Code of Federal Regulations is amended
     control emissions of the compound.                          HexaFluoro-2-Butene, August 8, 2011.              as follows:


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     61134        Federal Register / Vol. 83, No. 229 / Wednesday, November 28, 2018 / Rules and Regulations

     PART 51—REQUIREMENTS FOR                                1,1,1,2,3,3,3-heptafluoropropane                      FOR FURTHER INFORMATION CONTACT:         For
     PREPARATION, ADOPTION, AND                              ((CF3)2CFCF2OCH3); 1-ethoxy-                          additional information on this
     SUBMITTAL OF IMPLEMENTATION                             1,1,2,2,3,3,4,4,4-nonafluorobutane                    proceeding, contact Sonia Greenaway
     PLANS                                                   (C4F9OC2H5 or HFE–7200); 2-                           Mickle, Sonia.Greenaway@fcc.gov, of
                                                             (ethoxydifluoromethyl)-1,1,1,2,3,3,3-                 the Policy Division, Media Bureau, (202)
     ■ 1. The authority citation for part 51                 heptafluoropropane                                    418–1419.
     continues to read as follows:                           ((CF3)2CFCF2OC2H5); methyl acetate;                   SUPPLEMENTARY INFORMATION: This is a
       Authority: 23 U.S.C. 101; 42 U.S.C. 7401–             1,1,1,2,2,3,3-heptafluoro-3-methoxy-                  summary of the Commission’s Order,
     7671q.                                                  propane (n-C3F7OCH3, HFE–7000); 3-                    FCC 18–150, adopted and released on
                                                             ethoxy- 1,1,1,2,3,4,4,5,5,6,6,6-                      October 25, 2018. The full text of this
     Subpart F—Procedural Requirements                       dodecafluoro-2-(trifluoromethyl) hexane               document is available for public
                                                             (HFE–7500); 1,1,1,2,3,3,3-                            inspection and copying during regular
     ■ 2. Section 51.100 is amended by
                                                             heptafluoropropane (HFC 227ea);                       business hours in the FCC Reference
     revising paragraph (s)(1) introductory
                                                             methyl formate (HCOOCH3);                             Center, Federal Communications
     text to read as follows:
                                                             1,1,1,2,2,3,4,5,5,5-decafluoro-3-                     Commission, 445 12th Street SW, Room
     § 51.100   Definitions.                                 methoxy-4-trifluoromethyl-pentane                     CY–A257, Washington, DC 20554. This
     *      *     *    *     *                               (HFE–7300); propylene carbonate;                      document will also be available via
        (s) * * *                                            dimethyl carbonate; trans-1,3,3,3-                    ECFS at http://fjallfoss.fcc.gov/ecfs/.
        (1) This includes any such organic                   tetrafluoropropene; HCF2OCF2H (HFE–                   Documents will be available
     compound other than the following,                      134); HCF2OCF2OCF2H (HFE–236cal2);                    electronically in ASCII, Microsoft Word,
     which have been determined to have                      HCF2OCF2CF2OCF2H (HFE–338pcc13);                      and/or Adobe Acrobat. Copies of the
     negligible photochemical reactivity:                    HCF2OCF2OCF2CF2OCF2H (H-Galden                        materials can be obtained from the
     Methane; ethane; methylene chloride                     1040x or H-Galden ZT 130 (or 150 or                   FCC’s Reference Information Center at
     (dichloromethane); 1,1,1-trichloroethane                180)); trans 1-chloro-3,3,3-trifluoroprop-            (202) 418–0270. Alternative formats are
     (methyl chloroform); 1,1,2-trichloro-                   1-ene; 2,3,3,3-tetrafluoropropene; 2-                 available for people with disabilities
     1,2,2-trifluoroethane (CFC–113);                        amino-2-methyl-1-propanol; t-butyl                    (Braille, large print, electronic files,
     trichlorofluoromethane (CFC–11);                        acetate; 1,1,2,2- Tetrafluoro -1-(2,2,2-              audio format), by sending an email to
     dichlorodifluoromethane (CFC–12);                       trifluoroethoxy) ethane; cis-1,1,1,4,4,4-             fcc504@fcc.gov or calling the
     chlorodifluoromethane (HCFC–22);                        hexafluorobut-2-ene (HFO–1336mzz-Z);                  Commission’s Consumer and
     trifluoromethane (HFC–23); 1,2-dichloro                 and perfluorocarbon compounds which                   Governmental Affairs Bureau at (202)
     1,1,2,2-tetrafluoroethane (CFC–114);                    fall into these classes:                              418–0530 (voice), (202) 418–0432
     chloropentafluoroethane (CFC–115);                      *      *    *     *      *                            (TTY).
     1,1,1-trifluoro 2,2-dichloroethane                      [FR Doc. 2018–25891 Filed 11–27–18; 8:45 am]
     (HCFC–123); 1,1,1,2-tetrafluoroethane                   BILLING CODE 6560–50–P
                                                                                                                   Synopsis
     (HFC–134a); 1,1-dichloro 1-fluoroethane                                                                          1. The Commission in this Order
     (HCFC–141b); 1-chloro 1,1-                                                                                    establishes electronic filing procedures
     difluoroethane (HCFC–142b); 2-chloro-                   FEDERAL COMMUNICATIONS                                for parties seeking to operate an Open
     1,1,1,2-tetrafluoroethane (HCFC–124);                   COMMISSION                                            Video System (OVS) to submit a
     pentafluoroethane (HFC–125); 1,1,2,2-                                                                         certification application and notice of
     tetrafluoroethane (HFC–134); 1,1,1-                     47 CFR Part 76                                        intent. By replacing our current paper
     trifluoroethane (HFC–143a); 1,1-                                                                              filing requirements for OVS applications
                                                             [MB Docket No. 17–105; FCC 18–150]
     difluoroethane (HFC–152a);                                                                                    and notices with an electronic filing
     parachlorobenzotrifluoride (PCBTF);                     Procedural Revisions to the Filing of                 system, this Order modernizes our
     cyclic, branched, or linear completely                  Open Video System Certification                       regulations, reduces burdens for OVS
     methylated siloxanes; acetone;                          Applications                                          applicants, and increases the efficiency
     perchloroethylene (tetrachloroethylene);                                                                      of the Commission’s processing of
     3,3-dichloro-1,1,1,2,2-                                 AGENCY:  Federal Communications                       applications.
     pentafluoropropane (HCFC–225ca); 1,3-                   Commission.                                              2. The Telecommunications Act of
     dichloro-1,1,2,2,3-pentafluoropropane                   ACTION: Final rule.                                   1996 added section 653 to the
     (HCFC–225cb); 1,1,1,2,3,4,4,5,5,5-                                                                            Communications Act of 1934, as
     decafluoropentane (HFC 43–10mee);                       SUMMARY:    In this document, the Federal             amended (the Act), establishing OVS as
     difluoromethane (HFC–32);                               Communications Commission (FCC or                     a new framework for entry into the
     ethylfluoride (HFC–161); 1,1,1,3,3,3-                   Commission) modernizes the Open                       multichannel video programming
     hexafluoropropane (HFC–236fa);                          Video System (OVS) filing procedures                  distribution marketplace.1 Any party
     1,1,2,2,3-pentafluoropropane (HFC–                      by specifying that OVS applications be
     245ca); 1,1,2,3,3-pentafluoropropane                    required to send certification                          1 Telecommunications Act of 1996, Public Law

     (HFC–245ea); 1,1,1,2,3-                                 applications, including FCC Form 1275                 104–104, 110 Stat. 56, approved February 8, 1996.
                                                             and all attachments, as well as notices               An open video system is similar to a cable system
     pentafluoropropane (HFC–245eb);                                                                               in that it is a facilities-based system for the delivery
     1,1,1,3,3-pentafluoropropane (HFC–                      of intent, via electronic email (email)               of video programming. Unlike cable systems,
     245fa); 1,1,1,2,3,3-hexafluoropropane                   delivery to a designated Commission                   however, open video systems must set aside up to
     (HFC–236ea); 1,1,1,3,3-                                 email address. The FCC also eliminates                two thirds of their channel capacity for the delivery
                                                             certain existing requirements associated              of independent programming of third parties. The
     pentafluorobutane (HFC–365mfc);                                                                               OVS framework was established to provide
     chlorofluoromethane (HCFC–31); 1                        with the rule. Parties wishing to                     competition and lower barriers to entry in the
     chloro-1-fluoroethane (HCFC–151a); 1,2-                 respond to a FCC Form 1275 filing must                provision of video programming to consumers. See
     dichloro-1,1,2-trifluoroethane (HCFC–                   submit comments or oppositions via                    Implementation of Section 302 of the
                                                             electronic mail (email).                              Telecommunications Act of 1996, Open Video
     123a); 1,1,1,2,2,3,3,4,4-nonafluoro-4-                                                                        Systems, 11 FCC Rcd 18223, 18227, para. 2–3 (1996)
     methoxy-butane (C4F9OCH3 or HFE–                        DATES: Effective date: November 28,                   (Second Report and Order). The approach
     7100); 2-(difluoromethoxymethyl)-                       2018.                                                 developed for the OVS model provides streamlined



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Document Created: 2018-11-27 23:48:54
Document Modified: 2018-11-27 23:48:54
CategoryRegulatory Information
CollectionFederal Register
sudoc ClassAE 2.7:
GS 4.107:
AE 2.106:
PublisherOffice of the Federal Register, National Archives and Records Administration
SectionRules and Regulations
ActionFinal rule.
DatesThis final rule is effective on January 28, 2019.
ContactDr. Souad Benromdhane, Office of Air Quality Planning and Standards, Health and Environmental Impacts Division, Mail Code C539-07, Environmental Protection Agency, Research Triangle Park, NC 27711; telephone: (919) 541-4359; fax number: (919)
FR Citation83 FR 61127 
RIN Number2060-AT52
CFR AssociatedEnvironmental Protection; Administrative Practice and Procedure; Air Pollution Control; Ozone; Reporting and Recordkeeping Requirements and Volatile Organic Compounds

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